公开(公告)号：US20150086462A1

公开(公告)日：2015-03-26

申请号：US14397484

申请日：2013-04-25

申请人： Heraeus Quarzglas GmbH & Co. KG

发明人： Mario Such ,  Gerhard Schoetz ,  Andreas Langner

IPC分类号： C01B33/18

CPC分类号： C01B33/18 ,  C03B19/108 ,  C03C1/026

摘要： The invention relates to a process for producing SiO2 granules by freezing and re-thawing an SiO2 suspension, wherein a separation of liquid and sediment composed of agglomerated SiO2 particles occurs in the course of thawing, the liquid removed is decanted and the residual moisture in the sediment is removed by a drying step with formation of the SiO2 granules. According to the invention, an auxiliary comprising alkali metal-free bases in the form of nitrogen hydrides is added to the suspension to set the pH greater than 7.

摘要翻译： 本发明涉及一种通过冷冻和再融化SiO 2悬浮液来生产SiO 2颗粒的方法，其中在解冻过程中发生由附聚的SiO 2颗粒组成的液体和沉积物的分离，将去除的液体倾倒并将残留的水分 通过形成SiO 2颗粒的干燥步骤除去沉淀物。 根据本发明，向悬浮液中加入包含氮化氢形式的不含碱金属的碱的辅助剂，使pH大于7。

公开(公告)号：US20150060918A1

公开(公告)日：2015-03-05

申请号：US14453135

申请日：2014-08-06

申请人： Shin-Etsu Chemical Co., Ltd.

发明人： Toshio SHIOBARA ,  Yoshihiro TSUTSUMI

IPC分类号： C03C12/02 ,  H01L33/60 ,  H01L33/56 ,  G02B1/04 ,  C03B19/10

CPC分类号： C03C12/02 ,  C03B19/1065 ,  C03B19/108 ,  C03C1/006 ,  C08J3/203 ,  C08J2300/24 ,  C08J2383/06 ,  C08K3/22 ,  G02B1/04 ,  H01L24/97 ,  H01L33/60 ,  H01L2224/32245 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2224/97 ,  H01L2924/12042 ,  H01L2924/15747 ,  H01L2933/0058 ,  Y10T428/2982 ,  C08L83/04 ,  H01L2924/00014 ,  H01L2924/00 ,  C08L63/00

摘要： A composite oxide particle prepared from raw materials comprising: (1) a finely powdered silica having a BET specific surface area of 50 m2/g or greater or an alkoxysilane, and (2) a liquid metal alkoxide other than an alkoxysilane or a nano order metal oxide powder other than finely powdered silica, one of components (1) and (2) being a solid oxide and the other being a liquid alkoxide, wherein the composite oxide particle is prepared by mixing or kneading the raw materials to obtain a sol or gel-like substance, sintering the sol or gel-like substance at a temperature of 300° C. or higher to form a glass-like substance, and then crushing the glass-like substance is provided. Also, a resin composition containing the composite oxide particle, and a reflector for a light-emitting semiconductor device formed using the resin composition are provided. The invention is able to provide a resin composition which is ideal as a reflector material for a light-emitting semiconductor device that exhibits high light reflectance and minimal light transmission, and a composite oxide particle that is added to the resin composition.

摘要翻译： 由原料制备的复合氧化物颗粒，包括：（1）BET比表面积为50m 2 / g以上的细粉状二氧化硅或烷氧基硅烷，（2）除烷氧基硅烷或纳米级以外的液态金属醇盐 除了细粉状二氧化硅之外的金属氧化物粉末，组分（1）和（2）之一是固体氧化物，另一种是液体醇盐，其中复合氧化物颗粒通过混合或捏合原料制备以获得溶胶或 凝胶状物质，在300℃以上的温度下烧结溶胶或凝胶状物质，形成玻璃状物质，然后粉碎玻璃状物质。 此外，提供了含有复合氧化物粒子的树脂组合物和使用该树脂组合物形成的发光半导体器件的反射体。 本发明能够提供一种理想的树脂组合物，其是表现出高反射率和最小透光性的发光半导体器件的反射材料，以及添加到树脂组合物中的复合氧化物颗粒。

公开(公告)号：US08637300B2

公开(公告)日：2014-01-28

申请号：US13763331

申请日：2013-02-08

申请人： Sued-Chemie IP GmbH & Co. KG

发明人： Friedrich Ruf ,  Ulrich Sohling ,  Elisabeth Neitmann ,  Bernd Linke ,  Jan Mumme ,  Patrice Ramm ,  Oliver Menhorn ,  Karl Weinberger ,  Peter Kumpf

IPC分类号： A62D3/02 ,  C12N11/14

CPC分类号： C12N11/14 ,  C03B19/108 ,  C03C11/007 ,  C03C14/004 ,  C03C2214/04 ,  C03C2214/30 ,  C12M25/14 ,  C12N5/0068 ,  Y02P40/57

摘要： A method for treating an organic and/or inorganic substrate utilizing a granular material made of a solid foam as support for an active component, for example a biocatalyst such as a microorganism or an enzyme. The solid foam has a continuous phase in which magnetizable particles are embedded, such that the support with the biologically active component immobilized thereon can be separated from a mixture with a magnetic separation device.

摘要翻译： 使用由固体泡沫制成的颗粒材料作为活性组分的载体（例如微生物或酶等生物催化剂）处理有机和/或无机底物的方法。 固体泡沫体具有嵌入可磁化颗粒的连续相，使得其上固定有生物活性组分的载体可以与具有磁分离装置的混合物分离。

公开(公告)号：US20100221540A1

公开(公告)日：2010-09-02

申请号：US12224067

申请日：2006-02-24

申请人： Monika Hermann

发明人： Monika Hermann

IPC分类号： C03C11/00 ,  C03B19/10

CPC分类号： A61K6/0276 ,  A61K6/0008 ,  A61K6/0073 ,  A61K6/083 ,  B02C19/065 ,  B07B7/083 ,  C03B19/108 ,  C03C3/06 ,  C03C3/118 ,  C03C4/0021 ,  C03C11/005 ,  Y10T428/2982

摘要： The invention relates to a process for producing a porous glass and glass powder using a partial Vycor process on an alkali metal borosilicate glass material. The process is characterized in that an addition of metal oxides and/or rare earth metal oxides in variable proportions of from 0.05 to 15 percent by mass is carried out on the alkali metal borosilicate glass material during the course of the Vycor process, with a doping incorporation of the metal oxides and/or the rare earth metal oxides into the resulting SiO2 matrix with an increase in the optical index of refraction of the porous glass being brought about during the Vycor process, and an opposed jet milling process is employed in combination with a ceramic sifter wheel in a subsequent dry milling process, with classification of the porous glass particles produced which have a size range of less than 15 μm being carried out. The porous glass material is characterized by a ternary SiO2—B2O3—Na2O base mixture having an adjustable optical index fraction in a material composition having the following variable proportions of metal and lanthanide oxides: 0.001-0.1% by mass of Fe2O3, 0.01-0.2% by mass of MgO, 0.05-15% by mass of ZrO2, 0.5-15% by mass of La2O3, 0.5-15% by mass of WO3, 0.5-15% by mass of TiO2.

摘要翻译： 本发明涉及在碱金属硼硅酸盐玻璃材料上使用部分Vycor工艺制造多孔玻璃和玻璃粉末的方法。 该方法的特征在于，在Vycor工艺过程中，在碱金属硼硅酸盐玻璃材料上加入0.05至15质量％的可变比例的金属氧化物和/或稀土金属氧化物，掺杂 在Vycor工艺期间，随着多孔玻璃的光学折射率的增加，金属氧化物和/或稀土金属氧化物结合到所得的SiO 2基体中，并且采用相对的喷射研磨方法与 在随后的干法研磨过程中的陶瓷筛子轮，进行了尺寸范围小于15μm的生产的多孔玻璃颗粒的分级。 多孔玻璃材料的特征在于具有以下可变比例的金属和镧系元素氧化物的材料组成中具有可调光学指数分数的三元SiO 2 -B 2 O 3 -Na 2 O基混合物：0.001-0.1质量％的Fe 2 O 3，0.01-0.2％ 的MgO，0.05〜15质量％的ZrO 2，0.5〜15质量％的La 2 O 3，0.5〜15质量％的WO 3，0.5〜15质量％的TiO 2。

公开(公告)号：US07637126B2

公开(公告)日：2009-12-29

申请号：US10582117

申请日：2004-11-30

申请人： Rainer Koeppler ,  Bodo Kuehn ,  Waltraud Werdecker ,  Ulrich Kirst ,  Walter Lehmann

发明人： Rainer Koeppler ,  Bodo Kuehn ,  Waltraud Werdecker ,  Ulrich Kirst ,  Walter Lehmann

IPC分类号： C03B37/075

CPC分类号： C03C4/0071 ,  C03B19/06 ,  C03B19/063 ,  C03B19/066 ,  C03B19/1005 ,  C03B19/1065 ,  C03B19/108 ,  C03B19/1095 ,  C03B20/00 ,  C03B2201/07 ,  C03B2201/075 ,  C03B2201/34 ,  C03C1/026 ,  C03C3/06 ,  C03C2201/23 ,  C03C2201/3411 ,  C03C2201/3435 ,  C03C2201/3488 ,  C03C2201/36 ,  C03C2203/22 ,  C03C2203/30 ,  C03C2203/44 ,  C03C2203/52

摘要： The invention relates to a method for the economic production of a blank for a component made from laser-active quartz glass in any form or dimension. The method comprises the following method steps: a) preparation of a dispersion with a solids content of at least 40 wt. %, comprising SiO2 nanopowder and doping agents, including a cation of the rare earth metals and transition metals in a fluid, b) granulation by agitation of the dispersion, with removal of moisture to form a doped SiO2 granulate of spherical porous granular particles with a moisture content of less than 35 wt. % and a density of at least 0.95 g/cm3, c) drying and purification of the SiO2 granulate, by heating to a temperature of at least 1000° C. to form doped porous SiO2 grains with an OH content of less than 10 ppm and d) sintering or fusing the doped SiO2 grains in a reducing atmosphere to give the blank made from doped quartz glass.

摘要翻译： 本发明涉及一种用于经济地生产用于由任何形式或尺寸的激光 - 活性石英玻璃制成的部件的坯料的方法。 该方法包括以下方法步骤：a）制备固体含量为至少40wt。 ％，包括SiO 2纳米粉末和掺杂剂，其包括流体中的稀土金属和过渡金属的阳离子，b）通过搅拌分散体制粒，除去水分以形成掺杂的SiO 2颗粒的球形多孔颗粒，其具有 含水量小于35wt。 ％和密度至少为0.95g / cm 3，c）通过加热到至少1000℃的温度来干燥和纯化SiO 2颗粒，以形成OH含量低于10ppm的掺杂多孔SiO 2颗粒，以及 d）在还原气氛中烧结或熔融掺杂的SiO 2晶粒，得到由掺杂的石英玻璃制成的坯料。

公开(公告)号：US20070145332A1

公开(公告)日：2007-06-28

申请号：US10582117

申请日：2004-11-30

申请人： Rainer Koeppler ,  Bodo Kuehn ,  Waltraud Werdecker ,  Ulrich Kirst ,  Walter Lehmann

发明人： Rainer Koeppler ,  Bodo Kuehn ,  Waltraud Werdecker ,  Ulrich Kirst ,  Walter Lehmann

IPC分类号： C09K11/66 ,  C03B8/00 ,  C03B19/00

CPC分类号： C03C4/0071 ,  C03B19/06 ,  C03B19/063 ,  C03B19/066 ,  C03B19/1005 ,  C03B19/1065 ,  C03B19/108 ,  C03B19/1095 ,  C03B20/00 ,  C03B2201/07 ,  C03B2201/075 ,  C03B2201/34 ,  C03C1/026 ,  C03C3/06 ,  C03C2201/23 ,  C03C2201/3411 ,  C03C2201/3435 ,  C03C2201/3488 ,  C03C2201/36 ,  C03C2203/22 ,  C03C2203/30 ,  C03C2203/44 ,  C03C2203/52

摘要： The invention relates to a method for the economic production of a blank for a component made from laser-active quartz glass in any form or dimension. The method comprises the following method steps: a) preparation of a dispersion with a solids content of at least 40 wt. %, comprising SiO2 nanopowder and doping agents, including a cation of the rare earth metals and transition metals in a fluid, b) granulation by agitation of the dispersion, with removal of moisture to form a doped SiO2 granulate of spherical porous granular particles with a moisture content of less than 35 wt. % and a density of at least 0.95 g/cm3, c) drying and purification of the SiO2 granulate, by heating to a temperature of at least 1000° C. to form doped porous SiO2 grains with an OH content of less than 10 ppm and d) sintering or fusing the doped SiO2 grains in a reducing atmosphere to give the blank made from doped quartz glass.

摘要翻译： 本发明涉及一种用于经济地生产用于由任何形式或尺寸的激光 - 活性石英玻璃制成的部件的坯料的方法。 该方法包括以下方法步骤：a）制备固体含量为至少40wt。 ％，包括SiO 2纳米粉末和掺杂剂，其包括流体中的稀土金属和过渡金属的阳离子，b）通过搅拌分散体制粒，除去水分以形成掺杂的SiO 水分含量小于35重量％的球形多孔粒状颗粒颗粒。 ％，密度至少为0.95g / cm 3，c）通过加热到至少1000℃的温度来干燥和纯化SiO 2颗粒。 以形成OH含量小于10ppm的掺杂多孔SiO 2颗粒，以及d）在还原气氛中烧结或熔合掺杂的SiO 2颗粒，得到坯料 来自掺杂石英玻璃。

公开(公告)号：US06645424B2

公开(公告)日：2003-11-11

申请号：US10145177

申请日：2002-05-13

申请人： Hu Chun Yi ,  Jacques Y. Guigné ,  John J. Moore

发明人： Hu Chun Yi ,  Jacques Y. Guigné ,  John J. Moore

IPC分类号： B29C3502

CPC分类号： C03B19/108 ,  C03B19/1005 ,  C03B2201/60 ,  C03B2201/62 ,  C03C14/004 ,  C03C2214/20 ,  C03C2214/30

摘要： The present invention is directed to the preparation of in-situ formation of a series of glass-ceramic composites by the Self-propagating High temperature Synthesis (SHS) technique with advantages of processing simplicity as well as the potential of cost savings. The materials produced by the technique contain crystalline TiB2 phase and have either a pure glassy matrix or a glass matrix with partial devitrification based on the Al2O3—CaO system. The materials can potentially be used for infrared light transmission and for other high temperature applications. These materials can also be produced with relatively high porosity.

公开(公告)号：US5763341A

公开(公告)日：1998-06-09

申请号：US773461

申请日：1996-12-24

申请人： Vyacheslav F. Pavlov ,  Vasily F. Shabanov

发明人： Vyacheslav F. Pavlov ,  Vasily F. Shabanov

IPC分类号： C03B5/00 ,  C03B19/10 ,  C03B32/02 ,  C03C1/00 ,  C03C3/085 ,  C03C11/00

CPC分类号： C03B19/108 ,  C03B19/1095 ,  C03B32/02 ,  C03B5/005 ,  C03C1/002 ,  C03C11/00 ,  C03C3/085

摘要： A method of obtaining glass materials from ash-slag. Waste wherein the waste is heated to a melting point temperature and melted in a reducing medium. The obtained melt is cooled by a thermal shock to form a foamed glass material. Prior to heating the charge, the carbon content therein is brought to 3.0-8.0 wt %, and the foamed glass material is foamed under a flow of a gaseous medium resulting form decomposition of carbides formed in the melt as a result of carbon content adjustment. Carbon addition also reduces iron oxide present in the waste, this reduction facilitating iron separation from the foamed material.

摘要翻译： 从灰渣获得玻璃材料的方法。 将废物加热到熔点温度并在还原介质中熔化的废物。 将获得的熔体通过热冲击冷却以形成泡沫玻璃材料。 在加热电荷之前，其碳含量达到3.0-8.0重量％，并且在气态介质流下发泡玻璃材料，由于碳含量调节，形成熔体中形成的碳化物的分解。 碳添加还减少废物中存在的氧化铁，这种还原促进了铁与泡沫材料的分离。

公开(公告)号：US4493720A

公开(公告)日：1985-01-15

申请号：US464556

申请日：1983-02-07

申请人： Francis Gauthier ,  Jean Gombert

发明人： Francis Gauthier ,  Jean Gombert

IPC分类号： C03B37/014 ,  C03B8/00 ,  C03B19/10 ,  C03B20/00 ,  C03B37/012 ,  C03B37/016 ,  C03B37/018 ,  C03C15/00 ,  C03B23/00 ,  C03B37/01

CPC分类号： C03B19/1065 ,  C03B19/102 ,  C03B19/108 ,  C03B37/01282 ,  C03B37/01291 ,  C03B37/01294 ,  C03B37/016 ,  C03B37/01861 ,  C03B37/01869 ,  C03B2203/22 ,  C03B2203/24 ,  C03B2203/26 ,  Y02P40/57

摘要： The invention relates to a process for producing ultrapure doped vitreous silica for producing a preform for optical fibres. According to the invention, an ultrapure porous glass, glass obtained after its shaping, is used as the crude starting material in a deposition process of the plasma torch, grain by grain Verneuil type, for example, in order to complete a preform obtained by said process for the separation of phases and acid washing or etching of the glasses.

摘要翻译： 本发明涉及用于生产用于光纤的预制棒的超纯掺杂玻璃状二氧化硅的方法。 根据本发明，例如，在其成型后获得的超纯多孔玻璃（例如）在等离子体焰炬的晶粒（通过晶粒Verneuil型）的沉积工艺中用作粗制原料，以便完成由所述 用于相分离和酸洗或蚀刻玻​​璃的方法。

公开(公告)号：US4123247A

公开(公告)日：1978-10-31

申请号：US851636

申请日：1977-11-15

申请人： Paul Metz ,  Robert Schockmel ,  Roland Mersch

发明人： Paul Metz ,  Robert Schockmel ,  Roland Mersch

IPC分类号： C04B5/00 ,  C03B7/16 ,  C03B19/10 ,  C21B3/06 ,  F27D15/00 ,  C03B19/08

CPC分类号： C03B19/1085 ,  C03B19/108 ,  C03B7/16 ,  C21B3/06 ,  Y02P40/52 ,  Y02P40/57 ,  Y02W30/543

摘要： Molten metallurgical slags are expanded by contact with water in a liquid or vapor state by passing the molten slag along a prefoaming or expanding trough by delivering the slag to this trough via an intermediate trough which is shiftable along the prefoaming trough in order to vary the location at which the slag contacts the prefoaming trough and the expanding-agent film thereon in accordance with physical characteristics of the molten slag, especially its temperature and viscosity. From the pre-expanding or prefoaming trough, the partially expanded slag may be subjected to expansion by conventional means, e.g. a rotating drum which disperses the slag particles through the air so that they can be collected in a completely expanded, dry and solidified state.

摘要翻译： 熔融冶金炉渣通过与液体或蒸汽状态的水接触而膨胀，通过使熔融炉渣沿着预发泡或膨胀槽通过将渣通过沿预发泡槽移动的中间槽输送到该槽来改变位置 渣根据熔渣的物理特性，尤其是其温度和粘度，与预发泡槽及其上的膨胀剂膜接触。 从预膨胀或预发泡槽中，部分膨胀的炉渣可以通过常规方法进行膨胀，例如， 一个旋转的鼓，其将渣粒分散通过空气，使得它们可以以完全膨胀，干燥和固化的状态收集。