公开(公告)号：US08084387B2

公开(公告)日：2011-12-27

申请号：US12594617

申请日：2008-01-30

申请人： Ki-won Jun ,  Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee

发明人： Ki-won Jun ,  Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee

IPC分类号： B01J27/185 ,  B01J23/40 ,  B01J23/42 ,  B01J23/00 ,  B01J23/08 ,  C01F7/02 ,  C07C27/00 ,  C07C27/06

CPC分类号： B01J23/75 ,  B01J27/16 ,  B01J27/1853 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/033 ,  B01J37/18 ,  B01J37/28

摘要： The present invention relates to a cobalt/phosphorus-alumina catalyst in which cobalt is supported as an active component on a phosphorus-alumina support wherein phosphorus is supported on alumina surface. With a bimodal pore structure of pores of relatively different pore sizes, the catalyst provides superior heat- and matter-transfer performance and excellent catalytic reactivity. Especially, when Fischer-Tropsch (F-T) reaction is performed using the catalyst, deactivation by the water produced during the F-T reaction is inhibited and, at the same time, the dispersion and reducing property of cobalt and other active component are improved. Therefore, the cobalt/phosphorus-alumina catalyst for F-T reaction in accordance with the present invention provides good carbon monoxide conversion and stable selectivity for liquid hydrocarbons.

摘要翻译： 本发明涉及一种钴/磷 - 氧化铝催化剂，其中钴作为活性组分负载在磷 - 氧化铝载体上，其中磷负载在氧化铝表面上。 具有相对不同孔径的孔的双峰孔结构，催化剂提供优异的热和物质转移性能和优异的催化反应性。 特别是当使用催化剂进行费托（F-T）反应时，抑制了F-T反应期间产生的水的失活，同时改善了钴等活性成分的分散还原性。 因此，根据本发明的用于F-T反应的钴/磷 - 氧化铝催化剂提供了良好的一氧化碳转化率和对液体烃的稳定选择性。

公开(公告)号：US20100093523A1

公开(公告)日：2010-04-15

申请号：US12594617

申请日：2008-01-30

申请人： Ki-won Jun ,  Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee

发明人： Ki-won Jun ,  Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee

IPC分类号： B01J27/185

CPC分类号： B01J23/75 ,  B01J27/16 ,  B01J27/1853 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/033 ,  B01J37/18 ,  B01J37/28

摘要： The present invention relates to a cobalt/phosphorus-alumina catalyst in which cobalt is supported as an active component on a phosphorus-alumina support wherein phosphorus is supported on alumina surface. With a bimodal pore structure of pores of relatively different pore sizes, the catalyst provides superior heat- and matter-transfer performance and excellent catalytic reactivity. Especially, when Fischer-Tropsch (F-T) reaction is performed using the catalyst, deactivation by the water produced during the F-T reaction is inhibited and, at the same time, the dispersion and reducing property of cobalt and other active component are improved. Therefore, the cobalt/phosphorus-alumina catalyst for F-T reaction in accordance with the present invention provides good carbon monoxide conversion and stable selectivity for liquid hydrocarbons.

摘要翻译： 本发明涉及一种钴/磷 - 氧化铝催化剂，其中钴作为活性组分负载在磷 - 氧化铝载体上，其中磷负载在氧化铝表面上。 具有相对不同孔径的孔的双峰孔结构，催化剂提供优异的热和物质转移性能和优异的催化反应性。 特别是当使用催化剂进行费托（F-T）反应时，抑制了F-T反应期间产生的水的失活，同时改善了钴等活性成分的分散还原性。 因此，根据本发明的用于F-T反应的钴/磷 - 氧化铝催化剂提供了良好的一氧化碳转化率和对液体烃的稳定选择性。

公开(公告)号：US08598066B2

公开(公告)日：2013-12-03

申请号：US12594695

申请日：2008-08-06

申请人： Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee ,  Ki-won Jun

发明人： Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee ,  Ki-won Jun

IPC分类号： B01J27/185 ,  B01J27/18

CPC分类号： B01J27/1853 ,  B01J21/04 ,  B01J23/75 ,  B01J27/16 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/109 ,  B01J37/033 ,  C10G2/33 ,  C10G2/332

摘要： The present invention relates to a process of preparing of a phosphorus-containing phosphorus-alumina support by a sol-gel method and a cobalt/phosphorus-alumina catalyst where cobalt is supported onto the phosphorus-alumina support as an active ingredient. The phosphorus-alumina support is prepared by a sol-gel method and has wide specific surface area with bimodal pore size distribution and high cobalt dispersion, thereby enabling to increase heat and mass transfer, stabilize the structure by modifying the surface property of alumina and decrease the deactivation rate due to the reduced oxidation of cobalt component during the F-T reaction. When Fischer-Tropsch reaction (F-T) is conducted on the catalyst, the catalyst maintains a superior thermal stability, inhibits the deactivation due to water generation during the F-T reaction and also causes relatively high conversion of carbon monoxide and stable selectivity of liquid hydrocarbons.

摘要翻译： 本发明涉及一种通过溶胶 - 凝胶法制备含磷磷 - 氧化铝载体的方法和一种钴/磷 - 氧化铝催化剂，其中钴作为活性成分负载在磷 - 氧化铝载体上。 磷 - 氧化铝载体通过溶胶 - 凝胶法制备，具有宽的比表面积，具有双峰孔径分布和高钴分散性，从而能够增加热和质量传递，通过改变氧化铝的表面性能来稳定结构，并减少 由于在FT反应期间钴组分的氧化降低导致的失活速率。 当在催化剂上进行费 - 托反应（F-T）时，催化剂保持优异的热稳定性，抑制在F-T反应期间由于水的产生而失活，并且还导致一氧化碳相对较高的转化率和液体烃的稳定选择性。

公开(公告)号：US20100130349A1

公开(公告)日：2010-05-27

申请号：US12594695

申请日：2008-08-06

申请人： Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee ,  Ki-won Jun

发明人： Jong-Wook Bae ,  Seung-Moon Kim ,  Yun-Jo Lee ,  Ki-won Jun

IPC分类号： B01J27/185 ,  B01J27/14 ,  B01J21/04 ,  B01J23/75

CPC分类号： B01J27/1853 ,  B01J21/04 ,  B01J23/75 ,  B01J27/16 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/109 ,  B01J37/033 ,  C10G2/33 ,  C10G2/332

摘要： The present invention relates to a process of preparing of a phosphorus-containing phosphorus-alumina support by a sol-gel method and a cobalt/phosphorus-alumina catalyst where cobalt is supported onto the phosphorus-alumina support as an active ingredient. The phosphorus-alumina support is prepared by a sol-gel method and has wide specific surface area with bimodal pore size distribution and high cobalt dispersion, thereby enabling to increase heat and mass transfer, stabilize the structure by modifying the surface property of alumina and decrease the deactivation rate due to the reduced oxidation of cobalt component during the F-T reaction. When Fischer-Tropsch reaction (F-T) is conducted on the catalyst, the catalyst maintains a superior thermal stability, inhibits the deactivation due to water generation during the F-T reaction and also causes relatively high conversion of carbon monoxide and stable selectivity of liquid hydrocarbons.

摘要翻译： 本发明涉及一种通过溶胶 - 凝胶法制备含磷磷 - 氧化铝载体的方法和一种钴/磷 - 氧化铝催化剂，其中钴作为活性成分负载在磷 - 氧化铝载体上。 磷 - 氧化铝载体通过溶胶 - 凝胶法制备，具有宽的比表面积，具有双峰孔径分布和高钴分散性，从而能够增加热和质量传递，通过改变氧化铝的表面性能来稳定结构，并减少 由于在FT反应期间钴组分的氧化降低导致的失活速率。 当在催化剂上进行费 - 托反应（F-T）时，催化剂保持优异的热稳定性，抑制在F-T反应期间由于水的产生而失活，并且还导致一氧化碳相对较高的转化率和液体烃的稳定选择性。

公开(公告)号：US08852516B2

公开(公告)日：2014-10-07

申请号：US12919919

申请日：2008-12-08

申请人： Kwang Jae Woo ,  Ki-won Jun ,  Suk-Hwan Kang ,  Seung-Moon Kim ,  Jong-Wook Bae

发明人： Kwang Jae Woo ,  Ki-won Jun ,  Suk-Hwan Kang ,  Seung-Moon Kim ,  Jong-Wook Bae

IPC分类号： B01J8/20 ,  B01J8/22 ,  B01J4/00 ,  C10G2/00 ,  B01J8/00 ,  B01J8/18

CPC分类号： B01J8/22 ,  B01J8/006 ,  B01J8/1809 ,  B01J2208/00061 ,  B01J2208/0007 ,  B01J2208/0061 ,  B01J2219/002 ,  B01J2219/00213 ,  B01J2219/00236 ,  C10G2/342 ,  C10G2300/4056 ,  C10G2300/4081

摘要： The present invention relates to a continuous separation and discharge apparatus and method of solid catalysts and liquid products for Fischer-Tropsch synthesis reactions, and more particularly, to a continuous separation and discharge apparatus and method of solid catalysts and products for Fischer-Tropsch synthesis reactions involving the conversion of synthetic gas into synthetic oil, by which products of the Fischer-Tropsch synthesis including wax, as a long-chain hydrocarbon, can be stably obtained by continuously separating the products from a slurry comprising solid catalyst particles and the products using periodic pulses of a feeding gas and discharging the products through a lower portion of a reactor. Provided is a continuous separation and discharge apparatus of solid catalysts and products for Fischer-Tropsch synthesis reactions including: a level sensing device which is installed at an upper portion of a reactor and detects the slurry-level of reactants; a solid catalyst/product separation device and a discharge device which are installed at a lower portion of the reactor and separate and discharge liquid products from a mixed slurry in the reactor; and a control unit which receives a signal from the level sensing device to open and close the discharge device, wherein the separation device filters the solid catalysts, and the discharge device continuously discharges the products separated from the solid catalysts through the lower portion of the reactor by the amount of the synthesized products measured by a level sensing device.

摘要翻译： 本发明涉及用于费 - 托合成反应的固体催化剂和液体产品的连续分离和排出装置和方法，更具体地说，涉及用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置和方法 包括将合成气转化为合成油，由此通过使包含固体催化剂颗粒和产物的浆料的产物通过使用周期性的方式连续分离，可以稳定地获得包含蜡作为长链烃的费 - 托合成产物 进料气体的脉冲并将产物排出反应器的下部。 提供了用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置，包括：液位传感装置，其安装在反应器的上部并检测反应物的浆料水平; 固体催化剂/产物分离装置和排出装置，其安装在反应器的下部，并将反应器中的混合浆料分离和排出液体产物; 以及控制单元，其接收来自液位感测装置的信号以打开和关闭排出装置，其中分离装置对固体催化剂进行过滤，并且排出装置连续排出与固体催化剂分离的产物通过反应器的下部 通过液位感测装置测量的合成产品的量。

公开(公告)号：US20110028574A1

公开(公告)日：2011-02-03

申请号：US12919919

申请日：2008-12-08

申请人： Kwang Jae Woo ,  Ki-won Jun ,  Suk-Hwan Kang ,  Seung-Moon Kim ,  Jong-Wook Bae

发明人： Kwang Jae Woo ,  Ki-won Jun ,  Suk-Hwan Kang ,  Seung-Moon Kim ,  Jong-Wook Bae

IPC分类号： C07C1/12 ,  B01J19/00

CPC分类号： B01J8/22 ,  B01J8/006 ,  B01J8/1809 ,  B01J2208/00061 ,  B01J2208/0007 ,  B01J2208/0061 ,  B01J2219/002 ,  B01J2219/00213 ,  B01J2219/00236 ,  C10G2/342 ,  C10G2300/4056 ,  C10G2300/4081

摘要： The present invention relates to a continuous separation and discharge apparatus and method of solid catalysts and liquid products for Fischer-Tropsch synthesis reactions, and more particularly, to a continuous separation and discharge apparatus and method of solid catalysts and products for Fischer-Tropsch synthesis reactions involving the conversion of synthetic gas into synthetic oil, by which products of the Fischer-Tropsch synthesis including wax, as a long-chain hydrocarbon, can be stably obtained by continuously separating the products from a slurry comprising solid catalyst particles and the products using periodic pulses of a feeding gas and discharging the products through a lower portion of a reactor. Provided is a continuous separation and discharge apparatus of solid catalysts and products for Fischer-Tropsch synthesis reactions including: a level sensing device which is installed at an upper portion of a reactor and detects the slurry-level of reactants; a solid catalyst/product separation device and a discharge device which are installed at a lower portion of the reactor and separate and discharge liquid products from a mixed slurry in the reactor; and a control unit which receives a signal from the level sensing device to open and close the discharge device, wherein the separation device filters the solid catalysts, and the discharge device continuously discharges the products separated from the solid catalysts through the lower portion of the reactor by the amount of the synthesized products measured by a level sensing device.

摘要翻译： 本发明涉及用于费 - 托合成反应的固体催化剂和液体产品的连续分离和排出装置和方法，更具体地说，涉及用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置和方法 包括将合成气转化为合成油，由此通过使包含固体催化剂颗粒和产物的浆料的产物通过使用周期性的方式连续分离，可以稳定地获得包含蜡作为长链烃的费 - 托合成产物 进料气体的脉冲并将产物排出反应器的下部。 提供了用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置，包括：液位传感装置，其安装在反应器的上部并检测反应物的浆料水平; 固体催化剂/产物分离装置和排出装置，其安装在反应器的下部，并将反应器中的混合浆料分离和排出液体产物; 以及控制单元，其接收来自液位感测装置的信号以打开和关闭排出装置，其中分离装置对固体催化剂进行过滤，并且排出装置连续排出与固体催化剂分离的产物通过反应器的下部 通过液位感测装置测量的合成产品的量。

公开(公告)号：US20090104108A1

公开(公告)日：2009-04-23

申请号：US11886367

申请日：2006-01-25

申请人： Ki-Won Jun ,  Yun-Jo Lee ,  Seung-Moon Kim ,  Jeong Yeon Kim

发明人： Ki-Won Jun ,  Yun-Jo Lee ,  Seung-Moon Kim ,  Jeong Yeon Kim

IPC分类号： C01F7/06

CPC分类号： C01F7/36 ,  B01J20/08 ,  B01J20/284 ,  B01J21/04 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/033 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/80

摘要： The present invention relates to a method for preparing boehmite and γ-alumina with high surface area, and more particularly, to a method comprising hydrolysis of aluminum alkoxides to produce boehmite and calcination to produce γ-alumina, wherein an alcohol is used as a reaction solvent and a small amount of water and a particular organic carboxylic acid are added so that not only the reaction solvent is easily recovered and energy required for drying is significantly reduced but also it provides boehmite having nano-sized particles, high surface area, and high purity. Further, the prepared γ-alumina may be suitable for high value added industrial applications such as manufacture of adsorbents, catalysts, catalyst supports and chromatography materials.

摘要翻译： 本发明涉及一种具有高表面积的勃姆石和γ-氧化铝的制备方法，更具体地涉及一种包括水解醇铝以制备勃姆石并煅烧以产生γ-氧化铝的方法，其中使用醇作为反应 溶剂和少量的水和特定的有机羧酸，使得不仅反应溶剂容易回收并且干燥所需的能量显着降低，而且还提供具有纳米尺寸颗粒，高表面积和高的勃姆石 纯度。 此外，所制备的γ-氧化铝可适用于高附加值工业应用，例如制造吸附剂，催化剂，催化剂载体和色谱材料。

公开(公告)号：US20110015062A1

公开(公告)日：2011-01-20

申请号：US12933856

申请日：2009-02-16

申请人： Seung-Moon Kim ,  Jong-Wook Bae ,  Jong-Hyeok Oh ,  Yun-Jo Lee ,  Ki-won Jun

发明人： Seung-Moon Kim ,  Jong-Wook Bae ,  Jong-Hyeok Oh ,  Yun-Jo Lee ,  Ki-won Jun

IPC分类号： B01J27/185

CPC分类号： B01J27/1856 ,  B01J23/002 ,  B01J27/1853 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1023 ,  B01J37/0201 ,  B01J37/03 ,  B01J2523/00 ,  C10G2/332 ,  B01J2523/41 ,  B01J2523/48 ,  B01J2523/51 ,  B01J2523/821 ,  B01J2523/845

摘要： The present invention relates to a cobalt/zirconium-phosphorus/silica catalyst in which cobalt, as an active ingredient, is impregnated on a zirconium-phosphorus/silica support prepared by treating the surface of silica with zirconium and phosphorus, and a method of preparing the catalyst. The catalyst has excellent reactivity since it has excellent heat and mass transfer properties due to a large pore structure of silica and increased reducibility of cobalt; excellent dispersion of cobalt and other activation substances during Fischer-Tropsch (F-T) reaction; and reduced sintering of cobalt particles during the reaction, and thus high CO conversion and stable selectivity for liquid hydrocarbon can be obtained during the F-T reaction.

摘要翻译： 本发明涉及一种钴/锆 - 磷/二氧化硅催化剂，其中钴作为活性成分浸渍在用锆和磷处理二氧化硅表面制备的锆 - 磷/二氧化硅载体上，以及制备方法 催化剂。 催化剂具有优异的反应性，因为由于二氧化硅的大孔结构和钴的还原性，它具有优异的热传质性能; 在费 - 托（F-T）反应中钴和其他活化物质的优异分散性; 并且在反应期间减少了钴颗粒的烧结，因此在F-T反应期间可以获得高CO转化率和对液态烃的稳定选择性。

公开(公告)号：US20080197051A1

公开(公告)日：2008-08-21

申请号：US12063053

申请日：2006-07-31

申请人： Byong Sung Kwak ,  Young Seek Yoon ,  Jin Hong Kim ,  Il Su Kim ,  Keun Seob Choi ,  Jin Hwan Bang ,  Ki Won Jun ,  Hyung Tae Kim ,  Seung Moon Kim

发明人： Byong Sung Kwak ,  Young Seek Yoon ,  Jin Hong Kim ,  Il Su Kim ,  Keun Seob Choi ,  Jin Hwan Bang ,  Ki Won Jun ,  Hyung Tae Kim ,  Seung Moon Kim

IPC分类号： C10G29/04 ,  B01J20/02

CPC分类号： B01D53/485 ,  B01D53/02 ,  B01D2257/306 ,  B01J20/0237 ,  B01J20/0244 ,  B01J20/06 ,  B01J20/08 ,  B01J20/28059 ,  B01J20/28061 ,  B01J2220/42 ,  Y02C20/20

摘要： Disclosed herein are a desulfurizing agent for removing organic sulfur compounds, a preparation method thereof, and a method for removing organic sulfur compounds using the same. The desulfurizing agent consists of a copper-zinc-aluminum complex free of alkaline metal, with a large surface area. When being contacted with organic sulfur compounds, such as t-butylmercaptan, tetrahydrothiophene, dimethylsulfide, etc., the desulfurizing agent exhibits excellent desulfurization ability and is not de-graded especially at high temperatures as high as 150˜350° C.

摘要翻译： 本文公开了用于除去有机硫化合物的脱硫剂，其制备方法和使用其的有机硫化合物的除去方法。 脱硫剂由不含碱金属的铜 - 锌 - 铝络合物构成，表面积大。 脱硫剂与叔丁基硫醇，四氢噻吩，二甲基硫醚等有机硫化合物接触时，脱硫能力优异，特别是在高达150〜350℃的高温下不脱层。