摘要:
In one aspect, the present invention provides a chromatographic stationary phase material for various different modes of chromatography represented by Formula 1: [X](W)a(Q)b(T)c (Formula 1). X can be a high purity chromatographic core composition having a surface comprising a silica core material, metal oxide core material, an inorganic-organic hybrid material or a group of block copolymers thereof. W can be absent and/or can include hydrogen and/or can include a hydroxyl on the surface of X. Q can be a functional group that minimizes retention variation over time (drift) under chromatographic conditions utilizing low water concentrations. T can include one or more hydrophilic, polar, ionizable, and/or charged functional groups that chromatographically interact with the analyte. Additionally, b and c can be positive numbers, with the ratio 0.05≤(b/c)≤100, and a≥0.
摘要:
Described is a filter-drier core for removing acids and halides that are generated by decomposition of a refrigerant that contains a fluoroiodocarbon, the filter drier core comprising a molded core that includes gamma phase activated alumina and a molecular sieve. The molecular sieve has a pore size between 3-4 angstroms and between 300-00 m2/g surface area, and/or the alumina is provided in a beaded form with average bead diameter between 0.1-10 mm. An alumina surface area may be between 140-250 m2/g, and an average pore size may be 6 nm to 16 nm. A percent molecular sieve in the core may be between 0-40%, with the rest of the core being alumina. To increase surface area of the core, the filter-drier core may define a plurality of suitably shaped channels that extend longitudinally through the core, may have fins that extend from a central body, or may be configured as a plurality of rods. A refrigerant system includes a refrigerant circuit through which a refrigerant flows, and a filter-drier unit including the filter-drier core configured for contact with the refrigerant for removing contaminants from the refrigeration system.
摘要:
The present invention generally relates to the field of gas and liquid phase desiccation. In particular, the present invention relates to methods for removing moisture (and hence oxygen precursors) from hydrazine, thereby providing a high purity source gas suitable for use in vapor deposition processes, such as but not limited to, chemical vapor deposition (CVD) or an atomic layer deposition (ALD).
摘要:
Novel particles and materials for chromatographic separations, processes for preparation and separations devices containing the chromatographic particles and materials are provided by the instant invention. In particular, the invention provides a porous inorganic/organic hybrid particle, wherein the inorganic portion of the hybrid particle is present in an amount ranging from about 0 molar % to not more than about 49 molar %, wherein the pores of the particle are substantially disordered. The invention also provides a porous inorganic/organic hybrid particle, wherein the inorganic portion of the hybrid particle is present in an amount ranging from about 25 molar % to not more than about 50 molar %, wherein the pores of the particle are substantially disordered and wherein the particle has a chromatographically enhancing pore geometry (CEPG). Methods for producing the hybrid particles, separations devices comprising the hybrid particles and kits are also provided.
摘要:
A new adsorbent CO2-ONE for removal of acidic gases such as carbon dioxide and hydrogen sulfide was developed from hydrothermal reaction of natural limestone with natural kaolin via sodium hydroxide. Several synthesis conditions were employed such as initial concentration of NaOH, weight ratio of limestone to kaolin, reaction temperature and pressure. The produced Ca—Na—SiO2-Al2O3 samples were characterized using XRD and EDS and showed that a mixture of Gehlenite Ca2Al(Al1.22Si0.78O6.78)OH0.22 and Stilbite Na5.76Ca4.96(Al15.68Si56.32O144) with percentage of 43 and 57 was successfully produced, respectively. Another produced sample showed the presence of Gehlenite Ca2Al(Al1.22Si0.78O6.78)OH0.22, Stilbite Na5.76Ca4.96(Al15.68Si56.32O144) and Lawsonite CaAl2Si2O7OH2(H2O) with percentage of 4.1 and 7.4 and 88, respectively.
摘要:
In an embodiment, a method for manufacturing a thin layer chromatography (“TLC”) plate is disclosed. The method includes forming a layer of elongated nanostructures (e.g., carbon nanotubes), priming the elongated nanostructures with one or more adhesion priming layers, and at least partially coating the elongated nanostructures with a coating. The coating includes a stationary phase and/or precursor of a stationary phase for use in chromatography. The stationary phase may be functionalized with hydroxyl groups by exposure to a base or acid. The stationary phase may further be treated with a silane (e.g., an amino silane) to improve the performance of the TLC plate. Embodiments for TLC plates and related methods are also disclosed.
摘要:
The present invention is a process for making an inorganic/organic hybrid totally porous spherical silica particles by self assembly of surfactants that serve as organic templates via pseudomorphic transformation.
摘要:
The present invention relates to a process for the production of monolithic separating columns using monolithic moldings whose diameter is reduced by grinding, and to separating columns having improved separation efficiency produced in this way, and to the use thereof.
摘要:
An object of the present invention is to provide a support for solid phase extraction for preventing the fracture of the porous body of the support and the space between the porous body and its container, and for processing various amounts of liquids to be processed while maintaining the ease of passage of liquid in use. A support 1 for solid phase extraction comprises a ceramic substrate 1 with a hole or holes 3 formed therein and an inorganic porous material 4 filled in the hole 3 produced by sol-gel transition accompanied by phase transition.
摘要:
A stationary medium is employed both to separate chemicals from a sample solution and also for surface-enhanced Raman spectral analysis of the separated chemical, thereby greatly reducing the complexity of the apparatus and enhancing the efficiency of the chemical analysis method.