摘要:
Disclosed is a method for producing an electrode catalyst for a fuel cell, which comprises a Ru-containing metal microparticle supported on an electrically conductive carbon carrier, wherein M2RuX6 [M=at least one member selected from H, Li, Na, K and NH4; X=at least one member selected from Cl, Br, I and NO3] is used as a precursor of Ru. It becomes possible to produce an electrode catalyst for a fuel cell, which is improved in the methanol oxidation activity per mass or surface area of the catalyst compared with a conventional Pt- and Ru-carrying carbon catalyst prepared by using a Ru raw material having an average valency of 3.
摘要翻译:公开了一种用于制造燃料电池用电极催化剂的方法,其包含负载在导电性碳载体上的含Ru金属微粒,其中M2RuX6 [M =选自H,Li,Na,K和NH4中的至少一种 ; X =选自Cl,Br,I和NO 3中的至少一种]用作Ru的前体。 可以制备用于燃料电池的电极催化剂,其与常规的使用具有钌原子的Ru原料制备的Pt和Ru载体碳催化剂相比,其催化剂的每质量或表面积的甲醇氧化活性提高了 平均价格为3。
摘要:
Disclosed is a method for producing an electrode catalyst for a fuel cell, which comprises a Ru-containing metal microparticle supported on an electrically conductive carbon carrier, wherein M2RuX6 [M=at least one member selected from H, Li, Na, K and NH4; X=at least one member selected from Cl, Br, I and NO3] is used as a precursor of Ru. It becomes possible to produce an electrode catalyst for a fuel cell, which is improved in the methanol oxidation activity per mass or surface area of the catalyst compared with a conventional Pt- and Ru-carrying carbon catalyst prepared by using a Ru raw material having an average valency of 3.
摘要翻译:公开了一种用于制造燃料电池用电极催化剂的方法,其包含负载在导电性碳载体上的含Ru金属微粒,其中M2RuX6 [M =选自H,Li,Na,K和NH4中的至少一种 ; X =选自Cl,Br,I和NO 3中的至少一种]用作Ru的前体。 可以制备用于燃料电池的电极催化剂,其与常规的使用具有钌原子的Ru原料制备的Pt和Ru载体碳催化剂相比,其催化剂的每质量或表面积的甲醇氧化活性提高了 平均价格为3。
摘要:
In a coated optical fiber comprising a quartz glass fiber, a primary coating and a secondary coating, the secondary coating is formed by curing a resin composition comprising (A) 20-90 wt % of a polyurethane (meth)acrylate oligomer which is synthesized from an alicyclic polyisocyanate, contains 5-90 wt % of a polyurethane (meth)acrylate oligomer having a Mn of up to 1,000, and has an overall Mn of up to 10,000, and (B) 80-10 wt % of an ethylenically unsaturated compound, with electron beams accelerated at 50-125 kV. The coated optical fiber has a minimized transmission loss.
摘要:
Disclosed is an electrolyte membrane-electrode assembly for direct methanol fuel cells, wherein a solid polymer electrolyte membrane is held between a pair of electrodes each composed of a catalyst layer coated over and/or impregnated in a porous supporting body. This electrolyte membrane-electrode assembly for direct methanol fuel cells is characterized in that the solid polymer electrolyte membrane is obtained by irradiating a resin membrane with radiation and graft-polymerizing a radically polymerizable monomer. The electrolyte membrane-electrode assembly for direct methanol fuel cells is further characterized in that the catalyst layer of the anode electrode comprises a catalyst, wherein platinum group metal or platinum-containing alloy particles having a particle size of 5 nm or less are supported by carbon particles, and a solid polymer electrolyte, and the noble metal amount in the catalyst layer of the anode electrode is not more than 5 mg/cm2. By using such a catalyst, there can be obtained a direct methanol fuel cell wherein high output is achieved by using high methanol concentration.
摘要:
This invention provides a process for producing an electrode catalyst for a fuel cell, comprising a first support step of producing metallic fine particles having an average particle diameter of 0.1 to 1.5 nm provided at regulated particle intervals on an electroconductive carbon carrier, and a second support step of growing a metal identical to or dissimilar to the metal using the metallic fine particles as a nucleus. In the first support step, the metallic fine particles are supported by an immersion method. The above constitution can provide an electrode catalyst for a fuel cell, which has a high level of percentage support, has a high level of dispersibility, and has improved methanol oxidation activity per weight of the catalyst. Further, when treatment in an atmosphere containing hydrogen is carried out at a low temperature below 100° C., the methanol oxidation activity per active surface area can be improved without lowering the active area.
摘要:
An optical waveguide substrate is prepared by forming grooves in a silicon substrate in accordance with the pattern of a desired waveguide device, thermally oxidizing the silicon substrate to form a peripheral quartz layer surrounding the grooves, burying in the grooves a doped quartz glass layer having a higher refractive index, abrading the surface of the resulting structure to be flat, and forming on the flat surface a glass layer having a lower refractive index. An optical waveguide substrate featuring no distortion of the core pattern, little warp, and a low loss can be produced in a simple manner.
摘要:
Disclosed is an electrolyte membrane-electrode assembly for direct methanol fuel cells, wherein a solid polymer electrolyte membrane is held between a pair of electrodes each composed of a catalyst layer coated over and/or impregnated in a porous supporting body. This electrolyte membrane-electrode assembly for direct methanol fuel cells is characterized in that the solid polymer electrolyte membrane is obtained by irradiating a resin membrane with radiation and graft-polymerizing a radically polymerizable monomer. The electrolyte membrane-electrode assembly for direct methanol fuel cells is further characterized in that the catalyst layer of the anode electrode comprises a catalyst, wherein platinum group metal or platinum-containing alloy particles having a particle size of 5 nm or less are supported by carbon particles, and a solid polymer electrolyte, and the noble metal amount in the catalyst layer of the anode electrode is not more than 5 mg/cm2. By using such a catalyst, there can be obtained a direct methanol fuel cell wherein high output is achieved by using high methanol concentration.
摘要:
An electrolyte membrane for fuel cells is prepared by irradiating with radiation a composition comprising a radiation-curable liquid compound having proton conductivity for curing the liquid compound to form a cured film. The methods of the invention are successful in producing an electrolyte membrane and an electrolyte membrane/electrode assembly for fuel cells while satisfying both the requirements of productivity and cell-related properties including proton conduction and membrane strength.
摘要:
A curable resin composition for fuel cell electrolyte films characterized by comprising (1) 100 parts by mass of a monomer having at least one ethylenically unsaturated group per molecule and having, per molecule, either at least one, tonically conductive group or at least one precursor group capable of giving an tonically conductive group through a chemical reaction, (2) 10-400 parts by mass of an oligomer which has, per molecule, at least two reactive groups copolymerizable with the ethylenically unsaturated group of the ingredient (1) and has a number-average molecular weight of 400 or higher, (3) 10-400 parts by mass of a fluororesin, and (4) 0-2,000 parts by mass of a solvent.
摘要:
This invention provides a process for producing an electrode catalyst for a fuel cell, comprising a first support step of producing metallic fine particles having an average particle diameter of 0.1 to 1.5 nm provided at regulated particle intervals on an electroconductive carbon carrier, and a second support step of growing a metal identical to or dissimilar to the metal using the metallic fine particles as a nucleus. In the first support step, the metallic fine particles are supported by an immersion method. The above constitution can provide an electrode catalyst for a fuel cell, which has a high level of percentage support, has a high level of dispersibility, and has improved methanol oxidation activity per weight of the catalyst. Further, when treatment in an atmosphere containing hydrogen is carried out at a low temperature below 100° C., the methanol oxidation activity per active surface area can be improved without lowering the active area.