Method for production of electrode catalyst for fuel cell
    1.
    发明授权
    Method for production of electrode catalyst for fuel cell 有权
    燃料电池用电极催化剂的制造方法

    公开(公告)号:US08178462B2

    公开(公告)日:2012-05-15

    申请号:US12681223

    申请日:2008-08-13

    申请人: Shigeru Konishi

    发明人: Shigeru Konishi

    摘要: Disclosed is a method for producing an electrode catalyst for a fuel cell, which comprises a Ru-containing metal microparticle supported on an electrically conductive carbon carrier, wherein M2RuX6 [M=at least one member selected from H, Li, Na, K and NH4; X=at least one member selected from Cl, Br, I and NO3] is used as a precursor of Ru. It becomes possible to produce an electrode catalyst for a fuel cell, which is improved in the methanol oxidation activity per mass or surface area of the catalyst compared with a conventional Pt- and Ru-carrying carbon catalyst prepared by using a Ru raw material having an average valency of 3.

    摘要翻译: 公开了一种用于制造燃料电池用电极催化剂的方法,其包含负载在导电性碳载体上的含Ru金属微粒,其中M2RuX6 [M =选自H,Li,Na,K和NH4中的至少一种 ; X =选自Cl,Br,I和NO 3中的至少一种]用作Ru的前体。 可以制备用于燃料电池的电极催化剂,其与常规的使用具有钌原子的Ru原料制备的Pt和Ru载体碳催化剂相比,其催化剂的每质量或表面积的甲醇氧化活性提高了 平均价格为3。

    METHOD FOR PRODUCTION OF ELECTRODE CATALYST FOR FUEL CELL
    2.
    发明申请
    METHOD FOR PRODUCTION OF ELECTRODE CATALYST FOR FUEL CELL 有权
    用于生产燃料电极的电极催化剂的方法

    公开(公告)号:US20100222206A1

    公开(公告)日:2010-09-02

    申请号:US12681223

    申请日:2008-08-13

    申请人: Shigeru Konishi

    发明人: Shigeru Konishi

    IPC分类号: H01M4/88

    摘要: Disclosed is a method for producing an electrode catalyst for a fuel cell, which comprises a Ru-containing metal microparticle supported on an electrically conductive carbon carrier, wherein M2RuX6 [M=at least one member selected from H, Li, Na, K and NH4; X=at least one member selected from Cl, Br, I and NO3] is used as a precursor of Ru. It becomes possible to produce an electrode catalyst for a fuel cell, which is improved in the methanol oxidation activity per mass or surface area of the catalyst compared with a conventional Pt- and Ru-carrying carbon catalyst prepared by using a Ru raw material having an average valency of 3.

    摘要翻译: 公开了一种用于制造燃料电池用电极催化剂的方法,其包含负载在导电性碳载体上的含Ru金属微粒,其中M2RuX6 [M =选自H,Li,Na,K和NH4中的至少一种 ; X =选自Cl,Br,I和NO 3中的至少一种]用作Ru的前体。 可以制备用于燃料电池的电极催化剂,其与常规的使用具有钌原子的Ru原料制备的Pt和Ru载体碳催化剂相比,其催化剂的每质量或表面积的甲醇氧化活性提高了 平均价格为3。

    Electrolyte membrane-electrode assembly for direct methanol fuel cell
    4.
    发明授权
    Electrolyte membrane-electrode assembly for direct methanol fuel cell 有权
    用于直接甲醇燃料电池的电解质膜 - 电极组件

    公开(公告)号:US09083026B2

    公开(公告)日:2015-07-14

    申请号:US12304061

    申请日:2007-05-23

    摘要: Disclosed is an electrolyte membrane-electrode assembly for direct methanol fuel cells, wherein a solid polymer electrolyte membrane is held between a pair of electrodes each composed of a catalyst layer coated over and/or impregnated in a porous supporting body. This electrolyte membrane-electrode assembly for direct methanol fuel cells is characterized in that the solid polymer electrolyte membrane is obtained by irradiating a resin membrane with radiation and graft-polymerizing a radically polymerizable monomer. The electrolyte membrane-electrode assembly for direct methanol fuel cells is further characterized in that the catalyst layer of the anode electrode comprises a catalyst, wherein platinum group metal or platinum-containing alloy particles having a particle size of 5 nm or less are supported by carbon particles, and a solid polymer electrolyte, and the noble metal amount in the catalyst layer of the anode electrode is not more than 5 mg/cm2. By using such a catalyst, there can be obtained a direct methanol fuel cell wherein high output is achieved by using high methanol concentration.

    摘要翻译: 公开了一种用于直接甲醇燃料电池的电解质膜 - 电极组件,其中固体聚合物电解质膜保持在一对电极之间,每对电极由涂覆在多孔支撑体上的和/或浸渍在多孔支撑体中的催化剂层组成。 该直接甲醇燃料电池用电解质膜 - 电极组件的特征在于,固体高分子电解质膜通过用辐射照射树脂膜并使自由基聚合性单体进行接枝聚合而获得。 用于直接甲醇燃料电池的电解质膜 - 电极组件的特征还在于,阳极电极的催化剂层包括催化剂,其中具有5nm或更小的粒径的铂族金属或含铂合金颗粒由碳负载 颗粒和固体聚合物电解质,并且阳极电极的催化剂层中的贵金属量不大于5mg / cm 2。 通过使用这样的催化剂,可以获得通过使用高甲醇浓度实现高产量的直接甲醇燃料电池。

    Process for producing electrode catalyst for fuel cell
    5.
    发明授权
    Process for producing electrode catalyst for fuel cell 失效
    生产燃料电池用电极催化剂的方法

    公开(公告)号:US08748334B2

    公开(公告)日:2014-06-10

    申请号:US12532176

    申请日:2008-02-28

    申请人: Shigeru Konishi

    发明人: Shigeru Konishi

    摘要: This invention provides a process for producing an electrode catalyst for a fuel cell, comprising a first support step of producing metallic fine particles having an average particle diameter of 0.1 to 1.5 nm provided at regulated particle intervals on an electroconductive carbon carrier, and a second support step of growing a metal identical to or dissimilar to the metal using the metallic fine particles as a nucleus. In the first support step, the metallic fine particles are supported by an immersion method. The above constitution can provide an electrode catalyst for a fuel cell, which has a high level of percentage support, has a high level of dispersibility, and has improved methanol oxidation activity per weight of the catalyst. Further, when treatment in an atmosphere containing hydrogen is carried out at a low temperature below 100° C., the methanol oxidation activity per active surface area can be improved without lowering the active area.

    摘要翻译: 本发明提供了一种燃料电池用电极催化剂的制造方法,其特征在于,包括在导电性碳载体上以规定粒子间隔设置平均粒径为0.1〜1.5nm的金属微粒子的第一担载工序, 使用金属微粒作为核生长与金属相同或不相似的金属的步骤。 在第一支撑工序中,通过浸渍法支撑金属微粒。 上述结构可以提供一种燃料电池用电极催化剂,其具有高水平的载体百分比,具有高水平的分散性,并且每重量的催化剂具有改善的甲醇氧化活性。 此外,当在低于100℃的低温下进行含氢气氛的处理时,可以在不降低有效面积的情况下提高每活性表面积的甲醇氧化活性。

    Method for preparing optical waveguide substrate
    6.
    发明授权
    Method for preparing optical waveguide substrate 失效
    光波导基板的制备方法

    公开(公告)号:US06615614B1

    公开(公告)日:2003-09-09

    申请号:US09610952

    申请日:2000-07-06

    IPC分类号: C03B1914

    摘要: An optical waveguide substrate is prepared by forming grooves in a silicon substrate in accordance with the pattern of a desired waveguide device, thermally oxidizing the silicon substrate to form a peripheral quartz layer surrounding the grooves, burying in the grooves a doped quartz glass layer having a higher refractive index, abrading the surface of the resulting structure to be flat, and forming on the flat surface a glass layer having a lower refractive index. An optical waveguide substrate featuring no distortion of the core pattern, little warp, and a low loss can be produced in a simple manner.

    摘要翻译: 通过根据期望的波导器件的图案在硅衬底中形成沟槽,热氧化硅衬底以形成围绕沟槽的外围石英层来制备光波导衬底,在沟槽中埋设掺杂的石英玻璃层,其具有 更高的折射率,将所得结构的表面研磨成平坦的,并且在平坦表面上形成具有较低折射率的玻璃层。 可以以简单的方式产生不具有芯图案变形,少量翘曲和低损耗的光波导基板。

    ELECTROLYTE MEMBRANE-ELECTRODE ASSEMBLY FOR DIRECT METHANOL FUEL CELL
    7.
    发明申请
    ELECTROLYTE MEMBRANE-ELECTRODE ASSEMBLY FOR DIRECT METHANOL FUEL CELL 有权
    直接甲醇燃料电池用电解质膜电极组件

    公开(公告)号:US20100248071A1

    公开(公告)日:2010-09-30

    申请号:US12304061

    申请日:2007-05-23

    IPC分类号: H01M8/10

    摘要: Disclosed is an electrolyte membrane-electrode assembly for direct methanol fuel cells, wherein a solid polymer electrolyte membrane is held between a pair of electrodes each composed of a catalyst layer coated over and/or impregnated in a porous supporting body. This electrolyte membrane-electrode assembly for direct methanol fuel cells is characterized in that the solid polymer electrolyte membrane is obtained by irradiating a resin membrane with radiation and graft-polymerizing a radically polymerizable monomer. The electrolyte membrane-electrode assembly for direct methanol fuel cells is further characterized in that the catalyst layer of the anode electrode comprises a catalyst, wherein platinum group metal or platinum-containing alloy particles having a particle size of 5 nm or less are supported by carbon particles, and a solid polymer electrolyte, and the noble metal amount in the catalyst layer of the anode electrode is not more than 5 mg/cm2. By using such a catalyst, there can be obtained a direct methanol fuel cell wherein high output is achieved by using high methanol concentration.

    摘要翻译: 公开了一种用于直接甲醇燃料电池的电解质膜 - 电极组件,其中固体聚合物电解质膜保持在一对电极之间,每对电极由涂覆在多孔支撑体上的和/或浸渍在多孔支撑体中的催化剂层组成。 该直接甲醇燃料电池用电解质膜 - 电极组件的特征在于,固体高分子电解质膜通过用辐射照射树脂膜并使自由基聚合性单体进行接枝聚合而获得。 用于直接甲醇燃料电池的电解质膜 - 电极组件的特征还在于,阳极电极的催化剂层包括催化剂,其中具有5nm或更小的粒径的铂族金属或含铂合金颗粒由碳负载 颗粒和固体聚合物电解质,并且阳极电极的催化剂层中的贵金属量不大于5mg / cm 2。 通过使用这样的催化剂,可以获得通过使用高甲醇浓度实现高产量的直接甲醇燃料电池。

    PROCESS FOR PRODUCING ELECTRODE CATALYST FOR FUEL CELL
    10.
    发明申请
    PROCESS FOR PRODUCING ELECTRODE CATALYST FOR FUEL CELL 失效
    生产燃料电极催化剂的方法

    公开(公告)号:US20100048388A1

    公开(公告)日:2010-02-25

    申请号:US12532176

    申请日:2008-02-28

    申请人: Shigeru Konishi

    发明人: Shigeru Konishi

    IPC分类号: H01M4/88

    摘要: This invention provides a process for producing an electrode catalyst for a fuel cell, comprising a first support step of producing metallic fine particles having an average particle diameter of 0.1 to 1.5 nm provided at regulated particle intervals on an electroconductive carbon carrier, and a second support step of growing a metal identical to or dissimilar to the metal using the metallic fine particles as a nucleus. In the first support step, the metallic fine particles are supported by an immersion method. The above constitution can provide an electrode catalyst for a fuel cell, which has a high level of percentage support, has a high level of dispersibility, and has improved methanol oxidation activity per weight of the catalyst. Further, when treatment in an atmosphere containing hydrogen is carried out at a low temperature below 100° C., the methanol oxidation activity per active surface area can be improved without lowering the active area.

    摘要翻译: 本发明提供了一种燃料电池用电极催化剂的制造方法,其特征在于,包括在导电性碳载体上以规定粒子间隔设置平均粒径为0.1〜1.5nm的金属微粒子的第一担载工序, 使用金属微粒作为核生长与金属相同或不相似的金属的步骤。 在第一支撑工序中,通过浸渍法支撑金属微粒。 上述结构可以提供一种燃料电池用电极催化剂,其具有高水平的载体百分比,具有高水平的分散性,并且每重量的催化剂具有改善的甲醇氧化活性。 此外,当在低于100℃的低温下进行含氢气氛的处理时,可以在不降低有效面积的情况下提高每活性表面积的甲醇氧化活性。