摘要:
An object of the present invention is to provide polypropylene adhesive excellent in both initial adhesion and adhesion after heat history; and a laminate excellent in adhesion and heat resistance. Provided is a polypropylene-based adhesive having an MFR of 2.7 g/10 min or higher as measured at 230° C. under a load of 2.16 kg, comprising a composition which contains 5-95 parts by weight of (A) an isotactic polypropylene, 95-5 parts by weight of (B) a propylene/ethylene random copolymer, and 0-40 parts by weight of (C) an ethylene/propylene random copolymer, wherein 100 parts by weight of the composition is graft modified with 0.001-5 parts by weight of an unsaturated carboxylic acid and/or a derivative thereof, and wherein (B) is characterized by the following (i) to (iii): (i) the propylene/ethylene random copolymer (B) contains 60-90 mol % units derived from propylene and 10-40 mol % units derived from ethylene; (ii) the melting point (Tm) as measured with a differential scanning calorimeter is in the range of 40-120° C.; and (iii) the molecular weight distribution (Mw/Mn) as determined by gel permeation chromatography (GPC) is in the range of 1.0-3.0.
摘要:
It is an object of the invention to provide polypropylene adhesives which have excellent adhesion to polar materials and exhibit particularly excellent adhesion after high-speed cast film processing, stretching or extrusion coating, and are excellent in blushing resistance, and multilayer structures having the adhesives.The adhesive resin composition is a grafted resin composition comprising a polypropylene component (A), an ethylene/propylene/α-olefin copolymer component (B), an ethylene/α-olefin copolymer component (C), and an unsaturated carboxylic acid and/or a derivative thereof (D), and which contains the component (A) at 5 to 80 parts by mass, the component (B) at 5 to 70 parts by mass and the component (C) at 1 to 40 parts by mass based on 100 parts by mass of the components (A), (B) and (C) combined and has an ethylene/propylene/α-olefin ratio in n-decane-soluble components of 5-95/5-95/1-50 mol % and a graft ratio of 0.01 to 5 wt %.
摘要:
It is an object of the invention to provide a carbodiimide modified polyolefin adhesive having excellent adhesive strength in a room temperature atmosphere and excellent adhesive strength in a high temperature atmosphere even in continuously molding with a practical molding machine. An adhesive (D), i.e., a carbodiimide modified polyolefin adhesive of the present invention which can solve the above problem is obtainable by allowing a polyolefin (A) having a group capable of reacting with a carbodiimide group to react with a carbodiimide group-containing compound (B) in the presence of an unmodified polyolefin (C) and having a ratio of a peak intensity at 2130 to 2140 cm−1 to a peak intensity at 1470 cm−1, as determined by infrared absorbance analysis, of not more than 60% and a density of 0.870 g/cm3 to 0.920 g/cm3. Furthermore, the use of the adhesive provides a laminate of a polar resin (F) and a polyolefin (G) having excellent interlaminar adhesive force both under a room temperature atmosphere and under a high temperature atmosphere.
摘要翻译:本发明的目的是提供一种在室温气氛下具有优异的粘合强度的碳二亚胺改性聚烯烃粘合剂,并且即使在用实际模塑机连续成型的情况下也能在高温气氛下具有优异的粘合强度。 可以通过使具有能够与碳二亚胺基团反应的基团的聚烯烃(A)与含碳二亚胺基团反应的粘合剂(D),即可解决上述问题的碳二亚胺改性聚烯烃粘合剂 化合物(B)在未改性的聚烯烃(C)的存在下,通过红外吸光度分析测定,其在2130至2140cm -1处的峰强度与1470cm -1处的峰强度的比率不大于 60%,密度为0.870g / cm 3至0.920g / cm 3。 此外,使用粘合剂在室温气氛下和高温气氛下提供具有优异的层间粘合力的极性树脂(F)和聚烯烃(G)的层压体。
摘要:
A propylene-based polymer composition for adhesive use and a laminate structure thereof are provided, wherein decrease of bonding strength is prevented when the laminate structure is formed and heat treatment is applied and whitening in bending process is suppressed. Provided are a propylene-based polymer composition (D) for adhesive use comprising (i) 40 to 92 wt % of a graft-modified polypropylene (A); (ii) 5 to 30 wt % of an ethylene.α-olefin copolymer (B) having a melt flow rate (MFR) of 0.01 to 10 g/10 min at 230° C. under a load of 2.16 kg and a density of 0.940 g/cm3 or less; and (iii) 3 to 30 wt % of a block copolymer (C) composed of an olefin crystalline segment and an ethylene.α-olefin segment, wherein the sum of (A), (B) and (C) is 100 wt %, and a laminate comprising at least one layer of the propylene-based polymer composition for adhesive use.
摘要:
A propylene-based polymer composition for adhesive use and a laminate structure thereof are provided, wherein decrease of bonding strength is prevented when the laminate structure is formed and heat treatment is applied and whitening in bending process is suppressed.Provided are a propylene-based polymer composition (D) for adhesive use comprising (i) 40 to 92 wt % of a graft-modified polypropylene (A); (ii) 5 to 30 wt % of an ethylene.α-olefin copolymer (B) having a melt flow rate (MFR) of 0.01 to 10 g/10 min at 230° C. under a load of 2.16 kg and a density of 0.940 g/cm3 or less; and (iii) 3 to 30 wt % of a block copolymer (C) composed of an olefin crystalline segment and an ethylene.α-olefin segment, wherein the sum of (A), (B) and (C) is 100 wt %, and a laminate comprising at least one layer of the propylene-based polymer composition for adhesive use.
摘要:
The modified polypropylene composition of the invention comprises (A) modified polypropylene having been partially or wholly graft modified with an unsaturated carboxylic acid or its derivative, (B) an amorphous or low-crystalline ethylene/&agr;-olefin copolymer having a specific MFR and a specific density and (C) a styrene elastomer, in a specific ratio. The component (A) is a graft modification product of a propylene homopolymer and/or a graft modification product of a propylene/&agr;-olefin random copolymer. The laminate of the invention comprises a composition layer comprising the modified polypropylene composition and a resin layer provided on one or both surfaces of the composition layer. By the use of the modified polypropylene composition as a laminate-forming composition or an adhesive resin composition, there can be obtained a laminate which has excellent interlaminar strength and which can be prevented from lowering of the interlaminar strength even if it is subjected to a heat treatment at a high temperature such as a temperature of 80 to 125° C.
摘要:
Provided is a polypropylene-based adhesive having an MFR of 2.7 g/10 min or higher, as measured at 230 ° C. under a load of 2.16 kg, comprising a composition which contains 5-95 parts by weight of (A) an isotactic polypropylene, 95-5 parts by weight of (B) a propylene/ethylene random copolymer, and 0-40 parts by weight of (C) an ethylene/propylene random copolymer, wherein 100 parts by weight of the composition is graft modified with 0.001-5 parts by weight of an unsaturated carboxylic acid and/or a derivative thereof, and wherein (B) is characterized by the following (i) to (iii): (i) the propylene/ethylene random copolymer (B) contains 60-90 mol % units derived from propylene and 10-40 mol % units derived from ethylene; (ii) the melting point (Tm) is in the range of 40-120 ° C.; and (iii) the molecular weight distribution (Mw/Mn) is in the range of 1.0-3.0.
摘要:
It is an object of the invention to provide polypropylene adhesives which have excellent adhesion to polar materials and exhibit particularly excellent adhesion after high-speed cast film processing, stretching or extrusion coating, and are excellent in blushing resistance, and multilayer structures having the adhesives. The adhesive resin composition is a grafted resin composition comprising a polypropylene component (A), an ethylene/propylene/α-olefin copolymer component (B), an ethylene/α-olefin copolymer component (C), and an unsaturated carboxylic acid and/or a derivative thereof (D), and which contains the component (A) at 5 to 80 parts by mass, the component (B) at 5 to 70 parts by mass and the component (C) at 1 to 40 parts by mass based on 100 parts by mass of the components (A), (B) and (C) combined and has an ethylene/propylene/α-olefin ratio in n-decane-soluble components of 5-95/5-95/1-50 mol % and a graft ratio of 0.01 to 5 wt %.
摘要:
In a coextrusion molding method, a laminate having excellent interlaminar adhesion strength with a fluorocopolymer is provided, and also a laminate which can be used more than enough even at high temperatures or in applications where the laminate comes into contact with oil, gasoline or the like by controlling various properties of the adhesive layer is provided.The laminate of the present invention is a laminate of at least two or more layers comprising a structure obtained by bonding and laminating an adhesive (A) defined by the following (i) to (iii) and a fluorocopolymer (B), wherein the adhesive (A) (i) is obtained by allowing a polyolefin (a) having a group reactive with a carbodiimide group to react with a compound (b) having a carbodiimide group, (ii) has a ratio of peak intensity at 2130 to 2140 cm−1 to peak intensity at 1470 cm−1 of 60% or lower in infrared absorption spectroscopy, and (iii) has a density of 0.870 to 0.940 g/cm3. In the formula (1), R1 and R2 each independently represent a hydrogen atom or fluorine atom. In the formula (2), R3 represents a substituent represented by CnH2n+1 (in which n is an integer of 1 or more).
摘要翻译:在共挤出成型方法中,提供了与含氟共聚物具有优异的层间粘合强度的层压体,以及即使在高温下也可以使用的层压体,或者在层压体与油,汽油等接触的应用中 通过控制粘合剂层的各种性质。 本发明的层压体是至少两层以上的层压体,其包含通过粘合和层压由下列(i)至(iii)限定的粘合剂(A)和含氟共聚物(B)而获得的结构,其中粘合剂 (A)(i)是通过使具有与碳二亚胺基反应的基团的聚烯烃(a)与具有碳二亚胺基的化合物(b)反应而获得的,(ii)峰强度的比例为2130〜2140cm -1在红外吸收光谱中在1470cm -1处的峰强度为60%以下,(iii)密度为0.870〜0.940g / cm 3。 在式(1)中,R 1和R 2各自独立地表示氢原子或氟原子。 在式(2)中,R 3表示由C n H 2n + 1表示的取代基(n为1以上的整数)。
摘要:
Provided is a new adhesive polyolefin resin composition, containing 1 to 100% by weight of a high polymer structure, that has good heat resistance and excellent adhesion performance to polyolefins and various polar materials, wherein a polyolefin segment (A) is bonded with an addition polymer segment (B) of a non-olefinic vinyl monomer and a reactive group is introduced into the addition polymer segment (B) and an adhesive or dispersion obtained therefrom.