公开(公告)号：US20110213189A1

公开(公告)日：2011-09-01

申请号：US13128215

申请日：2008-11-07

申请人： Yuji Mishima ,  Shinya Hirahara ,  Nobuaki Kodakari

发明人： Yuji Mishima ,  Shinya Hirahara ,  Nobuaki Kodakari

IPC分类号： C07C5/48 ,  B01J27/20 ,  B01J37/04 ,  B01J37/08

CPC分类号： B01J23/002 ,  B01J23/83 ,  B01J23/8872 ,  B01J2523/00 ,  C07C5/3332 ,  C07C5/3337 ,  C07C2523/83 ,  C07C2523/89 ,  C07C15/46 ,  B01J2523/13 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/842 ,  B01J2523/23 ,  B01J2523/68

摘要： A dehydrogenation catalyst composition for use in preparing an alkenyl aromatic compound by dehydrogenation of an alkyl aromatic compound, a method for preparing the catalyst, and a process for using the catalyst in a dehydrogenation reaction. Carbon dioxide (CO2) is present in the reaction in a molar ratio of 0.015 to 0.20 based on an aromatic compound in a material gas. The catalyst further includes an iron compound, an alkali metal, and about 13 to about 60 wt % of a rare earth element calculated as an oxide.

摘要翻译： 用于通过烷基芳族化合物脱氢制备链烯基芳族化合物的脱氢催化剂组合物，制备催化剂的方法，以及在脱氢反应中使用该催化剂的方法。 二氧化碳（CO 2）在反应中以相对于原料气体中的芳香族化合物为0.015〜0.20的摩尔比存在。 催化剂还包括铁化合物，碱金属和约13至约60重量％的以氧化物计算的稀土元素。

公开(公告)号：US08809609B2

公开(公告)日：2014-08-19

申请号：US13128215

申请日：2008-11-07

申请人： Yuji Mishima ,  Shinya Hirahara ,  Nobuaki Kodakari

发明人： Yuji Mishima ,  Shinya Hirahara ,  Nobuaki Kodakari

IPC分类号： C07C5/367

CPC分类号： B01J23/002 ,  B01J23/83 ,  B01J23/8872 ,  B01J2523/00 ,  C07C5/3332 ,  C07C5/3337 ,  C07C2523/83 ,  C07C2523/89 ,  C07C15/46 ,  B01J2523/13 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/842 ,  B01J2523/23 ,  B01J2523/68

摘要： A dehydrogenation catalyst composition for use in preparing an alkenyl aromatic compound by dehydrogenation of an alkyl aromatic compound, a method for preparing the catalyst, and a process for using the catalyst in a dehydrogenation reaction. Carbon dioxide (CO2) is present in the reaction in a molar ratio of 0.015 to 0.20 based on an aromatic compound in a material gas. The catalyst further includes an iron compound, an alkali metal, and about 13 to about 60 wt % of a rare earth element calculated as an oxide.

摘要翻译： 用于通过烷基芳族化合物脱氢制备链烯基芳族化合物的脱氢催化剂组合物，制备催化剂的方法，以及在脱氢反应中使用该催化剂的方法。 二氧化碳（CO 2）在反应中以相对于原料气体中的芳香族化合物为0.015〜0.20的摩尔比存在。 催化剂还包括铁化合物，碱金属和约13至约60重量％的以氧化物计算的稀土元素。

公开(公告)号：US20070078055A1

公开(公告)日：2007-04-05

申请号：US11529287

申请日：2006-09-29

申请人： Hiroshi Takeda ,  Shinya Hirahara

发明人： Hiroshi Takeda ,  Shinya Hirahara

IPC分类号： B01J23/755

CPC分类号： B01J23/755 ,  B01J33/00 ,  B01J37/14

摘要： To provide a method of stabilizing a catalyst enabling the stabilization to be completed in a very short period of time by means of a simple process, particularly a method of stabilizing a reduced Ni-containing catalyst. [Solution]A method of stabilizing a reduced Ni-containing catalyst, where gas in which three kinds of 02, 1120, and CO2 coexist, or gas in which four kinds of 02, 1120, CO2, and inert gas coexist is introduced into the reduced Ni-containing catalyst at a temperature of not less than 0.1° C., and of less than 100° C. will make it possible to prepare a stable catalyst even in the air.

摘要翻译： 为了提供使催化剂稳定化的方法，使得能够通过简单的方法，特别是稳定还原的含Ni催化剂的方法在非常短的时间内完成稳定化。 [解决方案]将三种O 2，1120和CO 2共存的气体或其中四种O 2，1120，CO 2和惰性气体共存的气体引入到其中的将Ni还原催化剂稳定化的方法 在不低于0.1℃和小于100℃的温度下还原的含Ni催化剂将使得甚至可以在空气中制备稳定的催化剂成为可能。