摘要:
A process of manufacturing inorganic nanofibers, without using an organic polymer, using a highly reactive metal alkoxide such as titanium alkoxide or zirconium alkoxide, in particular, a process in which inorganic nanofibers can be stably produced over a long period, is provided. It is a process of manufacturing inorganic nanofibers by electrospinning using a sol solution containing an inorganic component as a main component, characterized in that the sol solution contains a metal alkoxide having a high reactivity and a salt catalyst, and that the salt catalyst is an amine compound having an N—N bond, an N—O bond, an N—C═N bond, or an N—C═S bond.
摘要:
A process of manufacturing inorganic nanofibers, without using an organic polymer, using a highly reactive metal alkoxide such as titanium alkoxide or zirconium alkoxide, in particular, a process in which inorganic nanofibers can be stably produced over a long period, is provided. It is a process of manufacturing inorganic nanofibers by electrospinning using a sol solution containing an inorganic component as a main component, characterized in that the sol solution contains a metal alkoxide having a high reactivity and a salt catalyst, and that the salt catalyst is an amine compound having an N—N bond, an N—O bond, an N—C═N bond, or an N—C═S bond.
摘要:
A process for manufacturing organic fibers containing an inorganic component comprising the steps of: (1) preparing an inorganic spinnable sol solution; (2) mixing the inorganic spinnable sol solution, a solvent capable of dissolving the inorganic spinnable sol solution, and an organic polymer capable of being dissolved in the solvent to prepare a spinning solution; and (3) spinning the spinning solution to form the organic fibers containing an inorganic component composed of an inorganic gel and the organic polymer, is disclosed. The inorganic spinnable sol solution preferably has a weight average molecular weight of 10,000 or more, and the inorganic spinnable sol solution is preferably prepared from a material containing a metal alkoxide having an organic substituent. According to the process of the present invention, organic fibers containing an inorganic component having an improved mechanical strength can be produced by mixing an inorganic component into an organic component, and a nonwoven fabric containing the fibers can be provided.
摘要:
A nonwoven fabric prepared from fibers which are not substantially fibrillated and have a diameter of less than 20 &mgr;m, by fusing a fiber web comprising fine fibers having a diameter of 4 &mgr;m or less, and adhesive fibers having a diameter ranging from 8 &mgr;m to less than 20 &mgr;m, wherein a maximum pore size in the nonwoven fabric is not more than twice a mean flow pore size of the nonwoven fabric is disclosed.
摘要:
An inorganic fiber structure comprising inorganic nanofibers having an average fiber diameter of 3 μm or less, in which an entirety including the inside thereof is adhered with an inorganic adhesive, and the porosity thereof is 90% or more, is disclosed. Furthermore, a process for producing an inorganic fiber structure is disclosed, which includes (i) a step of spinning inorganic fibers by an electrospinning method, from a spinning inorganic sol solution containing a compound mainly composed of an inorganic component; (ii) a step of forming an inorganic fiber aggregate by irradiating the inorganic fibers with ions having a polarity opposite to that of the inorganic fibers to accumulate the inorganic fibers; and (iii) a step of forming an inorganic fiber structure adhering to the inorganic fiber aggregate with an inorganic adhesive in an entirety including the inside thereof, in which an adhering inorganic sol solution containing a compound mainly composed of an inorganic component is imparted to an entirety including the inside of the inorganic fiber aggregate, and an excess adhering inorganic sol solution is removed by gas-through.
摘要:
A process for manufacturing an inorganic material-based article comprising the steps of (1) forming a sol solution mainly composed of an inorganic component, (2) producing inorganic material-based gel fine fibers by extruding the resulting sol solution from a nozzle, and at the same time, applying an electrical field to the extruded sol solution to thin the extruded sol solution, and then, collecting inorganic material-based gel fine fibers on a support, (3) drying the collected inorganic material-based gel fine fibers to produce inorganic material-based article containing inorganic material-based dried gel fine fibers, and then, (4) sintering the inorganic material-based article containing inorganic material-based dried gel fine fibers to produce inorganic material-based article containing inorganic material-based sintered fine fibers.
摘要:
A nonwoven fabric prepared from fibers which are not substantially fibrillated and have a diameter of less than 20 &mgr;m, by fusing a fiber web comprising fine fibers having a diameter of 4 &mgr;m or less, and adhesive fibers having a diameter ranging from 8 &mgr;m to less than 20 &mgr;m, wherein a maximum pore size in the nonwoven fabric is not more than twice the mean flow pore size of the nonwoven fabric is disclosed.
摘要:
A process for manufacturing organic fibers containing an inorganic component comprising the steps of: (1) preparing an inorganic spinnable sol solution; (2) mixing the inorganic spinnable sol solution, a solvent capable of dissolving the inorganic spinnable sol solution, and an organic polymer capable of being dissolved in the solvent to prepare a spinning solution; and (3) spinning the spinning solution to form the organic fibers containing an inorganic component composed of an inorganic gel and the organic polymer, is disclosed. The inorganic spinnable sol solution preferably has a weight average molecular weight of 10,000 or more, and the inorganic spinnable sol solution is preferably prepared from a material containing a metal alkoxide having an organic substituent. According to the process of the present invention, organic fibers containing an inorganic component having an improved mechanical strength can be produced by mixing an inorganic component into an organic component, and a nonwoven fabric containing the fibers can be provided.
摘要:
An inorganic fiber structure comprising inorganic nanofibers having an average fiber diameter of 3 μm or less, in which an entirety including the inside thereof is adhered with an inorganic adhesive, and the porosity thereof is 90% or more, is disclosed. Furthermore, a process for producing an inorganic fiber structure is disclosed, which includes (i) a step of spinning inorganic fibers by an electrospinning method, from a spinning inorganic sol solution containing a compound mainly composed of an inorganic component; (ii) a step of forming an inorganic fiber aggregate by irradiating the inorganic fibers with ions having a polarity opposite to that of the inorganic fibers to accumulate the inorganic fibers; and (iii) a step of forming an inorganic fiber structure adhering to the inorganic fiber aggregate with an inorganic adhesive in an entirety including the inside thereof, in which an adhering inorganic sol solution containing a compound mainly composed of an inorganic component is imparted to an entirety including the inside of the inorganic fiber aggregate, and an excess adhering inorganic sol solution is removed by gas-through.