Amorphous carbon electrode and a secondary battery having such an
electrode
    3.
    发明授权
    Amorphous carbon electrode and a secondary battery having such an electrode 失效
    无定形碳电极和具有这种电极的二次电池

    公开(公告)号:US5773167A

    公开(公告)日:1998-06-30

    申请号:US657269

    申请日:1996-06-03

    CPC分类号: H01M4/587 H01M10/0525

    摘要: An amorphous carbon material, especially for an electrode of a lithium ion secondary battery, is characterized by an interlayer spacing d(002), obtained from the X-ray diffraction line assigned to the (002) plane of the carbon, of 0.345 nm to 0.365 nm, a ratio (Ps) os the number of carbon atoms involved in the layer structure to the total number of carbon atoms of from 0.54 to 0.85, and a ratio of the total nitrogen:total carbon atoms in the amorphous carbon of 0.005:1 to 0.055:1. The amorphous carbon material is prepared by applying a heat treatment to an amorphous carbon under under vacuum or inert gas atmosphere for at least 30 minutes to provide the desired crystalline structure. The carbon material may take the form of carbon fiber material, especially short carbon fibers obtained by pulverizing larger carbon fibers. A lithium ion secondary battery containing an electrode comprising such an amorphous carbon material has a large discharge capacity and high charge-discharge cycle characteristics.

    摘要翻译: 特别是锂离子二次电池用电极的无定形碳材料的特征在于,将从分配给(002)面的X射线衍射线得到的层间距d(002)为0.345nm〜 0.363nm,层结构中涉及的碳原子数与碳原子总数的比例(Ps)为0.54〜0.85,无定形碳中的总氮:总碳原子数的比例为0.005: 1至0.055:1。 通过在真空或惰性气体气氛下对非晶碳进行热处理至少30分钟制备无定形碳材料,以提供所需的晶体结构。 碳材料可以采取碳纤维材料的形式,特别是通过粉碎较大的碳纤维获得的短碳纤维。 包含这种无定形碳材料的电极的锂离子二次电池具有大的放电容量和高的充放电循环特性。