Process for synthesis of N,N-disubstituted hydrazone
    1.
    发明授权
    Process for synthesis of N,N-disubstituted hydrazone 失效
    合成N,N-二取代腙的方法

    公开(公告)号:US4990625A

    公开(公告)日:1991-02-05

    申请号:US445930

    申请日:1989-12-05

    CPC classification number: C07C249/16 C07D209/86 G03G5/0616

    Abstract: A process for synthesizing an N,N-disubstituted hydrazone comprises carrying out nitrozation by adding an aqueous solution of sodium nitrite to a solution having one part by weight of an N,N-disubstituted amine dissolved in 3 to 30 parts by weight of an organic acid, then reducing the nitrozated product to an N,N-disubstituted hydrazine by adding a reducing agent to the mixture containing the nitrozated product, and thereafter adding to the mixture containing the N,N-disubstituted hydrazine a carbonyl compound of the formula: ##STR1## wherein A represents an aromatic hydrocarbon group or an aromatic heterocyclic group which may have a substituent, B represents a hydrogen atom, an alkyl group, an aryl group or an aromatic heterocyclic group, which may have a substituent, thereby performing condensation of the N,N-disubstituted hydrazine with the carbonyl compound.

    Abstract translation: 合成N,N-二取代腙的方法包括通过将亚硝酸钠水溶液加入到溶解有3重量份的N,N-二取代胺的溶液中进行硝化,所述N,N-二取代胺溶解在3-30重量份的有机 然后通过向含有硝基化产物的混合物中加入还原剂将硝化产物还原成N,N-二取代的肼,然后向含有N,N-二取代肼的混合物中加入下式的羰基化合物: 其中A表示可以具有取代基的芳香族烃基或芳香族杂环基,B表示可以具有取代基的氢原子,烷基,芳基或芳香族杂环基,由此进行 N,N-二取代肼与羰基化合物。

    Recording medium and process employing a photosensitive organic film
    3.
    发明授权
    Recording medium and process employing a photosensitive organic film 失效
    记录介质和采用光敏有机膜的工艺

    公开(公告)号:US4501808A

    公开(公告)日:1985-02-26

    申请号:US526533

    申请日:1983-08-25

    Abstract: An organic film comprising at least one compound of the following formulae (1)-(5): ##STR1## wherein R.sub.11 and R.sub.13 each represent substituted or unsubstituted aryl, R.sub.12 represents substituted or unsubstituted arylene, and A.sup..crclbar. represents an anionic residue; ##STR2## wherein R.sub.21, R.sub.22, and R.sub.24 each represent substituted or unsubstituted aryl, R.sub.23 represents substituted or unsubstituted arylene, and A.sup..crclbar. represents an anionic residue; ##STR3## wherein R.sub.31, R.sub.33, and R.sub.35 each represent substituted or unsubstituted aryl, R.sub.32 and R.sub.34 each represent substituted or unsubstituted arylene, and A.sup..crclbar. represents an anionic residue; ##STR4## wherein R.sub.41 represents alkyl, substituted or unsubstituted phenyl, or substituted or unsubstituted styryl, R.sub.42 represents substituted or unsubstituted arylene, R.sub.43 represents substituted or unsubstituted aryl, and A.sup..crclbar. represents an anionic residue; and ##STR5## wherein R.sub.51 represents alkoxy, R.sub.52 represents alkyl, R.sub.53 represents substituted or unsubstituted arylene, R.sub.54 represents substituted or unsubstituted aryl, A.sup..crclbar. represents an anionic residue, and n represents an integer of 1 or 2.

    Abstract translation: 包含至少一种下式(1) - (5)的化合物的有机膜:其中R11和R13各自表示取代或未取代的芳基,R12表示取代或未取代的亚芳基,A( - )表示 阴离子残基; (2)其中R21,R22和R24各自表示取代或未取代的芳基,R23表示取代或未取代的亚芳基,A( - )表示阴离子残基; (3)其中R 31,R 33和R 35各自表示取代或未取代的芳基,R 32和R 34各自表示取代或未取代的亚芳基,A( - )表示阴离子残基; (4)其中R41表示烷基,取代或未取代的苯基或取代或未取代的苯乙烯基,R42表示取代或未取代的亚芳基,R43表示取代或未取代的芳基,A( - )表示阴离子残基; (5)其中R51表示烷氧基,R52表示烷基,R53表示取代或未取代的亚芳基,R54表示取代或未取代的芳基,A( - )表示阴离子残基,n表示1或2的整数。

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