摘要:
A lithium secondary battery includes an electrode body containing a positive electrode and a negative electrode, a non-aqueous electrolytic solution, and a battery case in which the electrode body and the non-aqueous electrolytic solution are housed, wherein the positive electrode includes a positive electrode active material particle of a hollow structure having a shell portion formed of a lamellar lithium transition metal oxide and a hollow portion formed therein, the long diameter of a primary particle of the lithium transition metal oxide based on SEM observation is 1 μm or less, the thickness of the shell portion based on SEM observation is 2 μm or less, the negative electrode is provided with a negative electrode active material particle formed of a carbon material, and a krypton adsorption amount of the negative electrode active material particle is 3.5 m2/g or greater but 4 m2/g or less.
摘要:
Electrode active material that is used together with an electrolyte solution having an electrolyte decomposition potential Ve is represented by the general expression LixFeMyO2 and is amorphous. In the expression, x and y are values which independently satisfy 1
摘要:
A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode having, on a surface thereof, a negative electrode mixture layer containing a negative electrode active material, a thickening agent and a binder, and a separator. The positive electrode and the negative electrode are coiled together with the separator therebetween. The negative electrode active material has an average particle size of at least 5 μm and not more than 20 μm and has a fines content, defined as the cumulative frequency of the negative electrode active material having a particle size of 3 μm or less, of at least 10% and not more than 50%. The thickening agent has a 1.0% aqueous solution viscosity of at least 4,980 mPa·s. The negative electrode mixture layer is in an unpressed state.
摘要:
A non-aqueous electrolyte secondary battery includes a mixture layer of a negative electrode. The mixture layer contains carboxymethyl cellulose. A product of a median diameter (μm) of a negative electrode active material contained in the negative electrode and a ratio of a weight (wt %) of the carboxymethyl cellulose adsorbed on the negative electrode active material to a weight of the negative electrode active material is not less than 2.2 and not larger than 4.2.
摘要:
A lithium-ion secondary battery includes a positive electrode plate, a negative electrode plate, and a separator. The positive electrode plate includes a positive electrode collector plate and a positive electrode active material layer formed on the surface of the positive electrode collector plate. The negative electrode plate includes a negative electrode collector plate and a negative electrode active material layer formed on the surface of the negative electrode collector plate. The separator is disposed between the positive electrode plate and the negative electrode plate. The positive electrode plate, the negative electrode plate, and the separator are stacked and wound, and each of them includes a flat portion disposed along a plane and bearing an external load and a curved portion formed to be curved. The positive electrode active material layer includes a flat region corresponding to the flat portion and a curved region corresponding to the curved portion. The density of the positive electrode active material layer in at least a portion of the curved region is higher than the density of the positive electrode active material layer in the flat region.