公开(公告)号：US06835420B1

公开(公告)日：2004-12-28

申请号：US10049606

申请日：2002-02-14

申请人： Ulrike Röckrath ,  Hubert Baumgart ,  Andrea Zumbrink ,  Stefan Silber ,  Thomas Farwick

发明人： Ulrike Röckrath ,  Hubert Baumgart ,  Andrea Zumbrink ,  Stefan Silber ,  Thomas Farwick

IPC分类号： B05D136

CPC分类号： C09D183/10 ,  C08F290/148

摘要： The invention relates to a coating material which can be hardened thermally and, optionally, by using actinic radiation. Said coating material contains: A) a binding agent comprising at least two functional groups (a1) which can enter into thermal cross-linking reactions with complementary functional groups (b1) in cross-linking agent (B), and; (B) at least one cross-linking agent comprising at least two functional groups (b1) which can enter into thermal cross-linking reactions with complementary functional groups (a1) in binding agent (A). At least one binding agent (A) contains, in an integrally polymerized manner, at least one olefinically unsaturated polysiloxane macromonomer which contains, in the statistical mean, at least 3.0 double bonds per molecule. The invention also relates to the use of the coating material for producing highly scratch resistant multilayer transparent lacquers.

摘要翻译： 本发明涉及可以热和任选地通过使用光化辐射来硬化的涂层材料。 所述涂料含有：A）包含至少两个可与交联剂（B）中的互补官能团（b1）进行热交联反应的官能团（a1）的粘合剂， （B）至少一种包含至少两个官能团（b1）的交联剂，其可与粘合剂（A）中的互补官能团（a1）进行热交换反应。 至少一种结合剂（A）以整体聚合的方式含有至少一种烯属不饱和聚硅氧烷大分子单体，其在统计学意义上包含每个分子至少3.0个双键。 本发明还涉及涂覆材料用于生产高耐划伤多层透明漆的用途。

公开(公告)号：US07423077B2

公开(公告)日：2008-09-09

申请号：US10543274

申请日：2004-01-20

申请人： Guido Wilke ,  Vince Cook ,  Thomas Farwick

发明人： Guido Wilke ,  Vince Cook ,  Thomas Farwick

IPC分类号： C08K5/34

CPC分类号： C08G18/808 ,  C08G18/6283 ,  C09D133/14 ,  C08L2666/20

摘要： Coating materials, processes for preparing them, and their use. The coating materials include hydroxyl-containing (meth)acrylate (co)polymer, carbamate- and hydroxyl-functional compound, an amino resin, and a triazine compound. At least 10 equivalent % of the hydroxyl groups present in (A) and/or (B) are primary hydroxyl groups. The coating materials after curing have a storage modulus E′ in the rubber-elastic range of at least 1.5*107 Pa, the storage modulus E′ having been measured by dynamic mechanical thermoanalysis (DMTA) on homogeneous free films with a thickness of 40±10 μm.

摘要翻译： 涂料，其制备方法及其用途。 涂层材料包括含羟基的（甲基）丙烯酸酯（共）聚合物，氨基甲酸酯和羟基官能化合物，氨基树脂和三嗪化合物。 存在于（A）和/或（B）中的至少10当量的羟基是伯羟基。 固化后的涂料在橡胶弹性范围内具有至少1.5×10 7 Pa的储能模量E'，储能模量E'通过动态机械热分析（DMTA）在均相上测量 厚度为40±10um的自由膜。

公开(公告)号：US20060142440A1

公开(公告)日：2006-06-29

申请号：US10543274

申请日：2004-01-20

申请人： Guido Wilke ,  Vincent Cook ,  Thomas Farwick

发明人： Guido Wilke ,  Vincent Cook ,  Thomas Farwick

IPC分类号： C08K5/34

CPC分类号： C08G18/808 ,  C08G18/6283 ,  C09D133/14 ,  C08L2666/20

摘要： Coating materials, processes for preparing them, and their use. The coating materials include hydroxyl-containing (meth)acrylate (co)polymer, carbamate and hydroxyl-functional compound, an amino resin, and a triazine compound. At least 10 equivalent % of the hydroxyl groups present in (A) and/or (B) are primary hydroxyl groups. The coating materials after curing have a storage modulus E′ in the rubber-elastic range of at least 1.5*107 Pa, the storage modulus E′ having been measured by dynamic mechanical thermoanalysis (DMTA) on homogeneous free films with a thickness of 40±10 μm.

摘要翻译： 涂料，其制备方法及其用途。 涂层材料包括含羟基的（甲基）丙烯酸酯（共）聚合物，氨基甲酸酯和羟基官能化合物，氨基树脂和三嗪化合物。 存在于（A）和/或（B）中的至少10当量的羟基是伯羟基。 固化后的涂料在橡胶弹性范围内具有至少1.5×10 7 Pa的储能模量E'，储能模量E'通过动态机械热分析（DMTA）在均相上测量 厚度为40±10um的自由膜。

公开(公告)号：US20060116488A1

公开(公告)日：2006-06-01

申请号：US10541530

申请日：2003-11-19

申请人： Hubert Baumgart ,  Vincent Cook ,  Thomas Farwick ,  Sandra Hasse ,  Peter Mayenfels ,  Guido Schulze-Finkenbrink

发明人： Hubert Baumgart ,  Vincent Cook ,  Thomas Farwick ,  Sandra Hasse ,  Peter Mayenfels ,  Guido Schulze-Finkenbrink

IPC分类号： C08G18/06 ,  C08G18/00

CPC分类号： C08G18/792 ,  C08G18/6254 ,  C08G18/6283 ,  C08L61/28 ,  C09D175/04 ,  C08L2666/16

摘要： A multicomponent system comprising (I) a component comprising (A) an oligomer and/or polymer containing allophanate groups and/or carbamate groups, (B) an oligomer and/or polymer containing isocyanate-reactive functional groups, (C) a partly or fully alkylated amino resin, and (D) a compound containing groups which can be activated with actinic radiation; and (II) a component comprising (E) a polyisocyanate, with the proviso that the equivalents ratio of isocyanate groups in component (II) to isocyanate-reactive functional groups in component (I) is from 0.2:1 to 1:0.2 and the equivalents ratio of allophanate groups and/or carbamate groups in the oligomer and/or polymer (A) to the N-methylol ether groups or the N-methylol and N-methylol ether groups in the amino resin (C) is from 0.2:1 to 1:0.2; and its use to produce mixtures curable thermally and with actinic radiation.

摘要翻译： 一种多组分体系，其包含（I）包含（A）含有脲基甲酸酯基和/或氨基甲酸酯基团的低聚物和/或聚合物的组分，（B）含异氰酸酯反应性官能团的低聚物和/或聚合物，（C）部分或 完全烷基化的氨基树脂，和（D）可以用光化辐射活化的基团的化合物; 和（II）包含（E）多异氰酸酯的组分，条件是组分（II）中异氰酸酯基团与组分（I）中异氰酸酯反应性官能团的当量比为0.2:1至1:0.2， 低聚物和/或聚合物（A）中氨基甲酸酯基和/或氨基甲酸酯基与氨基树脂（C）中的N-羟甲基醚基或N-羟甲基和N-羟甲基醚基的当量比为0.2:1 至1:0.2; 以及其用于产生可热固化和与光化辐射固化的混合物的用途。

公开(公告)号：US20070054999A1

公开(公告)日：2007-03-08

申请号：US10558897

申请日：2004-05-21

申请人： Cornelia Ketteler ,  Thomas Farwick ,  Vincent Cook

发明人： Cornelia Ketteler ,  Thomas Farwick ,  Vincent Cook

IPC分类号： C08L91/06

CPC分类号： C09K3/10 ,  C09D7/47 ,  C09K2200/0625 ,  C09K2200/0667

摘要： The invention relates to coating substances that are free of hiding pigments, contain solvents and are cured thermally or with actinic radiation and also contain at least on of: low molecular mass, oligomeric and polymeric binders, crosslinking agents and reactive diluents that are curable thermally, with actinic radiation, or both thermally and with actinic radiation together with dispersed synthetic polyamide wax particles. The invention also relates to processes for preparing said coatings, and single-coat and multicoat clearcoat systems and multicoat color and/or effect paint systems or adhesives and sealants prepared from said substances.

摘要翻译： 本发明涉及不含隐藏颜料，含有溶剂并且被热或用光化辐射固化的涂层物质，并且还含有至少一种：低分子量，低​​聚和聚合物粘合剂，可热固化的交联剂和反应性稀释剂， 具有光化辐射，或热和光化辐射两者以及分散的合成聚酰胺蜡颗粒。 本发明还涉及制备所述涂层的方法，以及由所述物质制备的单涂层和多色透明涂层体系以及多色彩和/或效果涂料体系或粘合剂和密封剂。

公开(公告)号：US06652919B1

公开(公告)日：2003-11-25

申请号：US09890760

申请日：2001-08-02

申请人： Donald H. Campbell ,  Hubert Baumgart ,  Thomas Farwick ,  Ulrike Röckrath

发明人： Donald H. Campbell ,  Hubert Baumgart ,  Thomas Farwick ,  Ulrike Röckrath

IPC分类号： C08G1810

CPC分类号： B05D7/574 ,  B05D7/577 ,  C09D175/04 ,  Y10T428/31551

摘要： A highly scratch-resistant multicoat paint system on a primed or unprimed substrate, comprising above one another in this order (A) a basecoat, (B) a first clearcoat as intermediate coat, and (C) a second clearcoat as the topmost coat, wherein the second clearcoat (C) is producible from a coating coating material (C) comprising (C1) at least one oligomer and/or polymer containing at least one pendant carbamate and/or allophanate group (c11), especially carbamate group (c11), of the formula: —O—(CO)—NH2—O—(CO)—NH—(CO)—NH2  and (C2) at least one crosslinking agent containing at least two functional groups (c21) which undergo crosslinking reactions with the carbamate group and/or allophanate group (c11); and also a process for producing highly scratch-resistant multicoat systems.

摘要翻译： 在底漆或未底漆基材上的高度耐刮擦的多色漆系统，其顺序包括（A）底漆，（B）第一透明涂层作为中间涂层，和（C）作为最上层涂层的第二透明涂层， 其中所述第二透明涂层（C）可由包含（C1）至少一种含有至少一个氨基甲酸酯和/或脲基甲酸酯基（c11），特别是氨基甲酸酯基（c11）的至少一种低聚物和/或聚合物的涂层涂料（C） ，和（C2）至少一种含有至少两个与氨基甲酸酯基和/或脲基甲酸酯基团（c11）发生交联反应的官能团（c21）的交联剂;以及用于生产高耐划伤性的方法 多点系统

公开(公告)号：US20060173120A1

公开(公告)日：2006-08-03

申请号：US10543330

申请日：2004-01-20

申请人： Hubert Baumgart ,  Annette Roters ,  Vincent Cook ,  Thomas Farwick ,  Sandra Hasse ,  Cornelia Ketteler ,  Ulrike Rockrath

发明人： Hubert Baumgart ,  Annette Roters ,  Vincent Cook ,  Thomas Farwick ,  Sandra Hasse ,  Cornelia Ketteler ,  Ulrike Rockrath

IPC分类号： C09B67/00

CPC分类号： C08G18/80 ,  C09D133/14 ,  C08L2666/20

摘要： Coating materials including at least one hydroxyl-containing (meth)acrylate (co)polymer, at least one carbamate- and hydroxyl-containing compound and at least one amino resin, where at least 10 equivalent % of the hydroxyl groups present in the (meth)acrylate (co)polymers and/or the carbamate and hydroxyl containing compound are primary hydroxyl groups. The coating materials after curing have a storage modulus E′ in the rubber-elastic range of at least 1.5*107 Pa, the storage modulus E′ having been measured by dynamic mechanical thermoanalysis (DMTA) on homogeneous free films with a thickness of 40±10 μm. Also included is a processes for preparing the coating materials and applications therefor.

摘要翻译： 包含至少一种含羟基的（甲基）丙烯酸酯（共）聚合物，至少一种含氨基甲酸酯和羟基的化合物和至少一种氨基树脂的涂料，其中至少10当量的羟基存在于（甲基） ）丙烯酸酯（共）聚合物和/或含氨基甲酸酯和羟基的化合物是伯羟基。 固化后的涂料在橡胶弹性范围内具有至少1.5×10 7 Pa的储能模量E'，储能模量E'通过动态机械热分析（DMTA）在均相上测量 厚度为40±10um的自由膜。 还包括制备涂料及其应用的方法。

公开(公告)号：US06630211B1

公开(公告)日：2003-10-07

申请号：US09913588

申请日：2001-10-04

申请人： Hubert Baumgart ,  Heinz-Peter Rink ,  Ulrike Röckrath ,  Thomas Farwick

发明人： Hubert Baumgart ,  Heinz-Peter Rink ,  Ulrike Röckrath ,  Thomas Farwick

IPC分类号： B32B2728

CPC分类号： B05D7/53 ,  B05D7/57 ,  C08K5/05 ,  C09D7/63 ,  Y10T428/31504 ,  Y10T428/31551 ,  Y10T428/31935

摘要： The invention relates to the utilization of tricyclodecandimethanol for producing multilayer lacquers, in particular, multilayer transparent lacquer coatings, and as a binding agent in multilayer lacquers. The invention als relates to a coating substrance, especially transparent lacquer, containing at least one binding agent, at least one cross-linking agent and tricylodecandimethanol. In addition, the invention relates to a method for improving the adherence of the intermediate layer in multilayer transparent lacquer coatings.

摘要翻译： 本发明涉及三环癸二醇用于生产多层漆，特别是多层透明漆涂料以及作为多层漆中粘合剂的应用。 本发明涉及含有至少一种结合剂，至少一种交联剂和三氯甲烷二甲醇的涂层下层，特别是透明漆。 另外，本发明涉及一种改善多层透明漆涂层中间层粘附性的方法。

公开(公告)号：US06534185B1

公开(公告)日：2003-03-18

申请号：US09807711

申请日：2001-06-18

申请人： Hubert Baumgart ,  Thomas Farwick ,  Ulrich Poth ,  Ulrike Röckrath ,  Andrea Zumbrink

发明人： Hubert Baumgart ,  Thomas Farwick ,  Ulrich Poth ,  Ulrike Röckrath ,  Andrea Zumbrink

IPC分类号： B32B900

CPC分类号： C09D151/08 ,  C08F290/068 ,  C09D151/085 ,  Y10T428/31663 ,  C08L2666/02

摘要： A coating composition comprising A) at least one hydroxyl-containing polyacrylate containing in copolymerized form at least one polysiloxane macromonomer as binder and B) at least one tris(alkoxycarbonylamino)triazine as crosslinking agent, and its use to produce multicoat clearcoats and multicoat topcoats.

摘要翻译： 一种涂料组合物，其包含至少一种含共聚形式的至少一种含羟基的聚丙烯酸酯，所述聚丙烯酸酯含有至少一种聚硅氧烷大分子单体作为粘合剂，和B）至少一种作为交联剂的三（烷氧基羰基氨基）三嗪，以及其用于生产多色透明涂层和多层面漆的用途。

公开(公告)号：US06274660B1

公开(公告)日：2001-08-14

申请号：US09243948

申请日：1999-02-03

申请人： Edgar Zeller ,  Peter Schwab ,  Peter-Heinz Rink ,  Hubert Baumgart ,  Edeltraud Hagemeister ,  Thomas Farwick

发明人： Edgar Zeller ,  Peter Schwab ,  Peter-Heinz Rink ,  Hubert Baumgart ,  Edeltraud Hagemeister ,  Thomas Farwick

IPC分类号： B05D302

CPC分类号： C03C17/32 ,  C08G18/62 ,  C09D175/14

摘要： The present invention relates to a coating composition featuring increased solids contents, which comprises at least one polyol I obtainable by subjecting at least one oligomer of the general formula I R1R2C═[═CH—R—CH═]n—CR3R4  (I) in which R=—(—CH2—)m—, in which the index m is an integer from 2 to 6, or in which X=—CH2— or an oxygen atom R1,R2,R3 and R4 independently of one another=hydrogen atoms or alkyl; and the index n=an integer from 1 to 15; to hydroformylation and reducing the resultant aldehyde-functional products I to give the polyols I, which, if desired, are subjected to partial or complete hydrogenation.

摘要翻译： 本发明涉及具有增加的固体含量的涂料组合物，其包含至少一种多元醇I，其通过使至少一种通式Iin的低聚物R 1 - （ - CH 2 - ）m - ，其中指数m为 2至6的整数，其中X = -CH 2 - 或氧原子R 1，R 2，R 3和R 4彼此独立地为氢原子或烷基; 并且指数n = 1至15的整数;加氢甲酰化并还原所得的醛官能产物I，得到多元醇I，如果需要，其进行部分或完全氢化。