公开(公告)号：US08841443B2

公开(公告)日：2014-09-23

申请号：US13821523

申请日：2010-09-13

Applicant: Mingjie Zhou ,  Jie Huang ,  Yijin Liu

Inventor： Mingjie Zhou ,  Jie Huang ,  Yijin Liu

IPC: C07D487/22 ,  C07F1/08 ,  C07F7/08 ,  C07F15/06 ,  C07F7/22 ,  C08G61/12 ,  C07F3/06 ,  C07F15/02 ,  C07F3/08 ,  H01L51/42 ,  H01L51/00 ,  H01L51/50

CPC classification number: C07F7/0816 ,  B82Y10/00 ,  C07D487/22 ,  C07F1/08 ,  C07F3/06 ,  C07F3/08 ,  C07F7/2284 ,  C07F15/025 ,  C07F15/065 ,  C08G61/124 ,  C08G2261/124 ,  C08G2261/144 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/3221 ,  C08G2261/3244 ,  C08G2261/37 ,  C08G2261/411 ,  C08G2261/51 ,  C08G2261/91 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/0083 ,  H01L51/009 ,  H01L51/0091 ,  H01L51/0092 ,  H01L51/0094 ,  H01L51/424 ,  H01L51/5016 ,  Y02E10/549 ,  Y02P70/521

Abstract: A silafluorene metalloporphyrin- benzene organic semiconductor material and preparing method and uses thereof are provided. The structure of the silafluorene metalloporphyrin- benzene organic semiconductor material is defined by structure formula (I): wherein: n is an integer between 1 and 100, R1, R2, R3, R4 are H, alkyl with C1-C32, phenyl, alkyl benzene or alkoxyl benzene containing one or more C1-C32, M is a metal ion. The silafluorene metalloporphyrin- benzene organic semiconductor material has good solubility, high carrier mobility, strong absorbance, wide absorbent range to light and elevated utilization ratio of solar light. Besides, the process of the preparing method is simple and easy to operate and control.

Abstract translation: 提供了一种硅芴金属卟啉 - 苯有机半导体材料及其制备方法和用途。 硅芴金属卟啉 - 苯有机半导体材料的结构由结构式（I）定义：其中：n是1和100之间的整数，R1，R2，R3，R4是H，具有C1-C32的烷基，苯基，烷基 含有一个或多个C 1 -C 32的苯或烷氧基苯，M是金属离子。 硅芴金属卟啉 - 苯有机半导体材料具有良好的溶解性，载流子迁移率高，吸光度高，吸收范围广，光照范围广，利用率高等优点。 此外，制备方法的过程简单易操作和控制。

公开(公告)号：US08604147B2

公开(公告)日：2013-12-10

申请号：US13696433

申请日：2010-05-18

Applicant: Mingjie Zhou ,  Jie Huang ,  Yijin Liu

Inventor： Mingjie Zhou ,  Jie Huang ,  Yijin Liu

IPC: C08G65/38

CPC classification number: H01L51/0035 ,  B82Y10/00 ,  C08G61/122 ,  C08G61/124 ,  C08G2261/124 ,  C08G2261/148 ,  C08G2261/3221 ,  C08G2261/3241 ,  C08G2261/414 ,  C08G2261/526 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/009 ,  H01L51/4253 ,  Y02E10/549

Abstract: A porphyrin copolymer containing quinoxaline unit, preparation method and uses thereof are disclosed. The copolymer has the structural formula (I), wherein R1, R2, R3, R4 are selected from C1˜C32 alkyl groups, and n is an integer between 1 and 100. The copolymer is useful in the fields of solar battery and the like.

Abstract translation: 公开了含有喹喔啉单元的卟啉共聚物，其制备方法和用途。 共聚物具有结构式（I），其中R1，R2，R3，R4选自C1〜C32烷基，n为1〜100的整数。该共聚物可用于太阳能电池等领域 。

公开(公告)号：US08546512B2

公开(公告)日：2013-10-01

申请号：US13582807

申请日：2010-03-23

Applicant: Mingjie Zhou ,  Jie Huang ,  Yijin Liu

Inventor： Mingjie Zhou ,  Jie Huang ,  Yijin Liu

IPC: C08G8/02

CPC classification number: C07D487/22 ,  C08G61/124 ,  C08G2261/148 ,  C08G2261/15 ,  C08G2261/312 ,  C08G2261/3221 ,  C09K11/06 ,  C09K2211/1466 ,  H01L51/0043 ,  H01L51/0077 ,  H01L51/009 ,  H01S5/36 ,  H05B33/14 ,  Y02E10/549 ,  Y02P70/521

Abstract: A copolymer containing fluorenylporphyrin-benzene is disclosed, which comprises a copolymer represented by formula (1), in which R1, R2, R3 and R4, which may be identical or different, are C1-C16 alkyl, and n is an integer of 1 to 100. The preparation method of said copolymer containing fluorenylporphyrin-benzene and the use thereof in manufacture of solar batteries components, organic field effect transistors, organic electroluminescent components, organic optical storage components, organic non-linear materials or organic laser components are also disclosed.

Abstract translation: 公开了含有芴基卟啉 - 苯的共聚物，其包含由式（1）表示的共聚物，其中R 1，R 2，R 3和R 4可以相同或不同，为C 1 -C 16烷基，n为整数1 还公开了包含芴基卟啉 - 苯的所述共聚物的制备方法及其在制造太阳能电池组件，有机场效应晶体管，有机电致发光组分，有机光学存储组分，有机非线性材料或有机激光组分中的用途 。

公开(公告)号：US20120329979A1

公开(公告)日：2012-12-27

申请号：US13582807

申请日：2010-03-23

Applicant: Mingjie Zhou ,  Jie Huang ,  Yijin Liu

Inventor： Mingjie Zhou ,  Jie Huang ,  Yijin Liu

IPC: C08G73/06

CPC classification number: C07D487/22 ,  C08G61/124 ,  C08G2261/148 ,  C08G2261/15 ,  C08G2261/312 ,  C08G2261/3221 ,  C09K11/06 ,  C09K2211/1466 ,  H01L51/0043 ,  H01L51/0077 ,  H01L51/009 ,  H01S5/36 ,  H05B33/14 ,  Y02E10/549 ,  Y02P70/521

Abstract: A copolymer containing fluorenylporphyrin-benzene is disclosed, which comprises a copolymer represented by formula (1), in which R1, R2, R3 and R4, which may be identical or different, are C1-C16 alkyl, and n is an integer of 1 to 100. The preparation method of said copolymer containing fluorenylporphyrin-benzene and the use thereof in manufacture of solar batteries components, organic field effect transistors, organic electroluminescent components, organic optical storage components, organic non-linear materials or organic laser components are also disclosed.

Abstract translation: 公开了含有芴基卟啉 - 苯的共聚物，其包含由式（1）表示的共聚物，其中R 1，R 2，R 3和R 4可以相同或不同，为C 1 -C 16烷基，n为整数1 还公开了包含芴基卟啉 - 苯的所述共聚物的制备方法及其在制造太阳能电池组件，有机场效应晶体管，有机电致发光组分，有机光学存储组分，有机非线性材料或有机激光组分中的用途 。

公开(公告)号：US20120302717A1

公开(公告)日：2012-11-29

申请号：US13575684

申请日：2010-01-30

Applicant: Mingjie Zhou ,  Jie Huang ,  Yijin liu

Inventor： Mingjie Zhou ,  Jie Huang ,  Yijin liu

IPC: C08G73/06

CPC classification number: C07D487/22 ,  B82Y10/00 ,  C08G61/124 ,  C08G2261/148 ,  C08G2261/314 ,  C08G2261/3221 ,  C08G2261/411 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/0077 ,  H01L51/009 ,  H01L51/0545 ,  H01L51/42 ,  H01L51/4253 ,  H01L51/50 ,  H01S3/213 ,  H05B33/14 ,  Y02E10/549 ,  Y02P70/521

Abstract: A copolymer containing fluorenylporphyrin-anthracene is disclosed, which comprises a polymer represented by formula (1), in which R1, R2, R3 and R4, which may be identical or different, are C1-C16 alkyl, and n is an integer of 1 to 100. A preparation method of the copolymer containing fluorenylporphyrin-anthracene and the application thereof in manufacture of solar cell devices, organic field-effect transistors, organic electroluminescent devices, organic optical storage device, organic nonlinear materials or organic laser devices are also disclosed.

Abstract translation: 公开了包含芴基卟啉 - 蒽的共聚物，其包含由式（1）表示的聚合物，其中R 1，R 2，R 3和R 4可以相同或不同，为C 1 -C 16烷基，n为整数1 还公开了含有芴基卟啉 - 蒽的共聚物的制备方法及其在制造太阳能电池器件，有机场效应晶体管，有机电致发光器件，有机光学存储器件，有机非线性材料或有机激光器件中的应用。

公开(公告)号：US08598301B2

公开(公告)日：2013-12-03

申请号：US13575684

申请日：2010-01-30

Applicant: Mingjie Zhou ,  Jie Huang ,  Yijin Liu

Inventor： Mingjie Zhou ,  Jie Huang ,  Yijin Liu

IPC: C08G65/38

CPC classification number: C07D487/22 ,  B82Y10/00 ,  C08G61/124 ,  C08G2261/148 ,  C08G2261/314 ,  C08G2261/3221 ,  C08G2261/411 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/0077 ,  H01L51/009 ,  H01L51/0545 ,  H01L51/42 ,  H01L51/4253 ,  H01L51/50 ,  H01S3/213 ,  H05B33/14 ,  Y02E10/549 ,  Y02P70/521

Abstract: A copolymer containing fluorenylporphyrin-anthracene is disclosed, which comprises a polymer represented by formula (1), in which R1, R2, R3 and R4, which may be identical or different, are C1-C16 alkyl, and n is an integer of 1 to 100. A preparation method of the copolymer containing fluorenylporphyrin-anthracene and the application thereof in manufacture of solar cell devices, organic field-effect transistors, organic electroluminescent devices, organic optical storage device, organic nonlinear materials or organic laser devices are also disclosed.

Abstract translation: 公开了包含芴基卟啉 - 蒽的共聚物，其包含由式（1）表示的聚合物，其中R 1，R 2，R 3和R 4可以相同或不同，为C 1 -C 16烷基，n为整数1 还公开了含有芴基卟啉 - 蒽的共聚物的制备方法及其在制造太阳能电池器件，有机场效应晶体管，有机电致发光器件，有机光学存储器件，有机非线性材料或有机激光器件中的应用。

公开(公告)号：US20130096270A1

公开(公告)日：2013-04-18

申请号：US13702105

申请日：2010-06-07

Applicant: Mingjie Zhou ,  Jie Huang ,  Yijin Liu

Inventor： Mingjie Zhou ,  Jie Huang ,  Yijin Liu

IPC: C08F236/20

CPC classification number: C08F236/20 ,  C08G61/123 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/148 ,  C08G2261/3221 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/91 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1466 ,  C09K2211/1483 ,  H01L51/0043 ,  H01L51/0077 ,  H01L51/009 ,  H01L51/0558 ,  H01L51/424 ,  H01L51/5012 ,  Y02E10/549 ,  Y02P70/521

Abstract: A porphyrin copolymer containing thienothiadiazole units, preparation method and uses thereof are disclosed. The copolymer has the structural formula (I), wherein: R1, R2, R3, R4 are same or different and each represents a C1-C32 alkyl; n is an integer of 1-100. The copolymer comprises fluorene units, thienothiadiazole units and porphyrin units, which enhance the density of electron cloud in copolymer skeleton, make the band-gap of the copolymer become narrow, thereby broaden the spectral response range of the copolymer, and improve the photoelectric transformation efficiency.

Abstract translation: 公开了含有噻吩并噻二唑单元的卟啉共聚物，其制备方法和用途。 共聚物具有结构式（I），其中：R 1，R 2，R 3，R 4相同或不同，各自表示C 1 -C 32烷基; n为1-100的整数。 共聚物包括芴单元，噻吩并噻二唑单元和卟啉单元，其增强共聚物骨架中电子云的密度，使共聚物的带隙变窄，从而拓宽共聚物的光谱响应范围，提高光电转换效率 。

公开(公告)号：US08507637B2

公开(公告)日：2013-08-13

申请号：US13702105

申请日：2010-06-07

Applicant: Mingjie Zhou ,  Jie Huang ,  Yijin Liu

Inventor： Mingjie Zhou ,  Jie Huang ,  Yijin Liu

IPC: C08G8/02

CPC classification number: C08F236/20 ,  C08G61/123 ,  C08G61/124 ,  C08G61/126 ,  C08G2261/124 ,  C08G2261/148 ,  C08G2261/3221 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/91 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1466 ,  C09K2211/1483 ,  H01L51/0043 ,  H01L51/0077 ,  H01L51/009 ,  H01L51/0558 ,  H01L51/424 ,  H01L51/5012 ,  Y02E10/549 ,  Y02P70/521

Abstract: A porphyrin copolymer containing thienothiadiazole units, preparation method and uses thereof are disclosed. The copolymer has the structural formula (I), wherein: R1, R2, R3, R4 are same or different and each represents a C1-C32 alkyl; n is an integer of 1-100. The copolymer comprises fluorene units, thienothiadiazole units and porphyrin units, which enhance the density of electron cloud in copolymer skeleton, make the band-gap of the copolymer become narrow, thereby broaden the spectral response range of the copolymer, and improve the photoelectric transformation efficiency.

Abstract translation: 公开了含有噻吩并噻二唑单元的卟啉共聚物，其制备方法和用途。 共聚物具有结构式（I），其中：R 1，R 2，R 3，R 4相同或不同，各自表示C 1 -C 32烷基; n为1-100的整数。 共聚物包括芴单元，噻吩并噻二唑单元和卟啉单元，其增强共聚物骨架中电子云的密度，使共聚物的带隙变窄，从而拓宽共聚物的光谱响应范围，提高光电转换效率 。

公开(公告)号：US20130165646A1

公开(公告)日：2013-06-27

申请号：US13821523

申请日：2010-09-13

Applicant: Mingjie Zhou ,  Jie Huang ,  Yijin Liu

Inventor： Mingjie Zhou ,  Jie Huang ,  Yijin Liu

IPC: C07F7/08 ,  C07F15/06 ,  C07F3/06 ,  C07F1/08 ,  C07F15/02 ,  C07F7/22 ,  C07F3/08

CPC classification number: C07F7/0816 ,  B82Y10/00 ,  C07D487/22 ,  C07F1/08 ,  C07F3/06 ,  C07F3/08 ,  C07F7/2284 ,  C07F15/025 ,  C07F15/065 ,  C08G61/124 ,  C08G2261/124 ,  C08G2261/144 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/3221 ,  C08G2261/3244 ,  C08G2261/37 ,  C08G2261/411 ,  C08G2261/51 ,  C08G2261/91 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/0083 ,  H01L51/009 ,  H01L51/0091 ,  H01L51/0092 ,  H01L51/0094 ,  H01L51/424 ,  H01L51/5016 ,  Y02E10/549 ,  Y02P70/521

Abstract: A silafluorene metalloporphyrin-benzene organic semiconductor material and preparing method and uses thereof are provided. The structure of the silafluorene metalloporphyrin-benzene organic semiconductor material is defined by structure formula (I); wherein: n is an integer between 1 and 100, R1, R2, R3, R4 are H, alkyl with C1-C32, phenyl, alkyl benzene or alkoxyl benzene containing one or more C1-C32, M is a metal ion. The silafluorene metalloporphyrin-benzene organic semiconductor material has good solubility, high carrier mobility, strong absorbance, wide absorbent range to light and elevated utilization ratio of solar light. Besides, the process of the preparing method is simple and easy to operate and control.

Abstract translation: 提供了一种硅芴金属卟啉 - 苯有机半导体材料及其制备方法和用途。 硅芴金属卟啉 - 苯有机半导体材料的结构由结构式（I）定义; 其中：n为1〜100的整数，R 1，R 2，R 3，R 4为H，含有C 1 -C 32的烷基，苯基，烷基苯或含有一个或多个C 1 -C 32的烷氧基苯，M为金属离子。 硅芴金属卟啉 - 苯有机半导体材料具有良好的溶解性，载流子迁移率高，吸光度高，吸收范围广，吸光度高，太阳能利用率提高。 此外，制备方法的过程简单易操作和控制。

公开(公告)号：US20130059994A1

公开(公告)日：2013-03-07

申请号：US13696433

申请日：2010-05-18

Applicant: Mingjie Zhou ,  Jie Huang ,  Yijin Liu

Inventor： Mingjie Zhou ,  Jie Huang ,  Yijin Liu

IPC: C08G73/06 ,  C08F4/80

CPC classification number: H01L51/0035 ,  B82Y10/00 ,  C08G61/122 ,  C08G61/124 ,  C08G2261/124 ,  C08G2261/148 ,  C08G2261/3221 ,  C08G2261/3241 ,  C08G2261/414 ,  C08G2261/526 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/009 ,  H01L51/4253 ,  Y02E10/549

Abstract: A porphyrin copolymer containing quinoxaline unit, preparation method and uses thereof are disclosed. The copolymer has the structural formula (I), wherein R1, R2, R3, R4 are selected from C1˜C32 alkyl groups, and n is an integer between 1 and 100. The copolymer is useful in the fields of solar battery and the like.

Abstract translation: 公开了含有喹喔啉单元的卟啉共聚物，其制备方法和用途。 共聚物具有结构式（I），其中R 1，R 2，R 3，R 4选自C 1 -C 32烷基，n为1至100之间的整数。该共聚物可用于太阳能电池等领域 。