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公开(公告)号:US5648510A
公开(公告)日:1997-07-15
申请号:US627897
申请日:1996-04-03
申请人: Katsumasa Harada , Yoichi Imbe , Keigo Nishihira , Shuji Tanaka , Satoru Fujitsu , Ryoji Sugise , Koichi Kashiwagi , Toshihiko Sumida
发明人: Katsumasa Harada , Yoichi Imbe , Keigo Nishihira , Shuji Tanaka , Satoru Fujitsu , Ryoji Sugise , Koichi Kashiwagi , Toshihiko Sumida
IPC分类号: C07C67/333 , C07C68/00 , C07D307/68 , C07D333/38 , C07C69/96
CPC分类号: C07C67/333 , C07C68/00 , C07D307/68 , C07D333/38
摘要: A diaryl carbonate is prepared at a high yield and a high selectivity by heating a diaryl oxalate in the presence of an organic phosphorous compound to release carbon monoxide therefrom. A halogen atom-containing compound can be employed in combination with the organic phosphorous compound.
摘要翻译: 通过在有机磷化合物的存在下加热草酸二芳基酯从而释放一氧化碳,以高产率和高选择性制备碳酸二芳基酯。 含卤原子的化合物可以与有机磷化合物组合使用。
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公开(公告)号:US5892089A
公开(公告)日:1999-04-06
申请号:US944231
申请日:1997-10-06
申请人: Katsumasa Harada , Ryoji Sugise , Koichi Kashiwagi , Yoichi Imbe , Takashi Doi , Keigo Nishihira , Shuji Tanaka , Hirofumi Ii
发明人: Katsumasa Harada , Ryoji Sugise , Koichi Kashiwagi , Yoichi Imbe , Takashi Doi , Keigo Nishihira , Shuji Tanaka , Hirofumi Ii
IPC分类号: C07C68/00
CPC分类号: C07C68/00
摘要: A process for preparing a diaryl carbonate from a diaryl oxalate in a liquid phase by decarbonylation is conducted by the steps of:1) performing a decarbonylation reaction of a diaryl oxalate in the presence of an organic phosphorus compound catalyst to give a reaction mixture of a diaryl carbonate and the organic phosphorus compound catalyst;2) recovering the diaryl carbonate from the reaction mixture; and3) performing a decarbonylation reaction of a diaryl oxalate in the presence of the reaction mixture from which the diaryl carbonate has been recovered and to which a halogen atom-containing compound is added, to give a reaction mixture of a diaryl carbonate and the organic phosphorus compound catalyst.
摘要翻译: 通过脱羰由草酸二芳基酯在液相中制备碳酸二芳基酯的方法是通过以下步骤进行的:1)在有机磷化合物催化剂存在下进行草酸二芳基酯的脱羰基化反应,得到 碳酸二芳酯和有机磷化合物催化剂; 2)从反应混合物中回收碳酸二芳基酯; 和3)在已经回收了碳酸二芳基酯并且含有含卤原子的化合物的反应混合物存在下进行草酸二芳酯的脱羰基反应,得到碳酸二芳基酯和有机物的反应混合物 磷化合物催化剂。
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公开(公告)号:US5892091A
公开(公告)日:1999-04-06
申请号:US889390
申请日:1997-07-08
申请人: Katsumasa Harada , Yoichi Imbe , Keigo Nishihira , Shuji Tanaka , Satoru Fujitsu , Ryoji Sugise , Koichi Kashiwagi , Toshihiko Sumida , Takashi Doi , Masayuki Nishio
发明人: Katsumasa Harada , Yoichi Imbe , Keigo Nishihira , Shuji Tanaka , Satoru Fujitsu , Ryoji Sugise , Koichi Kashiwagi , Toshihiko Sumida , Takashi Doi , Masayuki Nishio
IPC分类号: C07C67/333 , C07C68/00 , C07D307/68 , C07D333/38 , C07C69/96
CPC分类号: C07C67/333 , C07C68/00 , C07D307/68 , C07D333/38
摘要: A catalyst composed of an organic phosphorus compound having a trivalent or pentavalent phosphorus atom and at least one carbon-phosphorus bonding or a combination of the organic phosphorus compound and a halogen atom-containing compound is effective for decarbonylation, that is, for releasing carbon monoxide from a compound containing a moiety of --CO--CO--O-- in its molecular structure.
摘要翻译: 由具有三价或五价磷原子和至少一个碳 - 磷键的有机磷化合物或有机磷化合物和含卤素原子的化合物的组合的催化剂对脱碳作用是有效的,即用于释放一氧化碳 来自在其分子结构中含有-CO-CO-O-部分的化合物。
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