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公开(公告)号：US20090272507A1
公开(公告)日：2009-11-05
申请号：US12225727
申请日：2006-03-30
IPC分类号： D21H19/00 , C08F220/10 , C08F220/34 , C08F220/56
摘要： The invention improves a sizing effect even on paper containing no internal sizing agent and improves productivity by making solution polymerization in a small amount of an organic solvent. The invention provides a cationic surface sizing agent composed of a copolymer obtained by solution polymerization of (a) 15 to 35% by weight of a tertiary amino group-containing monomer, (b) 30 to 85% by weight of C1 to C4 alkyl (meth)acrylate, and (c) 1 to 50% by weight of styrenes in an organic solvent in the presence of a chain transfer agent. The copolymer may be subjected to cationization treatment with a quaternization agent. As a constituent monomer of the copolymer, 0 to 20% by weight of another copolymerizable vinyl monomer (d) may be contained. The cationic surface sizing agent is applied to paper.
摘要翻译： 本发明即使对不含内部施胶剂的纸也能提高施胶效果，并且通过在少量的有机溶剂中进行溶液聚合来提高生产率。 本发明提供一种阳离子表面施胶剂，其由通过（a）15〜35重量％的含叔氨基单体的溶液聚合得到的共聚物，（b）30〜85重量％的C1〜C4烷基（ 甲基）丙烯酸酯，和（c）1至50重量％的苯乙烯在有机溶剂中，在链转移剂存在下。 共聚物可以用季铵化剂进行阳离子化处理。 作为共聚物的构成单体，可以含有0〜20重量％的其它可共聚乙烯基单体（d）。 阳离子表面施胶剂适用于纸张。
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公开(公告)号：US5306779A
公开(公告)日：1994-04-26
申请号：US937723
申请日：1992-09-01
IPC分类号： C08F8/04 , C08F297/04 , C08L51/00 , C08L53/02
CPC分类号： C08L53/025 , C08F297/04 , C08F8/04 , C08L51/006 , Y10S525/94
摘要： A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)-(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)-(B)-(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)-(B)-(A) block copolymer in which (A) and (B) are as defined above and in which hydrogenation product at least 80% of the double bonds of the conjugated diene portion is saturated by the hydrogenation. Said hydrogenated diene block copolymer is useful as a modifier for polar resins, non-polar resins or both of them.
摘要翻译： 具有聚苯乙烯换算的数均分子量为50,000-600,000的氢化二烯嵌段共聚物，其是（A） - （B）嵌段共聚物的氢化产物，其中（A）表示链烯基芳族化合物聚合物嵌段和（B 是指共轭二烯部分的乙烯基含量大于60％的共轭二烯均聚物嵌段或共轭二烯部分的乙烯基含量为15％以上的链烯基芳香族化合物 - 共轭二烯无规共聚物嵌段，（ A） - （B） - （C）嵌段共聚物，其中（A）和（B）如上所定义，（C）是烯基芳族化合物 - 共轭二烯共聚物渐缩嵌段，其中烯基芳族化合物的比例逐渐增加 或（A） - （B） - （A）嵌段共聚物，其中（A）和（B）如上所定义，并且其中至少80％的共轭二烯部分的双键被氢化产物饱和 氢化。 所述氢化二烯嵌段共聚物可用作极性树脂，非极性树脂或它们两者的改性剂。
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公开(公告)号：US20100084102A1
公开(公告)日：2010-04-08
申请号：US12449156
申请日：2008-01-16
申请人： Kazunari Sakai , Tomohiko Nakata , Yoshiharu Hashiguchi , Takashi Yamaguchi , Masaki Ito , Yasunobu Ooka
发明人： Kazunari Sakai , Tomohiko Nakata , Yoshiharu Hashiguchi , Takashi Yamaguchi , Masaki Ito , Yasunobu Ooka
CPC分类号： D21H21/16 , D21H17/41 , D21H17/42 , D21H17/44 , D21H17/455 , D21H17/675 , D21H17/69
摘要： To effectively impart sizing performance to paper, while reducing the amounts of an internal sizing agent and aluminum sulfate, the invention provides as a papermaking additive a mixture of a cationic copolymer having a hydrophobic group whose quarterization ratio is 40% by mole or more, or an amphoteric copolymer having a hydrophobic group which has the same quarterization ratio as above, and in which the ratio of the anion equivalent to the cation equivalent is 0.1 to 90%, and a filler (a pretreated filler). The pretreated filler is one in which suitable water repellency is imparted to the filler. Hence, by adding this to pulp slurry, followed by a wet papermaking, the pretreated filler is efficiently adsorbed onto pulp fibers having anionic property, so that effective sizing performance can be imparted to the paper by using a smaller amount thereof than the internal sizing agent, while reducing the amounts of the internal sizing agent and the aluminum sulfate.
摘要翻译： 为了有效地赋予纸张施胶性能，同时减少内部施胶剂和硫酸铝的量，本发明提供了具有疏水性基团的阳离子共聚物的混合物，该疏水基团的四分子化比例为40摩尔％以上，或者 具有与上述相同的季铵化比例的疏水性基团，阴离子当量与阳离子当量的比例为0.1〜90％的两性共聚物和填料（预处理填料）。 预处理的填料是赋予填料适当的防水性的填料。 因此，通过将其添加到纸浆中，然后进行湿法造纸，将预处理的填料有效地吸附到具有阴离子性质的纸浆纤维上，从而通过使用比内部施胶剂更少量的纸赋予纸张有效的施胶性能 同时减少内部施胶剂和硫酸铝的量。
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公开(公告)号：US20090068485A1
公开(公告)日：2009-03-12
申请号：US12084099
申请日：2006-10-26
CPC分类号： D21H19/20 , C08F212/08 , C08F220/18 , C08F220/34 , D21H17/35 , D21H17/37 , D21H17/455 , D21H21/14 , D21H21/16 , Y10T428/3179
摘要： It is an object to improve sizing performance and anti-plate-soiling property in offset printing, for example, in a cationic surface sizing agent to be used for coating base paper of newsprint paper, and as a means for solving the object, a cationic surface sizing agent is produced by quaternizing a copolymer having a weight average molecular weight ranging from 30,000 to 60,000 obtained by polymerizing (a) 20 to 40% by weight of a monomer containing tertiary amino group; (b) 10 to 80% by weight of a C4 to C18 alkyl ester of (meth) acrylic acid; and (c) 0 to 70% by weight of a styrene or derivative thereof, using an azoic polymerization initiator in the presence of a chain transfer agent. In this manner, it is possible to improve sizing performance without reducing the hydrophobic level of copolymer and to suppress sensitization of printing plate such as PS plate by specifying the monomer composition ratio, using an azoic polymerization initiator, and specifying molecular weight of the copolymer.
摘要翻译： 本发明的目的是提高胶版印刷中的施胶性能和抗平板性能，例如在用于涂布新闻纸的原纸的阳离子表面施胶剂中，作为解决该目的的方法，阳离子 表面施胶剂通过季铵化通过聚合（a）20至40重量％的含有叔氨基的单体而获得的重均分子量范围为30,000至60,000的共聚物; （b）10〜80重量％的（甲基）丙烯酸的C 4〜C 18烷基酯; 和（c）0〜70重量％的苯乙烯或其衍生物，在链转移剂存在下使用偶氮聚合引发剂。 以这种方式，可以在不降低共聚物的疏水性水平的情况下提高施胶性能，并且通过使用偶氮聚合引发剂指定单体组成比例和确定共聚物的分子量来抑制印刷板如PS板的敏化。
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5.发明授权(Modified) hydrogenated diene block copolymer and composition comprising the same 失效（改性）氢化二烯嵌段共聚物及其组合物
公开(公告)号：US5346964A
公开(公告)日：1994-09-13
申请号：US80115
申请日：1993-06-23
IPC分类号： C08F8/04 , C08F297/04 , C08L51/00 , C08L53/02 , C08F287/00
CPC分类号： C08L53/025 , C08F297/04 , C08F8/04 , C08L51/006 , Y10S525/94
摘要： A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)-(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)-(B)-(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)-(B)-(A) block copolymer in which (A) and (B) are as defined above. Said hydrogenated diene block copolymer is useful as a modifier for polar resins, non-polar resins or both of them.
摘要翻译： 具有聚苯乙烯换算的数均分子量为50,000-600,000的氢化二烯嵌段共聚物，其是（A） - （B）嵌段共聚物的氢化产物，其中（A）表示链烯基芳族化合物聚合物嵌段和（B 是指共轭二烯部分的乙烯基含量大于60％的共轭二烯均聚物嵌段或共轭二烯部分的乙烯基含量为15％以上的链烯基芳香族化合物 - 共轭二烯无规共聚物嵌段，（ A） - （B） - （C）嵌段共聚物，其中（A）和（B）如上所定义，（C）是烯基芳族化合物 - 共轭二烯共聚物渐缩嵌段，其中烯基芳族化合物的比例逐渐增加 或（A） - （B） - （A）嵌段共聚物，其中（A）和（B）如上所定义。 所述氢化二烯嵌段共聚物可用作极性树脂，非极性树脂或它们两者的改性剂。
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6.发明授权
公开(公告)号：US5270274A
公开(公告)日：1993-12-14
申请号：US981288
申请日：1992-11-25
CPC分类号： B01J31/143 , B01J31/0208 , B01J31/0244 , B01J31/122 , B01J31/2295 , C08C19/02 , C08F8/04 , B01J2231/645 , B01J2531/46 , B01J2531/48 , B01J2531/49 , Y10S526/943
摘要： A catalyst composition comprising: (a) a bis(cyclopentadienyl) transition metal compound, (b) at least one polarized compound selected from the group consisting of carbonyl group-containing compounds and epoxy group containing compounds, and (c) an organic lithium compound. It has a high hydrogenation activity and is useful for hydrogenating olefinically unsaturated polymers for providing the olefinically unsaturated polymers with excellent characteristics as superior weatherability, good heat resistance, superb oxidation resistance, and the like.
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7.发明授权Hydrogenation catalyst composition and process for hydrogenating olefinically unsaturated polymer using the same 失效氢化催化剂组合物和使用其加氢烯烃不饱和聚合物的方法
公开(公告)号：US5169905A
公开(公告)日：1992-12-08
申请号：US627770
申请日：1990-12-14
IPC分类号： C08F4/642 , B01J31/02 , B01J31/12 , B01J31/14 , B01J31/22 , C08C19/02 , C08F8/04 , C08F36/00 , C08F36/04 , C08F36/06 , C08F297/04
CPC分类号： C08F8/04 , B01J31/0211 , B01J31/12 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/2295 , C08C19/02 , B01J2231/645 , B01J2531/46 , B01J2531/48
摘要： A hydrogenation catalyst composition comprising, as essential components, (a) at least one bis(cyclopentadienyl)transition metal compound represented by general formula (i): ##STR1## and (b) at least one member selected from the group consisting of complex compounds represented by general formulas (ii) and (iii): ##STR2## and further comprising, if necessary, (c) at least one polar compound selected from the group consisting of ether compounds, thioether compounds, ketone compounds, sulfoxide compounds, carboxylic acid ester compounds, lactone compounds, amine compounds, amide compounds, nitrile compounds and oxime compounds and/or (d) an alkali compound represented by general formula (iv):M.sup.2 OR.sup.7 (iv)The contact of an olefinically unsaturated polymer with hydrogen in the presence of said catalyst composition enables the selective hydrogenation of the olefinic double bonds in said polymer. The thus obtained hydrogenated polymer has excellent weather resistance, heat resistance and oxidation resistance.
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公开(公告)号：US08349135B2
公开(公告)日：2013-01-08
申请号：US12449156
申请日：2008-01-16
申请人： Kazunari Sakai , Tomohiko Nakata , Yoshiharu Hashiguchi , Takashi Yamaguchi , Masaki Ito , Yasunobu Ooka
发明人： Kazunari Sakai , Tomohiko Nakata , Yoshiharu Hashiguchi , Takashi Yamaguchi , Masaki Ito , Yasunobu Ooka
CPC分类号： D21H21/16 , D21H17/41 , D21H17/42 , D21H17/44 , D21H17/455 , D21H17/675 , D21H17/69
摘要： To effectively impart sizing performance to paper, while reducing the amounts of an internal sizing agent and aluminum sulfate, a papermaking additive comprises a mixture of an amphoteric copolymer having a hydrophobic group whose quaternization ratio is 40% by mole or more, and in which the ratio of the anion equivalent to the cation equivalent is 0.1 to 90%, and a calcium carbonate filler. The filler is one in which suitable water repellency is imparted to the filler. Hence, by adding this to pulp slurry, followed by a wet papermaking, the filler is efficiently adsorbed onto pulp fibers having anionic property, so that effective sizing performance can be imparted to the paper by using a smaller amount thereof than the internal sizing agent, while reducing the amounts of the internal sizing agent and the aluminum sulfate.
摘要翻译： 为了有效地赋予纸张上浆性能，同时减少内部上浆剂和硫酸铝的量，造纸添加剂包括具有季铵化比例为40摩尔％以上的疏水基团的两性共聚物的混合物，其中 阴离子当量与阳离子当量的比例为0.1〜90％，碳酸钙填料。 填料是赋予填料适当的防水性的填料。 因此，通过将其添加到纸浆中，然后进行湿法造纸，将填料有效地吸附到具有阴离子性质的纸浆纤维上，从而通过使用比内部施胶剂更少的量赋予纸张有效的施胶性能， 同时减少内部施胶剂和硫酸铝的量。
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公开(公告)号：US07988826B2
公开(公告)日：2011-08-02
申请号：US12225727
申请日：2006-03-30
IPC分类号： D21H19/20
摘要： The invention improves a sizing effect even on paper containing no internal sizing agent and improves productivity by making solution polymerization in a small amount of an organic solvent. The invention provides a cationic surface sizing agent composed of a copolymer obtained by solution polymerization of (a) 15 to 35% by weight of a tertiary amino group-containing monomer, (b) 30 to 85% by weight of C1 to C4 alkyl(meth)acrylate, and (c) 1 to 50% by weight of styrenes in an organic solvent in the presence of a chain transfer agent. The copolymer may be subjected to cationization treatment with a quaternization agent. As a constituent monomer of the copolymer, 0 to 20% by weight of another copolymerizable vinyl monomer (d) may be contained. The cationic surface sizing agent is applied to paper.
摘要翻译： 本发明即使对不含内部施胶剂的纸也能提高施胶效果，并且通过在少量的有机溶剂中进行溶液聚合来提高生产率。 本发明提供一种阳离子表面施胶剂，其由通过（a）15〜35重量％的含叔氨基单体的溶液聚合得到的共聚物，（b）30〜85重量％的C1〜C4烷基（ 甲基）丙烯酸酯，和（c）1至50重量％的苯乙烯在有机溶剂中，在链转移剂存在下。 共聚物可以用季铵化剂进行阳离子化处理。 作为共聚物的构成单体，可以含有0〜20重量％的其它可共聚乙烯基单体（d）。 阳离子表面施胶剂适用于纸张。
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公开(公告)号：US20060057310A1
公开(公告)日：2006-03-16
申请号：US10532531
申请日：2003-11-12
申请人： Atsushi Suzuki , Norifumi Tanaka , Yoshio Yoshida , Masanori Kawashima , Yoshiharu Hashiguchi , Yoko Matsunaga
发明人： Atsushi Suzuki , Norifumi Tanaka , Yoshio Yoshida , Masanori Kawashima , Yoshiharu Hashiguchi , Yoko Matsunaga
IPC分类号： B41M5/00
CPC分类号： B41M5/506 , B41M5/502 , B41M5/52 , B41M5/5245 , B41M5/5254 , B41M7/0027 , B41M2205/12
摘要： An inkjet recording medium containing an ink absorbing layer the main component of which are fine inorganic particles having an average particle diameter of from 10 nm to 500 nm on a base material and a glossy layer obtained by coating a polymer dispersion over the ink absorbing layer wherein the polymer dispersion is a dispersion of fine, non cross-linked styrene-acrylic type polymer particles obtained by a copolymerization reaction of monomer components containing at least a cationic monomer, (meth)acrylamide, styrene and methyl methacrylate, said glossy layer is formed by having the fine polymer particles in the polymer dispersion present in the ink absorbing layer maintain their particulate shapes.
摘要翻译： 一种喷墨记录介质，其特征在于，在基材上含有主要成分为平均粒径为10nm〜500nm的无机微粒的吸墨层和通过在该吸墨层上涂布聚合物分散体得到的光泽层的吸墨层， 聚合物分散体是通过使至少含有阳离子单体（甲基）丙烯酰胺，苯乙烯和甲基丙烯酸甲酯的单体成分的共聚反应而得到的精细非交联苯乙烯 - 丙烯酸类聚合物粒子的分散液，所述光泽层由 存在于吸墨层中的聚合物分散体中的聚合物微粒保持其颗粒形状。
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