公开(公告)号：US06635733B2

公开(公告)日：2003-10-21

申请号：US09850152

申请日：2001-05-08

申请人： Tsuyoshi Yahata ,  Masato Nakano ,  Yoshiyuki Ohgi ,  Tsutomu Ushioda

发明人： Tsuyoshi Yahata ,  Masato Nakano ,  Yoshiyuki Ohgi ,  Tsutomu Ushioda

IPC分类号： C08F21006

CPC分类号： C08F110/06 ,  C08F4/65912 ,  C08F10/00 ,  Y10S526/943 ,  C08F4/65925 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/21

摘要： An elastomeric polypropylene wherein (a) an isotactic pentad (I5) is 0.150-0.749, (b) a different bond due to a 2,1-insertion reaction is 0.11-20 mol %, (c) a different bond due to a 1,3-insertion reaction is 0-10 mol % and (d) a melting point (Tm) is 50-160° C., (a) to (c) being determined from 13C NMR spectra, which is obtainable by the polymerization of propylene using any one of a metallocene catalyst (I) comprising a metallocene compound (A), an activating compound (B) and if desired, an organoaluminum compound (C), a supported metallocene catalyst (II) prepared by supporting the metallocene catalyst (I) on a finely particulate support (D), and a supported metallocene catalyst (III) prepared by adding an organoaluminum compound (E) to the supported metallocene catalyst (II). In particular, it has excellent transparency and elastic characteristics.

摘要翻译： 一种弹性体聚丙烯，其中（a）全同立构五单元组（I5）为0.150-0.749，（b）由于2,1-插入反应引起的不同键为0.11-20摩尔％，（c）由于1 ，3-插入反应为0-10摩尔％，（d）熔点（Tm）为50-160℃，（a）至（c）由13 C NMR谱确定，可通过 使用包含茂金属化合物（A）的茂金属催化剂（I），活化化合物（B）和如果需要的话，使用有机铝化合物（C），负载金属茂催化剂（II） 在精细颗粒载体（D）上的金属茂催化剂（I）和通过将有机铝化合物（E）加入到负载的茂金属催化剂（II）中制备的负载金属茂催化剂（III）。 特别是具有优异的透明性和弹性特性。

公开(公告)号：US06410662B1

公开(公告)日：2002-06-25

申请号：US09485492

申请日：2000-02-11

申请人： Tsutomu Ushioda ,  Jun Saito ,  Mototake Tsutsui ,  Yoshitoyo Yasuda ,  Hiroyuki Fujita ,  Toshihiro Uwai ,  Yoshiyuki Ohgi ,  Minoru Adachi ,  Yoshitaka Morimoto ,  Taketo Hirose ,  Youichi Kugimiya ,  Masahiko Taniguchi ,  Hitoshi Kuramochi

发明人： Tsutomu Ushioda ,  Jun Saito ,  Mototake Tsutsui ,  Yoshitoyo Yasuda ,  Hiroyuki Fujita ,  Toshihiro Uwai ,  Yoshiyuki Ohgi ,  Minoru Adachi ,  Yoshitaka Morimoto ,  Taketo Hirose ,  Youichi Kugimiya ,  Masahiko Taniguchi ,  Hitoshi Kuramochi

IPC分类号： C08F444

CPC分类号： C08F10/06 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/65916 ,  C08F2500/03 ,  C08F2500/15 ,  C08F2500/01 ,  C08F2500/12 ,  C08F2500/26

摘要： Disclosed is a process for producing olefin polymers or copolymers which can freely regulates the molecular weight of the polymers or copolymers as well as novel olefin polymers or copolymers excellent in rigidity, heat-resisting property and transparency, moldings and compositions thereof which find a wide variety of applications in versatile industrial parts including containers, films, sheets, filaments or fibers, featured by (1) a process for producing olefin polymers or copolymers by the aid of a catalyst comprised predominantly of the compounds: (A) a transition metal compound of the formula: Q(C5H4−mR1m)(C5H4−nR2n)MXY, (B) an aluminoxane, (C) a fine particulate carrier, and (D) an organoaluminum compound; (2) olefin polymers or copolymers characterized by (a) a specific ratio of isotactic pentad, (b) 2,1- and 1.3-propylene units contents in the polymer chain, (c) a specific Mw, (d) a specific Mw/Mn, and (e) in case of elevating temperature of o-dichlorobenzene continuously or stepwise up to given temperatures to measure the amount of eluated polyolefin at each temperature, the position of a main elution peak and the amount of components existing in the range of ±10° C. of the main elution peak; (3) injection moldings, films, filaments or fibers, and non-woven fabric of the polypropylene obtained; and (4) a composition comprising the polypropylene obtained and an &agr;-nucleating agent or a composition comprising the polypropylene and a radical generator and having been produced by subjecting to the mixture to melt-kneading.

摘要翻译： 公开了可以自由调节聚合物或共聚物的分子量的烯烃聚合物或共聚物的方法，以及刚性，耐热性能和透明性，模制品和组合物的新型烯烃聚合物或共聚物，其具有广泛的种类 在包括容器，膜，片，长丝或纤维在内的通用工业部件中的应用，其特征在于（1）主要由以下化合物构成的催化剂生产烯烃聚合物或共聚物的方法：（A）过渡金属化合物 式（QH（C5H4-mR1m）（C5H4-nR2n））MXY，（B）铝氧烷，（C）微粒载体和（D）有机铝化合物; （2）烯烃聚合物或共聚物，其特征在于（a）聚合物链中全同立构五单体，（b）2,1-和1.3-丙烯单元含量的比例，（c）特定Mw，（d）特定Mw / Mn，（e）在邻二氯苯连续或逐步升高至给定温度的情况下，在每个温度下测量洗脱聚烯烃的量，主洗脱峰的位置和存在于该范围内的组分的量 ±10℃的主洗脱峰; （3）注射成型品，薄膜，细丝或纤维，以及得到的聚丙烯的无纺布; 和（4）包含所得聚丙烯和α-成核剂或包含聚丙烯和自由基发生剂的组合物并通过使混合物进行熔融捏合而制备的组合物的组合物。

公开(公告)号：US06846943B2

公开(公告)日：2005-01-25

申请号：US09861726

申请日：2001-05-22

申请人： Masato Nakano ,  Tsutomu Ushioda ,  Hiroshi Yamazaki ,  Toshihiro Uwai ,  Masami Kimura ,  Yoshiyuki Ohgi ,  Kiyomi Yamamoto

发明人： Masato Nakano ,  Tsutomu Ushioda ,  Hiroshi Yamazaki ,  Toshihiro Uwai ,  Masami Kimura ,  Yoshiyuki Ohgi ,  Kiyomi Yamamoto

IPC分类号： C07F17/00 ,  C08F2/00 ,  C08F4/44 ,  C08F4/64 ,  C08F4/659 ,  C08F4/74 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06

CPC分类号： C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F4/65927 ,  C08F2500/03 ,  C08F2500/15 ,  C08F2500/12 ,  C08F210/16

摘要： The present invention provides a metallocene compound which produces an olefin polymer having a high molecular weight with a high stereoregularity. The metallocene compound has the following formula (1): Q(C5H4-mR1m)(C5H4-nR2n)MXY  (1) wherein (C5H4-mR1m) and (C5H4-nR2n) each independently represent a cyclopentadienyl group; C5H4-m and C5H4-n each independently represent a cyclopentadienyl ring; m represents an integer of 1-3; n represents an integer of 2 or 3; R1 and R2 are each independently a substituent bonded respectively to C5H4-m and C5H4-n, and represent a hydrocarbon group of 1-20 carbon atoms, a silicon-containing hydrocarbon group of 1-20 carbon atoms or a heteroaromatic group; each R1m and each R2n may be the same or different; one pair of R2's in the R2n are bonded to each other to form at least one ring; Q represents a divalent group for cross-linking (C5H4-mR1m) and (C5H4-nR2n); M represents a titanium atom, a zirconium atom or a hafnium atom; and X and Y are the same or different and each a hydrogen atom, a halogen atom or a hydrocarbon group.

摘要翻译： 本发明提供茂金属化合物，其生产具有高立构规整性的具有高分子量的烯烃聚合物。 金属茂化合物具有下式（1）：其中（C5H4-mR1m）和（C5H4-nR_2n）各自独立地表示环戊二烯基; C5H4-m和C5H4-n各自独立地表示环戊二烯基 环; m表示1-3的整数; n表示2或3的整数; R 1和R 2分别独立地表示与C5H4-m和C5H4-n键合的取代基，表示烃基 1-20个碳原子的含硅烃基或杂芳基;每个R 1 m和每个R 2可以相同或不同;一对R 2 R 2相互键合形成至少一个环; Q表示用于交联的二价基团（C 5 H 4 -m R m）和（C 5 H 4 -NR 2 n） M表示钛原子，锆原子或铪原子; X和Y相同或不同，各自为氢原子，卤素原子或烃基。

公开(公告)号：US06388040B1

公开(公告)日：2002-05-14

申请号：US09421329

申请日：1999-10-18

申请人： Hiroyuki Fujita ,  Jun Saito ,  Yoshitoyo Yasuda ,  Yoshiyuki Ohgi ,  Yasuhiro Shiraishi ,  Shinji Nakata ,  Tsutomu Ushioda ,  Mototake Tsutsui

发明人： Hiroyuki Fujita ,  Jun Saito ,  Yoshitoyo Yasuda ,  Yoshiyuki Ohgi ,  Yasuhiro Shiraishi ,  Shinji Nakata ,  Tsutomu Ushioda ,  Mototake Tsutsui

IPC分类号： C08F21000

CPC分类号： C08F210/16 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F210/06 ,  Y10S526/943 ,  C08F4/65927 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26

摘要： A propylene/ethylene/&agr;-olefin terpolymer characterized in that i) there is from 0.01 mol % to less than 15 mol % of a comonomer unit with a molar ratio of ethylene units/C4-C20 &agr;-olefin units being in the range of from 6.5×10−4 to 0.99, and from more than 85 mol % to not more than 99.99 mol % of a propylene unit with 2,1- and 1,3-propylene units being in the range of from 0 to 1 mol %, in a polymer chain determined by 13C-NMR spectroscopy; ii) a weight average molecular weight (Mw) determined by GPC is in the range of from 40,000 to 1,000,000; and iii) the amount of the component eluted in o-dichlorobenzene at a temperature of not higher than 40° C. is not more than 10 % by weight based on the total weight of the terpolymer and the amount of the component eluted in o-dichlorobenzene within the ±10° C. range of an elution peak temperature is not less than 75 % by weight based on the weight of the component eluted at a temperature of higher than 0° C.

摘要翻译： 丙烯/乙烯/α-烯烃三元共聚物，其特征在于：）具有0.01摩尔％至小于15摩尔％的共聚单体单元，其中乙烯单元/ C 4 -C 20α-烯烃单元的摩尔比在 具有2,1-和1,3-丙烯单元的丙烯单元的摩尔比为6.5×10 -4〜0.99，以及大于85摩尔％以上且99.99摩尔％以下的丙烯单元，为0〜1摩尔％ 通过13 C-NMR光谱测定的聚合物链; ii）通过GPC测定的重均分子量（Mw）在40,000至1,000,000的范围内; 和iii）在不高于40℃的温度下在邻二氯苯中洗脱的组分的量不超过基于三元共聚物的总重量的10重量％，并且在邻二氯苯中洗脱的组分的量 洗脱峰温度的±10℃范围内，在高于0℃的温度下洗脱的成分的重量为75重量％以上。

公开(公告)号：US06326432B1

公开(公告)日：2001-12-04

申请号：US09508799

申请日：2000-03-17

申请人： Hiroyuki Fujita ,  Jun Saito ,  Yoshitoyo Yasuda ,  Tsutomu Ushioda ,  Mototake Tsutsui ,  Yoshiyuki Ohgi ,  Minoru Adachi

发明人： Hiroyuki Fujita ,  Jun Saito ,  Yoshitoyo Yasuda ,  Tsutomu Ushioda ,  Mototake Tsutsui ,  Yoshiyuki Ohgi ,  Minoru Adachi

IPC分类号： C08F800

CPC分类号： C08L23/12 ,  C08F110/06 ,  C08L23/16 ,  C08L2666/04 ,  C08F2500/03 ,  C08F2500/15

摘要： Disclosed is a polypropylene composition excellent in balance of low temperature impact-strength, rigidity, heat resistance and transparency, which is featured by comprising 20-95% by weight of a polypropylene defined in the following [I] and 5-80% by weight of a propylene-&agr;-olefin copolymer defined in the following [II]: [I] a polypropylene featured by having: (1) a ratio of isotactic pentad (mmmm) of 0.900-0.949, (2) the 2,1- and 1,3-propylene units in the polymer chain in the amount of 0-1 mole %, (3) a weight average molecular weight (Mw) of 40,000-1,000,000, (4) a ratio of a weight average molecular weight (Mw) to a number average molecular weight (Mn), i.e. (Mw)/(Mn) of 1.5-3.8, and (5) in case of elevating the temperature of o-dichlorobenzene continuously or stepwise up to given temperatures to measure the amount of eluted polypropylene at each temperature, the position of a main elution peak is 95-110° C. and the amount of components existing in the range of ±10° C. of the main elution peak is at least 90% of the total amounts of components eluted at a temperature higher than 0° C. and [II] a propylene-&agr;-olefin copolymer containing 10-90% by weight of a constituent derived from propylene and 10-90% by weight of a constituent derived from &agr;-olefin other than propylene.

摘要翻译： 公开了低温冲击强度，刚性，耐热性和透明性的平衡优异的聚丙烯组合物，其特征在于包含20-95重量％的以下[I]中定义的聚丙烯和5-80重量％ 的以下[II]中定义的丙烯-α-烯烃共聚物：[I]聚丙烯，其特征在于具有：（1）全同立构五单元组比（mmmm）为0.900-0.949，（2）2,1-和 聚合物链中的1,3-丙烯单元的量为0-1摩尔％，（3）重均分子量（Mw）为40,000-1,000,000，（4）重均分子量（Mw） 达到数均分子量（Mn），即（Mw）/（Mn）为1.5-3.8，和（5）在连续或逐步升高到给定温度的邻二氯苯温度下测量洗脱量 聚丙烯在每个温度下，主洗脱峰的位置为95-110℃，组分的存在量在±10℃的范围内 n洗脱峰为在高于0℃的温度下洗脱的组分的总量的至少90％，[II]含有10-90重量％的衍生自丙烯的组分和10重量％的丙烯-α-烯烃共聚物 -90重量％的除丙烯以外的α-烯烃的成分。

公开(公告)号：US06303698B1

公开(公告)日：2001-10-16

申请号：US09486921

申请日：2000-05-09

申请人： Tsutomu Ushioda ,  Jun Saito ,  Mototake Tsutsui ,  Yoshitoyo Yasuda ,  Hiroyuki Fujita ,  Yoshiyuki Ohgi

发明人： Tsutomu Ushioda ,  Jun Saito ,  Mototake Tsutsui ,  Yoshitoyo Yasuda ,  Hiroyuki Fujita ,  Yoshiyuki Ohgi

IPC分类号： C08F21006

CPC分类号： C08F210/06 ,  C08F4/61912 ,  C08F4/61927 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/61916 ,  C08F4/65927 ,  C08F236/20 ,  C08F2500/12 ,  C08F2500/11 ,  C08F2500/03 ,  C08F2500/24 ,  C08F2500/18

摘要： Disclosed is propylene copolymers produced by the aid of a specific metallocene catalyst system, wherein a percentage of mis-insertion in the copolymer is highly controlled and the copolymers possess beat-resisting property and a high melt strength and a low MFR and are narrow in molecular weight distribution excellent in particulate properties as well as a process for producing the copolymers possessing high steroregularity at a practical polymerzation temperature. The gist of the present invention resides in production of propylene copolymers wherein copolymerization with &agr;,&ohgr;-diene is carried out by the aid of a supported-type catalyst system comprised predominantly of the following compound (A), (B), (C) and (D) at a temperature above 45° C.: the compound (A): a specific metallocene compound represented by Q(C5H4−mR1m)(C5H4−nR2n) MXY, the compound (B): an aluminoxane, the compound (C): an organoaluminum compound, and the compound (D): a particulate carrier. An important feature of the propylene copolymers of the present invention resides in the fact that the copolymers are high stereoregular and have a ratio of a mis-inserted unit based on 2,1-insertion of propylene monomer in the total propylene insertion being defined within a specific range.

摘要翻译： 公开了通过特定的茂金属催化剂体系制备的丙烯共聚物，其中共聚物中错误插入的百分比被高度控制，并且共聚物具有抗电阻性能和高熔体强度和低MFR并且分子窄 颗粒性能优异的重量分布以及在实际聚合温度下具有高立体规整性的共聚物的制备方法。 本发明的主旨在于制备丙烯共聚物，其中与α，ω-二烯的共聚合是借助于主要由以下化合物（A），（B），（C）组成的负载型催化剂体系进行的， 化合物（A）：由化合物（B）表示的特定茂金属化合物：铝氧烷，化合物（C）：有机铝化合物和化合物（D）：a 颗粒载体。本发明的丙烯共聚物的一个重要特征在于这样的事实：共聚物是高立构规整性的，并且在总丙烯插入中丙烯单体的2,1-插入比例为错误插入单元 在特定范围内定义。