公开(公告)号：US07341657B2

公开(公告)日：2008-03-11

申请号：US10740807

申请日：2003-12-22

申请人： Dadong Li ,  Yulin Shi ,  Yunjian Hu ,  Yuanbing Xi ,  Mingfeng Li ,  Yahua Shi

发明人： Dadong Li ,  Yulin Shi ,  Yunjian Hu ,  Yuanbing Xi ,  Mingfeng Li ,  Yahua Shi

IPC分类号： C10G65/02

CPC分类号： C10G45/64 ,  C10G2400/02

摘要： Disclosed is a process for reducing sulfur and olefin contents in gasoline, comprising contacting gasoline feedstock and hydrogen with a hydrorefining catalyst and an paraffin-modification catalyst. The effluent of the process is separated to obtain a hydrotreated gasoline fraction free of mercaptan and having a low content of sulfur, e.g. less than 200 ppm, a low content of olefins, e.g. less than 20% by volume, and little octane loss. The hydrotreated gasoline fraction can be used as blending component of a final gasoline product.

摘要翻译： 公开了一种降低汽油中硫和烯烃含量的方法，包括使汽油原料和氢气与加氢精制催化剂和石蜡改性催化剂接触。 将该方法的流出物分离以获得不含硫醇并具有低含量硫的加氢处理汽油馏分， 小于200ppm，低含量的烯烃，例如。 小于20体积％，辛烷值损失小。 加氢处理的汽油馏分可用作最终汽油产品的共混组分。

公开(公告)号：US20050137434A1

公开(公告)日：2005-06-23

申请号：US11016986

申请日：2004-12-21

申请人： Mingfeng Li ,  Yang Chu ,  Yunjian Hu ,  Guofu Xia ,  Hong Nie ,  Yahua Shi ,  Dadong Li

发明人： Mingfeng Li ,  Yang Chu ,  Yunjian Hu ,  Guofu Xia ,  Hong Nie ,  Yahua Shi ,  Dadong Li

IPC分类号： B01J21/04 ,  B01J23/04 ,  B01J23/28 ,  B01J23/30 ,  B01J23/85 ,  B01J23/883 ,  B01J23/887 ,  B01J23/888 ,  B01J37/02 ,  C07C7/163 ,  C10G45/38

CPC分类号： B01J23/85 ,  B01J23/8872 ,  B01J23/888 ,  B01J23/8885 ,  B01J37/0201 ,  C07C7/163 ,  C07C2523/84 ,  C10G2300/104 ,  C10G2300/1088 ,  C10G2300/4018 ,  C10G2400/02

摘要： A catalyst for the selective hydrogenation of olefins especially dienes, its preparation and use, said catalyst comprising an alumina support and cobalt and/or nickel selected from Group VIII, molybdenum and/or tungsten from Group VIB and alkali metal components supported on said support, characterized in that the catalyst contains 0.5-8% by weight of cobalt and/or nickel selected from Group VIII, 2-15% by weight of molybdenum and/or tungsten from Group VIB, over 2-8% by weight of alkali metals, and a balanced amount of alumina support calculated for oxides and based on the catalyst. Compared to the prior catalysts, the activity and selectivity for olefins especially dienes of the catalyst are higher when used in the hydrogenation of a gasoline distillate.

摘要翻译： 用于烯烃特别是二烯的选择性氢化的催化剂及其制备和用途，所述催化剂包含氧化铝载体和选自组VIB的VIII族，钼和/或钨的钴和/或镍和负载在所述载体上的碱金属组分， 其特征在于催化剂含有0.5-8重量％的选自VIII族的钴和/或镍，2-15重量％的来自VIB族的钼和/或钨，超过2-8重量％的碱金属， 和氧化铝的平衡量计算氧化物和催化剂。 与现有催化剂相比，当用于汽油馏分氢化时，烯烃特别是催化剂二烯的活性和选择性较高。

公开(公告)号：US07745372B2

公开(公告)日：2010-06-29

申请号：US11016986

申请日：2004-12-21

申请人： Mingfeng Li ,  Yang Chu ,  Yunjian Hu ,  Guofu Xia ,  Hong Nie ,  Yahua Shi ,  Dadong Li

发明人： Mingfeng Li ,  Yang Chu ,  Yunjian Hu ,  Guofu Xia ,  Hong Nie ,  Yahua Shi ,  Dadong Li

IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00

CPC分类号： B01J23/85 ,  B01J23/8872 ,  B01J23/888 ,  B01J23/8885 ,  B01J37/0201 ,  C07C7/163 ,  C07C2523/84 ,  C10G2300/104 ,  C10G2300/1088 ,  C10G2300/4018 ,  C10G2400/02

摘要： A catalyst for the selective hydrogenation of olefins especially dienes, its preparation and use, said catalyst comprising an alumina support and cobalt and/or nickel selected from Group VIII, molybdenum and/or tungsten from Group VIB and alkali metal components supported on said support, characterized in that the catalyst contains 0.5-8% by weight of cobalt and/or nickel selected from Group VIII, 2-15% by weight of molybdenum and/or tungsten from Group VIB, over 2-8% by weight of alkali metals, and a balanced amount of alumina support calculated for oxides and based on the catalyst. Compared to the prior catalysts, the activity and selectivity for olefins especially dienes of the catalyst are higher when used in the hydrogenation of a gasoline distillate.

摘要翻译： 用于烯烃特别是二烯的选择性氢化的催化剂及其制备和用途，所述催化剂包含氧化铝载体和选自组VIB的VIII族，钼和/或钨的钴和/或镍和负载在所述载体上的碱金属组分， 其特征在于催化剂含有0.5-8重量％的选自VIII族的钴和/或镍，2-15重量％的来自VIB族的钼和/或钨，超过2-8重量％的碱金属， 和氧化铝的平衡量计算氧化物和催化剂。 与现有催化剂相比，当用于汽油馏分氢化时，烯烃特别是催化剂二烯的活性和选择性较高。

公开(公告)号：US20050133410A1

公开(公告)日：2005-06-23

申请号：US10740807

申请日：2003-12-22

申请人： Dadong Li ,  Yulin Shi ,  Yunjian Hu ,  Yuanbing Xi ,  Mingfeng Li ,  Yahua Shi

发明人： Dadong Li ,  Yulin Shi ,  Yunjian Hu ,  Yuanbing Xi ,  Mingfeng Li ,  Yahua Shi

IPC分类号： C10G45/02 ,  C10G45/64 ,  C10G65/02 ,  C10G65/04

CPC分类号： C10G45/64 ,  C10G2400/02

摘要： Disclosed is a process for reducing sulfur and olefin contents in gasoline, comprising contacting gasoline feedstock and hydrogen with a hydrorefining catalyst and an paraffin-modification catalyst. The effluent of the process is separated to obtain a hydrotreated gasoline fraction free of mercaptan and having a low content of sulfur, e.g. less than 200 ppm, a low content of olefins, e.g. less than 20% by volume, and little octane loss. The hydrotreated gasoline fraction can be used as blending component of a final gasoline product.

摘要翻译： 公开了一种降低汽油中硫和烯烃含量的方法，包括使汽油原料和氢气与加氢精制催化剂和石蜡改性催化剂接触。 将该方法的流出物分离以获得不含硫醇并具有低含量硫的加氢处理汽油馏分， 小于200ppm，低含量的烯烃，例如。 小于20体积％，辛烷值损失小。 加氢处理的汽油馏分可用作最终汽油产品的共混组分。