公开(公告)号：US5266397A

公开(公告)日：1993-11-30

申请号：US851910

申请日：1992-03-16

申请人： Masahide Ogawa ,  Kiyoshi Abe ,  Masao Takahashi ,  Yuuzi Washio ,  Kazumitsu Enomoto ,  Toshio Kitsu

发明人： Masahide Ogawa ,  Kiyoshi Abe ,  Masao Takahashi ,  Yuuzi Washio ,  Kazumitsu Enomoto ,  Toshio Kitsu

IPC分类号： B41M5/337 ,  C01B33/154 ,  C08K3/36 ,  C09C1/30 ,  B32B9/00

CPC分类号： C09C1/30 ,  B41M5/3377 ,  B82Y30/00 ,  C01B33/154 ,  C08K3/36 ,  C01P2002/02 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/10 ,  C01P2006/12 ,  C01P2006/19 ,  C01P2006/22 ,  C01P2006/60 ,  C01P2006/80 ,  C01P2006/90 ,  Y10S428/913 ,  Y10T428/24802 ,  Y10T428/24893 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/259

摘要： The amorphous silica has a large apparent specific gravity despite of its BET specific surface area of 20 to 500 m.sup.2 /g, has an oil absorption amount of as small as 50 to 120 ml/100 g, has an agglomeration degree (D1/D0=DA) defined by the ratio of silica elementary particle diameter D0 to primary particle diameter D1 of from 10 to 50, and has nearly a spherical particulate structure which is quite different from that of the conventional gelation method silica (DA=.infin.). The amorphous silica-type filler exhibits excellent properties in regard to handling, processability, dispersion property and abrasion-resistant property and, when added as, for example, an anti-blocking agent, makes it possible to obtain resin films having transparency and scratch-resistant property without fisheyes or voids. Owing to the above properties, the amorphous silica that is used as a filler for the heat-sensitive recording papers suppresses ground fogging, improves the image concentration, makes it possible to apply a highly viscous coating solution since the filler dispersed in an aqueous solution creates very small viscosity, and imparts excellent abrasion resistance to the apparatus during the step of coating.

公开(公告)号：US5384191A

公开(公告)日：1995-01-24

申请号：US95245

申请日：1993-07-22

申请人： Masahide Ogawa ,  Kiyoshi Abe ,  Masao Takahashi ,  Yuuzi Washio ,  Kazumitsu Enomoto ,  Toshio Kitsu

发明人： Masahide Ogawa ,  Kiyoshi Abe ,  Masao Takahashi ,  Yuuzi Washio ,  Kazumitsu Enomoto ,  Toshio Kitsu

IPC分类号： B41M5/337 ,  C01B33/154 ,  C08K3/36 ,  C09C1/30 ,  B32B9/00

CPC分类号： C09C1/30 ,  B41M5/3377 ,  B82Y30/00 ,  C01B33/154 ,  C08K3/36 ,  C01P2002/02 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/10 ,  C01P2006/12 ,  C01P2006/19 ,  C01P2006/22 ,  C01P2006/60 ,  C01P2006/80 ,  C01P2006/90 ,  Y10S428/913 ,  Y10T428/24802 ,  Y10T428/24893 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/259

摘要： The amorphous silica has a large apparent specific gravity despite of its BET specific surface area of 200 to 500 m.sup.2 /g, has an oil-absorption amount of as small as 50 to 120 ml/100 g, has an agglomeration degree (D1/D0=DA) defined by the ratio of silica elementary particle diameter D0 to primary particle diameter D1 of from 10 to 50, and has nearly a spherical particulate structure which is quite different from that of the conventional gelation method silica (DA=.infin.). The amorphous silica-type filler exhibits excellent properties in regard to handling, processability, dispersion property and abrasion-resistant property and, when added as, for example, an anti-blocking agent, makes it possible to obtain resin films having transparency and scratch-resistant property without fisheyes or voids. Owing to the above properties, the amorphous silica that is used as a filler for the heat-sensitive recording papers suppresses ground fogging, improves the image concentration, makes it possible to apply a highly viscous coating solution since the filler dispersed in an aqueous solution creates very small viscosity, and imparts excellent abrasion resistance to the apparatus during the step of coating.

摘要翻译： 无定形二氧化硅的BET比表面积为200〜500m 2 / g，表观比重大，吸油量小至50〜120ml / 100g，具有附聚度（D1 / D0 = DA）由二氧化硅基本粒径D0与一次粒径D1的比例为10〜50定义，并且具有与常规的凝胶化法二氧化硅（DA = INFINITY）相当不同的球状颗粒结构。 无定形二氧化硅型填料在处理，加工性，分散性和耐磨性方面表现出优异的性能，并且当添加作为例如防粘连剂时，可以获得具有透明性和划痕性的树脂膜， 没有鱼眼或空隙的抗性。 由于上述性质，用作热敏记录纸的填料的无定形二氧化硅抑制地面雾化，提高图像浓度，使得可以施加高粘度的涂布溶液，因为分散在水溶液中的填料产生 非常小的粘度，并且在涂布步骤期间赋予装置优异的耐磨性。

公开(公告)号：US5418043A

公开(公告)日：1995-05-23

申请号：US245920

申请日：1994-05-19

申请人： Masahide Ogawa ,  Kiyoshi Abe ,  Masao Takahashi ,  Yuuzi Washio ,  Kazumitsu Enomoto ,  Toshio Kitsu

发明人： Masahide Ogawa ,  Kiyoshi Abe ,  Masao Takahashi ,  Yuuzi Washio ,  Kazumitsu Enomoto ,  Toshio Kitsu

IPC分类号： B41M5/337 ,  C01B33/154 ,  C08K3/36 ,  C09C1/30 ,  B32B3/00

CPC分类号： C09C1/30 ,  B41M5/3377 ,  B82Y30/00 ,  C01B33/154 ,  C08K3/36 ,  C01P2002/02 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/10 ,  C01P2006/12 ,  C01P2006/19 ,  C01P2006/22 ,  C01P2006/60 ,  C01P2006/80 ,  C01P2006/90 ,  Y10S428/913 ,  Y10T428/24802 ,  Y10T428/24893 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/259

摘要： The amorphous silica has a large apparent specific gravity despite of its BET specific surface area of 200 to 500 m.sup.2 /g, has an oil absorption amount of as small as 50 to 120 ml/100 g, has an agglomeration degree (D1/D0=DA) defined by the ratio of silica elementary particle diameter D0 to primary particle diameter D1 of from 10 to 50, and has nearly a spherical particulate structure which is quite different from that of the conventional gelation method silica (DA=OO). The amorphous silica-type filler exhibits excellent properties in regard to handling, processability, dispersion property and abrasion-resistant property and, when added as, for example, an anti-blocking agent, makes it possible to obtain resin films having transparency and scratch-resistant property without fisheyes or voids. Owing to the above properties, the amorphous silica that is used as a filler for the heat-sensitive recording papers suppresses ground fogging, improves the image concentration, makes it possible to apply a highly viscous coating solution since the filler dispersed in an aqueous solution creates very small viscosity, and imparts excellent abrasion resistance to the apparatus during the step of coating.

摘要翻译： 无定形二氧化硅的BET比表面积为200〜500m 2 / g，油吸收量小至50〜120ml / 100g，表观比重大，具有附聚度（D1 / D0 = DA）由二氧化硅基本粒径D0与一次粒径D1的比例为10〜50所定义，并且与现有的凝胶化法二氧化硅（DA = OO）相当差的球状颗粒结构。 无定形二氧化硅型填料在处理，加工性，分散性和耐磨性方面表现出优异的性能，并且当添加作为例如防粘连剂时，可以获得具有透明性和划痕性的树脂膜， 没有鱼眼或空隙的抗性。 由于上述性质，用作热敏记录纸的填料的无定形二氧化硅抑制地面雾化，提高图像浓度，使得可以施加高粘度的涂布溶液，因为分散在水溶液中的填料产生 非常小的粘度，并且在涂布步骤期间赋予装置优异的耐磨性。