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公开(公告)号:US5384191A
公开(公告)日:1995-01-24
申请号:US95245
申请日:1993-07-22
申请人: Masahide Ogawa , Kiyoshi Abe , Masao Takahashi , Yuuzi Washio , Kazumitsu Enomoto , Toshio Kitsu
发明人: Masahide Ogawa , Kiyoshi Abe , Masao Takahashi , Yuuzi Washio , Kazumitsu Enomoto , Toshio Kitsu
IPC分类号: B41M5/337 , C01B33/154 , C08K3/36 , C09C1/30 , B32B9/00
CPC分类号: C09C1/30 , B41M5/3377 , B82Y30/00 , C01B33/154 , C08K3/36 , C01P2002/02 , C01P2004/03 , C01P2004/32 , C01P2004/50 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/10 , C01P2006/12 , C01P2006/19 , C01P2006/22 , C01P2006/60 , C01P2006/80 , C01P2006/90 , Y10S428/913 , Y10T428/24802 , Y10T428/24893 , Y10T428/25 , Y10T428/251 , Y10T428/259
摘要: The amorphous silica has a large apparent specific gravity despite of its BET specific surface area of 200 to 500 m.sup.2 /g, has an oil-absorption amount of as small as 50 to 120 ml/100 g, has an agglomeration degree (D1/D0=DA) defined by the ratio of silica elementary particle diameter D0 to primary particle diameter D1 of from 10 to 50, and has nearly a spherical particulate structure which is quite different from that of the conventional gelation method silica (DA=.infin.). The amorphous silica-type filler exhibits excellent properties in regard to handling, processability, dispersion property and abrasion-resistant property and, when added as, for example, an anti-blocking agent, makes it possible to obtain resin films having transparency and scratch-resistant property without fisheyes or voids. Owing to the above properties, the amorphous silica that is used as a filler for the heat-sensitive recording papers suppresses ground fogging, improves the image concentration, makes it possible to apply a highly viscous coating solution since the filler dispersed in an aqueous solution creates very small viscosity, and imparts excellent abrasion resistance to the apparatus during the step of coating.
摘要翻译: 无定形二氧化硅的BET比表面积为200〜500m 2 / g,表观比重大,吸油量小至50〜120ml / 100g,具有附聚度(D1 / D0 = DA)由二氧化硅基本粒径D0与一次粒径D1的比例为10〜50定义,并且具有与常规的凝胶化法二氧化硅(DA = INFINITY)相当不同的球状颗粒结构。 无定形二氧化硅型填料在处理,加工性,分散性和耐磨性方面表现出优异的性能,并且当添加作为例如防粘连剂时,可以获得具有透明性和划痕性的树脂膜, 没有鱼眼或空隙的抗性。 由于上述性质,用作热敏记录纸的填料的无定形二氧化硅抑制地面雾化,提高图像浓度,使得可以施加高粘度的涂布溶液,因为分散在水溶液中的填料产生 非常小的粘度,并且在涂布步骤期间赋予装置优异的耐磨性。
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公开(公告)号:US5418043A
公开(公告)日:1995-05-23
申请号:US245920
申请日:1994-05-19
申请人: Masahide Ogawa , Kiyoshi Abe , Masao Takahashi , Yuuzi Washio , Kazumitsu Enomoto , Toshio Kitsu
发明人: Masahide Ogawa , Kiyoshi Abe , Masao Takahashi , Yuuzi Washio , Kazumitsu Enomoto , Toshio Kitsu
IPC分类号: B41M5/337 , C01B33/154 , C08K3/36 , C09C1/30 , B32B3/00
CPC分类号: C09C1/30 , B41M5/3377 , B82Y30/00 , C01B33/154 , C08K3/36 , C01P2002/02 , C01P2004/03 , C01P2004/32 , C01P2004/50 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/10 , C01P2006/12 , C01P2006/19 , C01P2006/22 , C01P2006/60 , C01P2006/80 , C01P2006/90 , Y10S428/913 , Y10T428/24802 , Y10T428/24893 , Y10T428/25 , Y10T428/251 , Y10T428/259
摘要: The amorphous silica has a large apparent specific gravity despite of its BET specific surface area of 200 to 500 m.sup.2 /g, has an oil absorption amount of as small as 50 to 120 ml/100 g, has an agglomeration degree (D1/D0=DA) defined by the ratio of silica elementary particle diameter D0 to primary particle diameter D1 of from 10 to 50, and has nearly a spherical particulate structure which is quite different from that of the conventional gelation method silica (DA=OO). The amorphous silica-type filler exhibits excellent properties in regard to handling, processability, dispersion property and abrasion-resistant property and, when added as, for example, an anti-blocking agent, makes it possible to obtain resin films having transparency and scratch-resistant property without fisheyes or voids. Owing to the above properties, the amorphous silica that is used as a filler for the heat-sensitive recording papers suppresses ground fogging, improves the image concentration, makes it possible to apply a highly viscous coating solution since the filler dispersed in an aqueous solution creates very small viscosity, and imparts excellent abrasion resistance to the apparatus during the step of coating.
摘要翻译: 无定形二氧化硅的BET比表面积为200〜500m 2 / g,油吸收量小至50〜120ml / 100g,表观比重大,具有附聚度(D1 / D0 = DA)由二氧化硅基本粒径D0与一次粒径D1的比例为10〜50所定义,并且与现有的凝胶化法二氧化硅(DA = OO)相当差的球状颗粒结构。 无定形二氧化硅型填料在处理,加工性,分散性和耐磨性方面表现出优异的性能,并且当添加作为例如防粘连剂时,可以获得具有透明性和划痕性的树脂膜, 没有鱼眼或空隙的抗性。 由于上述性质,用作热敏记录纸的填料的无定形二氧化硅抑制地面雾化,提高图像浓度,使得可以施加高粘度的涂布溶液,因为分散在水溶液中的填料产生 非常小的粘度,并且在涂布步骤期间赋予装置优异的耐磨性。
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公开(公告)号:US5266397A
公开(公告)日:1993-11-30
申请号:US851910
申请日:1992-03-16
申请人: Masahide Ogawa , Kiyoshi Abe , Masao Takahashi , Yuuzi Washio , Kazumitsu Enomoto , Toshio Kitsu
发明人: Masahide Ogawa , Kiyoshi Abe , Masao Takahashi , Yuuzi Washio , Kazumitsu Enomoto , Toshio Kitsu
IPC分类号: B41M5/337 , C01B33/154 , C08K3/36 , C09C1/30 , B32B9/00
CPC分类号: C09C1/30 , B41M5/3377 , B82Y30/00 , C01B33/154 , C08K3/36 , C01P2002/02 , C01P2004/03 , C01P2004/32 , C01P2004/50 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2006/10 , C01P2006/12 , C01P2006/19 , C01P2006/22 , C01P2006/60 , C01P2006/80 , C01P2006/90 , Y10S428/913 , Y10T428/24802 , Y10T428/24893 , Y10T428/25 , Y10T428/251 , Y10T428/259
摘要: The amorphous silica has a large apparent specific gravity despite of its BET specific surface area of 20 to 500 m.sup.2 /g, has an oil absorption amount of as small as 50 to 120 ml/100 g, has an agglomeration degree (D1/D0=DA) defined by the ratio of silica elementary particle diameter D0 to primary particle diameter D1 of from 10 to 50, and has nearly a spherical particulate structure which is quite different from that of the conventional gelation method silica (DA=.infin.). The amorphous silica-type filler exhibits excellent properties in regard to handling, processability, dispersion property and abrasion-resistant property and, when added as, for example, an anti-blocking agent, makes it possible to obtain resin films having transparency and scratch-resistant property without fisheyes or voids. Owing to the above properties, the amorphous silica that is used as a filler for the heat-sensitive recording papers suppresses ground fogging, improves the image concentration, makes it possible to apply a highly viscous coating solution since the filler dispersed in an aqueous solution creates very small viscosity, and imparts excellent abrasion resistance to the apparatus during the step of coating.
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公开(公告)号:US4892591A
公开(公告)日:1990-01-09
申请号:US202804
申请日:1988-06-03
申请人: Masahide Ogawa , Teiji Sato , Masao Takahashi , Kazumitsu Enomoto
发明人: Masahide Ogawa , Teiji Sato , Masao Takahashi , Kazumitsu Enomoto
CPC分类号: B41M5/5218 , C01B33/16 , C09C1/30 , C01P2002/02 , C01P2004/61 , C01P2004/80 , C01P2006/12 , C01P2006/14 , C01P2006/19 , C01P2006/60 , C01P2006/90
摘要: Disclosed is a filler for ink jet recording paper, said filler being composed of amorphous silica particles having a median diameter, measured by the coulter counter method, of 2 to 15 .mu.m, an oil absorption of at least 180 ml/100 g, a refractive index, measured by the solvent method, of at least 1.450, and a moisture absorption, measured when it is caused to absorb moisture for 200 hours at a relative humidity of 90% and a temperature of 25.degree. C., of at least 35%, and a coating of a compound of a metal of Group II of the periodic table on the surface of the silica particles in an amount of 0.5 to 20% by weight.
摘要翻译: 公开了一种用于喷墨记录纸的填料,所述填料由具有中间直径的无定形二氧化硅颗粒组成,通过粗铣计数法测量为2至15μm,吸油量至少为180ml / 100g, 通过溶剂法测定的折射率为至少1.450,并且当在相对湿度为90%和25℃的温度下吸收水分200小时时测量的吸湿性为至少35 %,二氧化硅颗粒表面的II族金属化合物的涂层量为0.5〜20重量%。
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