公开(公告)号：US4216024A

公开(公告)日：1980-08-05

申请号：US962205

申请日：1978-11-20

申请人： Sergei S. Ivanchev ,  Nikolai S. Enikolopov ,  Boris V. Polozov ,  Anatoly A. Syrov ,  Oleg N. Primachenko ,  Zorislav N. Polyakov

发明人： Sergei S. Ivanchev ,  Nikolai S. Enikolopov ,  Boris V. Polozov ,  Anatoly A. Syrov ,  Oleg N. Primachenko ,  Zorislav N. Polyakov

IPC分类号： C08K9/00 ,  C03C17/30 ,  C03C25/40 ,  C07F7/08 ,  C08F2/00 ,  C08F2/44 ,  C08K9/06 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L51/00 ,  C08L51/02 ,  C08L101/00 ,  C09C1/28 ,  C09C1/30 ,  C09C1/40 ,  C09C3/00 ,  C09C3/12

CPC分类号： C09C3/12 ,  C03C17/30 ,  C03C25/40 ,  C08K9/06 ,  C09C1/3081 ,  C09C1/40 ,  C01P2004/84 ,  Y10T428/2995 ,  Y10T428/2996

摘要： The process for producing mineral fillers with graft peroxy groups for polymers according to the present invention comprises treatment of mineral fillers, at a temperature of from 50 to 150.degree. C. under a pressure of from 1.33.10.sup.2 to 4.10.sup.5 Pa (lmmHg to 4 atm), with an organosilicon compound of the formula:R.sub.4-y SiX.sub.y or R'R.sub.3-z SiX.sub.z, whereinR is vinyl, allyl, norbornyl,X is chlorine, an alkoxy or acyloxy,y=1-3,z=1-2,R' is methyl, ethyl, propyl,whereafter the mineral filler containing graft unsaturated groups is separated from the reaction mixture, dried and ozonized with an ozone-oxygen mixture containing 4 to 6 vol.% of ozone at a temperature of from -40.degree. to +20.degree. C.The process for producing mineral fillers with graft peroxy groups for polymers is technologically simple and makes it possible to perform extending and grafting of a polymer at lower temperatures (50.degree.-140.degree. C.).

摘要翻译： 用于生产根据本发明的用于聚合物的接枝过氧基团的矿物填料的方法包括在50-150℃的温度下在1.33.102至4.105Pa（1mmHg至4atm）的压力下处理矿物填料 ）与下式的有机硅化合物：R4-ySiXy或R'R3-zSiXz，其中R是乙烯基，烯丙基，降冰片基，X是氯，烷氧基或酰氧基，y = 1-3，z = 1-2， R'是甲基，乙基，丙基，然后从反应混合物中分离含有接枝不饱和基团的矿物填料，在-40℃的温度下用含有4至6体积％臭氧的臭氧 - 氧混合物进行干燥和臭氧化 到+ 20℃。用于生产用于聚合物的接枝过氧基团的矿物填料的方法在技术上是简单的，并且可以在较低的温度（50-140℃）下进行聚合物的延伸和接枝。

公开(公告)号：US4214914A

公开(公告)日：1980-07-29

申请号：US962191

申请日：1978-11-20

申请人： Sergei S. Ivanchev ,  Nikolai S. Enikolopov ,  Boris V. Polozov ,  Anatoly A. Syrov ,  Oleg N. Primachenko ,  Zorislav N. Polyakov

发明人： Sergei S. Ivanchev ,  Nikolai S. Enikolopov ,  Boris V. Polozov ,  Anatoly A. Syrov ,  Oleg N. Primachenko ,  Zorislav N. Polyakov

IPC分类号： C08K9/00 ,  C03C17/30 ,  C03C25/40 ,  C07F7/08 ,  C08K9/06 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L51/00 ,  C08L51/02 ,  C08L101/00 ,  C09C1/28 ,  C09C1/30 ,  C09C1/40 ,  C09C3/12

CPC分类号： C03C17/30 ,  C03C25/40 ,  C08K9/06 ,  C09C1/3081 ,  C09C1/40 ,  C09C3/12 ,  C01P2004/84 ,  Y10T428/2995 ,  Y10T428/2996

摘要： According to the invention, the method for producing mineral polymer fillers containing graft hydroperoxide groups consists in treating mineral fillers at a temperature of 50.degree. to 150.degree. C. and a pressure of 1.33.10.sup.2 to 4.10.sup.5 Pa (1 mm Hg to 4 atm) with organosilicon compounds of the general formula:R.sub.4-y SiX.sub.yorR'R.sub.3-z SiX.sub.z,whereR is vinyl, allyl or norbornyl,X is chlorine, alkoxy or acyloxy,y=1-3,z=1-2,R' is methyl, ethyl or propyl,whereupon the mineral filler containing graft unsaturated groups is separated from the reaction mixture, dried and ozonized with an ozone-oxygen mixture containing 4 to 6 percent by volume of ozone at a temperature of -20.degree. C. to +20.degree. C. in an aliphatic saturated monohydric alcohol or aliphatic saturated monohydric acid.The method for producing mineral polymer fillers containing graft hydroperoxide groups is quite simple and makes it possible to carry out the filling and grafting of polymers at a reduced temperature of 50.degree. to 140.degree. C.

摘要翻译： 根据本发明，用于生产含有接枝氢过氧化物基团的矿物聚合物填料的方法包括在50至150℃的温度和1.33.102至4.105Pa（1mmHg至4atm）的压力下处理矿物填料， 具有以下通式的有机硅化合物：R4-ySiXy或R'R3-zSiXz，其中R是乙烯基，烯丙基或降冰片基，X是氯，烷氧基或酰氧基，y = 1-3，z = 1-2，R' 甲基，乙基或丙基，随后将含有接枝不饱和基团的矿物填料从反应混合物中分离出来，干燥并用含有4至6体积％臭氧的臭氧 - 氧混合物在-20℃至+ 20℃下在脂族饱和一元醇或脂族饱和一元酸中。 含有接枝氢过氧化物基团的矿物聚合物填料的制造方法相当简单，可以在50〜140℃的降温下进行聚合物的填充和接枝。