-
公开(公告)号:US20180194922A1
公开(公告)日:2018-07-12
申请号:US15751575
申请日:2016-07-29
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Ryan E. Marx , Jay R. Lomeda , Wendy L. Thompson , Gezahegn D. Damte , Kent S. Tarbutton , Armin Kayser
CPC classification number: C08K3/34 , B82Y30/00 , C01B32/956 , C01P2004/64 , C08K3/14 , C08K9/06 , C08L75/02 , C08L75/08 , C08L2201/08 , C08L2203/16 , C08L75/00
Abstract: Polyurethane/urea nanocomposites, precursors thereof, and methods of their manufacture and use are provided, the nanocomposites comprising: a) a polyurethane/urea polymer matrix, and b) surface modified silicon carbide nanoparticles dispersed within and covalently bound to a polyurethane/urea polymer comprising the polyurethane/urea polymer matrix. In some embodiments, the surface modified silicon carbide nanoparticle comprises a silicon carbide core and a linking group covalently bound to the surface of the silicon carbide core and covalently bound to the polyurethane/urea polymer. In some embodiments, the linking group is a moiety according to Formula where the urethane group of the linking group is covalently bound to the polyurethane/urea polymer; and where each open valence of the silicon atom of the linking group is bound to a hydroxyl group (—OH) or is covalently bound to the surface of the silicon carbide core through an oxygen atom.