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公开(公告)号：US20220152578A1
公开(公告)日：2022-05-19
申请号：US17486482
申请日：2021-09-27
摘要： An activated carbon sorbent composition comprising activated carbon and a passivation agent, wherein the activated carbon sorbent composition exhibits reduced self-heating or auto-ignition properties as compared to the activated carbon. The activated carbon sorbent composition may be utilized to sequester contaminants such as mercury from a flue gas stream. The passivation agent includes a sulfur species, and may be a sulfur oxide compound, a sulfide compound, or an organic sulfur compound. Methods for the manufacture of the activated carbon sorbent composition and for the sequestration of contaminants in a flue gas stream using the composition are also disclosed.
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2.发明申请公开(公告)号：US20180029006A1
公开(公告)日：2018-02-01
申请号：US15729347
申请日：2017-10-10
CPC分类号： B01J20/02 , B01D53/025 , B01D53/10 , B01D53/64 , B01D53/83 , B01D2251/108 , B01D2253/102 , B01D2257/602 , B01D2258/0283 , B01J20/20 , B01J20/28016 , B01J20/28061 , B01J20/28071 , B01J20/3204 , B01J20/3234 , B01J20/3293
摘要： Methods for the manufacture of sorbent compositions, sorbent compositions and methods for using the sorbent compositions. The methods include the utilization of an acidic halogen solution as a source of a halogen species that is dispersed on a solid sorbent. The use of the acidic halogen solution results in a highly active halogen species that demonstrates improved efficacy for the removal of heavy metal(s) from a flue gas. The sorbent composition includes a substantially amorphous halogen species associated with a solid sorbent such as powdered activated carbon (PAC).
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3.发明申请METHOD FOR TREATING A FLUE GAS STREAM WITH A SORBENT COMPOSITION HAVING PNEUMATIC CONVEYANCE CAPABILITIES 有权用具有气动输送能力的吸附组合物处理烟气流的方法公开(公告)号：US20160220945A1
公开(公告)日：2016-08-04
申请号：US15093930
申请日：2016-04-08
IPC分类号： B01D53/10
CPC分类号： B01D53/10 , B01D53/64 , B01D53/83 , B01D2253/102 , B01D2253/304 , B01D2257/504 , B01D2257/602 , B01J20/20 , B01J20/28004
摘要： Sorbent compositions including sorbent particles of a small particle sized sorbent with increased pneumatic conveyance properties. The sorbent compositions have relatively small median particle size and have a controlled particle size distribution (PSD). Specifically, the sorbent compositions include a relatively small percentage of very fine particles, such as a small percentage of particles having a particle size of not greater than about 5 μm. The sorbent compositions are particularly useful for the treatment of a flue gas stream to remove mercury from the flue gas stream.
摘要翻译： 吸附剂组合物包括具有增加的气动输送性能的小粒径吸附剂的吸附剂颗粒。 吸附剂组合物具有相对小的中值粒度并且具有受控的粒度分布（PSD）。 具体地，吸附剂组合物包括相对小百分比的非常细的颗粒，例如粒径不大于约5μm的小百分比的颗粒。 吸附剂组合物特别可用于处理烟道气流以从烟道气流中除去汞。
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4.发明申请公开(公告)号：US20220314193A1
公开(公告)日：2022-10-06
申请号：US17559892
申请日：2021-12-22
摘要： Methods for the manufacture of sorbent compositions, sorbent compositions and methods for using the sorbent compositions. The methods include the utilization of an acidic halogen solution as a source of a halogen species that is dispersed on a solid sorbent. The use of the acidic halogen solution results in a highly active halogen species that demonstrates improved efficacy for the removal of heavy metal(s) from a flue gas. The sorbent composition includes a substantially amorphous halogen species associated with a solid sorbent such as powdered activated carbon (PAC).
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5.发明授权公开(公告)号：US11219878B2
公开(公告)日：2022-01-11
申请号：US15237089
申请日：2016-08-15
IPC分类号： B01J20/20 , B01J20/02 , B01J20/28 , B01J20/32 , B01D53/64 , B01D53/02 , B01J20/10 , B01D53/83 , B01D53/10
摘要： Methods for the manufacture of sorbent compositions, sorbent compositions and methods for using the sorbent compositions. The methods include the utilization of an acidic halogen solution as a source of a halogen species that is dispersed on a solid sorbent. The use of the acidic halogen solution results in a highly active halogen species that demonstrates improved efficacy for the removal of heavy metal(s) from a flue gas. The sorbent composition includes a substantially amorphous halogen species associated with a solid sorbent such as powdered activated carbon (PAC).
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6.发明申请公开(公告)号：US20200324273A1
公开(公告)日：2020-10-15
申请号：US16911161
申请日：2020-06-24
发明人： Joseph M. Wong , Christopher Vizcaino , Robert B. Huston , Frederick S. Cannon , Jacob B. Lowring , Jacqueline Cecil de Peyer
摘要： A multi-functional composition of matter that is useful for injection into a flue gas stream to rapidly and efficiently remove mercury from the flue gas streams, particularly at above average flue stream temperatures of about 340° F. or higher. The multi-functional composition of matter may include a fixed carbon content of at least about 20 wt. %, a mineral content of from about 20 wt. % to about 50 wt. %, a sum of micropore plus mesopore volume of at least about 0.20 cc/g, a micropore volume to mesopore volume ratio of at least about 0.7, and a tapped density of not greater than about 0.575 g/ml. These compositions may be further characterized by number of particles per gram of the composition of matter such that the composition may have at least about 0.8 billion particles per gram, or even as many as 1.5 billion particles per gram. These physical and chemical properties may enhance (1) the oxidation reaction kinetics for the oxidation of mercury species, (2) frequency of contact events, and (3) capture and sequestration of mercury, to achieve efficient mercury capture by the composition even in high temperature flue gas streams.
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7.发明授权公开(公告)号：US10780396B2
公开(公告)日：2020-09-22
申请号：US15729308
申请日：2017-10-10
IPC分类号： B01D53/86 , B01J21/18 , B01D53/64 , B01J35/02 , B01J20/28 , B01J20/20 , B01D53/83 , B01J27/122 , B01J27/128 , B01J37/02 , B01J27/053 , B01J27/055 , B01J35/00 , B01J35/10
摘要： A sorbent composition that is useful for injection into a flue gas stream of a coal burning furnace to efficiently remove mercury from the flue gas stream. The sorbent composition may include a sorbent with an associated ancillary catalyst component that is a catalytic metal, a precursor to a catalytic metal, a catalytic metal compound or a precursor to a catalytic metal compound. Alternatively, a catalytic metal or metal compound, or their precursors, may be admixed with the coal feedstock prior to or during combustion in the furnace, or may be independently injected into a flue gas stream. A catalytic promoter may also be used to enhance the performance of the catalytic metal or metal compound.
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公开(公告)号：US09314767B2
公开(公告)日：2016-04-19
申请号：US14201398
申请日：2014-03-07
CPC分类号： B01D53/10 , B01D53/64 , B01D53/83 , B01D2253/102 , B01D2253/304 , B01D2257/504 , B01D2257/602 , B01J20/20 , B01J20/28004
摘要： Sorbent compositions including sorbent particles of a small particle sized sorbent with increased pneumatic conveyance properties. The sorbent compositions have relatively small median particle size and have a controlled particle size distribution (PSD). Specifically, the sorbent compositions include a relatively small percentage of very fine particles, such as a small percentage of particles having a particle size of not greater than about 5 μm. The sorbent compositions are particularly useful for the treatment of a flue gas stream to remove mercury from the flue gas stream.
摘要翻译： 吸附剂组合物包括具有增加的气动输送性能的小粒径吸附剂的吸附剂颗粒。 吸附剂组合物具有相对小的中值粒度并且具有受控的粒度分布（PSD）。 具体地，吸附剂组合物包括相对小百分比的非常细的颗粒，例如粒径不大于约5μm的小百分比的颗粒。 吸附剂组合物特别可用于处理烟道气流以从烟道气流中除去汞。
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公开(公告)号：US20150251159A1
公开(公告)日：2015-09-10
申请号：US14201398
申请日：2014-03-07
CPC分类号： B01D53/10 , B01D53/64 , B01D53/83 , B01D2253/102 , B01D2253/304 , B01D2257/504 , B01D2257/602 , B01J20/20 , B01J20/28004
摘要： Sorbent compositions including sorbent particles of a small particle sized sorbent with increased pneumatic conveyance properties. The sorbent compositions have relatively small median particle size and have a controlled particle size distribution (PSD). Specifically, the sorbent compositions include a relatively small percentage of very fine particles, such as a small percentage of particles having a particle size of not greater than about 5 μm. The sorbent compositions are particularly useful for the treatment of a flue gas stream to remove mercury from the flue gas stream.
摘要翻译： 吸附剂组合物包括具有增加的气动输送性能的小粒径吸附剂的吸附剂颗粒。 吸附剂组合物具有相对小的中值粒度并且具有受控的粒度分布（PSD）。 具体地，吸附剂组合物包括相对小百分比的非常细的颗粒，例如粒径不大于约5μm的小百分比的颗粒。 吸附剂组合物特别可用于处理烟道气流以从烟道气流中除去汞。
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10.发明申请公开(公告)号：US20140186625A1
公开(公告)日：2014-07-03
申请号：US13730490
申请日：2012-12-28
CPC分类号： B01J20/20 , B01D53/002 , B01D53/10 , B01D53/685 , B01D53/8665 , B01D2251/602 , B01D2251/604 , B01D2251/606 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2255/2092 , B01D2255/2094 , B01D2258/0283 , B01J20/0248 , B01J20/0251 , B01J20/0277 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/18 , B01J20/28004 , B01J20/3085 , B01J20/3204 , B01J20/3236 , B01J2220/42 , Y10T428/2982
摘要： Method and compositions useful for removal of mercury from a flue gas stream with relatively high concentrations of acid gas precursors and/or acid gases. The method includes contacting the flue gas stream with a multi-functional agent, where the multi-functional agent includes a salt having a cation of valency 3 or higher. A composition comprises a (1) sorbent material such as powdered activated carbon which will ultimately capture and sequester oxidized mercury, (2) a multi-functional agent that protects the sorbent core from unfavorable reaction conditions or inhibitors, oxidizes or helps catalyze the oxidation of elemental mercury, and/or amalgamates with elemental mercury to make it easier to capture, among other benefits, and optionally (3) a halogen such as in the form of a halide salt that helps facilitate the oxidation of elemental mercury into its oxidized form.
摘要翻译： 用于从具有相对高浓度的酸性气体前体和/或酸性气体的烟道气流中除去汞的方法和组合物。 该方法包括使烟气流与多官能试剂接触，其中多官能试剂包括具有3或更高的阳离子的盐。 组合物包含（1）吸附剂材料，例如粉末状活性炭，其将最终捕获和螯合氧化的汞，（2）多官能试剂，其保护吸附剂芯不受不利的反应条件或抑制剂，氧化或有助于催化氧化 元素汞和/或具有元素汞的汞合金，以使其更容易捕获以及其它益处，以及任选地（3）卤素，例如卤化物形式的卤素，这有助于元素汞氧化为氧化形式。
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