Production method for stabilized olefin resin composition

    公开(公告)号:US11613628B2

    公开(公告)日:2023-03-28

    申请号:US16490378

    申请日:2018-02-28

    Abstract: Provided is a production method that can produce an olefin resin composition having excellent long-term stability and providing a sufficient stabilization effect to the olefin resin composition. This production method is a method of producing an olefin resin composition that contains a polyolefin resin polymerized with, an addition of a mixture of a phenolic antioxidant represented by the following Formula (1) and a phosphite compound represented by the following Formula (2) or (3), and an organoaluminum compound or a mixed solvent of an organoaluminum compound and an organic solvent, to a catalyst system or a polymerization system before or during the polymerization of the olefin monomer.

    Olefin-based resin composition, manufacturing method therefor, and molded article thereof

    公开(公告)号:US11339231B2

    公开(公告)日:2022-05-24

    申请号:US16763370

    申请日:2018-11-07

    Abstract: Provided are: an olefin-based resin composition that can yield a molded article having excellent transparency in which coloration is inhibited; a method for producing the olefin-based resin composition; and a molded article of the olefin-based resin composition. The olefin-based resin composition contains, with respect to 100 parts by mass of an olefin polymer: 0.001 to 10 parts by mass of one or more compounds (A) represented by Formula (1) wherein R1 to R4 each independently represent a hydrogen atom or an alkyl group having 1 to 9 carbon atoms; R5 represents a hydrogen atom or methyl; m represents 1 or 2; and M1 represents, for example, a hydrogen atom; and 0.001 to 10 parts by mass of a fatty acid metal salt (B) represented by Formula (2) wherein R6 represents a group having 10 to 30 carbon atoms and introduced from an aliphatic organic acid; n represents 1 or 2; and M2 represents an alkali metal atom or a multivalent metal inorganic group. In the olefin-based resin composition, an aluminum content in the olefin polymer is 0.01 mol or less per 1 kg of the olefin polymer.

    Stabilizer composition, resin composition, and molded product using same
    3.
    发明授权
    Stabilizer composition, resin composition, and molded product using same 有权
    稳定剂组合物,树脂组合物和使用其的成型体

    公开(公告)号:US09212307B2

    公开(公告)日:2015-12-15

    申请号:US14396986

    申请日:2013-05-23

    CPC classification number: C09K15/14 C08K5/375 C08L101/00 C08L23/06

    Abstract: The present invention provides a stabilizer composition comprising a monoester and diester of alkylmercapto carboxylic acid of bisphenol sulfide, which is capable of maintaining good ease of handling without causing precipitation of solids even in low temperature environments. The stabilizer composition according to the present invention comprises: a diester represented by the following Formula (1): (wherein, R1, R2 and R3 each independently represent a hydrogen atom or the like; and R4 and R5 each independently represent a linear or branched alkyl group having 3 to 30 carbon atoms which is optionally substituted); and a monoester represented by the following Formula (2): (wherein, R1, R2 and R3 each independently represent a hydrogen atom or the like; and R6 represents a linear or branched alkyl group having 3 to 30 carbon atoms which is optionally substituted) wherein the content of the diester represented by the Formula (1) is more than 65 parts by mass and less than 80 parts by mass in a total of 100 parts by mass of the diester represented by the Formula (1) and the monoester represented by the Formula (2).

    Abstract translation: 本发明提供一种稳定剂组合物,其包含双酚硫化物的烷基巯基羧酸的单酯和二酯,即使在低温环境中也能保持良好的操作便利性而不引起固体沉淀。 根据本发明的稳定剂组合物包含:由下式(1)表示的二酯:(其中,R 1,R 2和R 3各自独立地表示氢原子等; R 4和R 5各自独立地表示直链或支链 任选取代的具有3-30个碳原子的烷基); 和由下式(2)表示的单酯:(其中,R 1,R 2和R 3各自独立地表示氢原子等; R 6表示任选被取代的碳原子数为3〜30的直链或支链烷基) 其中由式(1)表示的二酯的含量相对于由式(1)表示的二酯100质量份和由式(1)表示的单酯的总量超过65质量份且小于80质量份, 公式(2)。

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