公开(公告)号：US10577483B2

公开(公告)日：2020-03-03

申请号：US14400276

申请日：2013-05-07

申请人： ADEKA CORPORATION

发明人： Takuya Maeda ,  Atsushi Sakai ,  Naoko Tanji ,  Naoshi Kawamoto

IPC分类号： B65D1/02 ,  C08K5/527 ,  C08L23/16 ,  C08K5/00 ,  C08K5/098

摘要： Provided is a clarifying agent composition which is capable of yielding a molded article having excellent transparency whose initial coloration is suppressed. The clarifying agent composition is characterized by comprising 1.0 to 10 parts by mass of a colorant with respect to 100 parts by mass of a clarifying agent represented by the following Formula (1): (wherein, R1 to R4 each independently represent a hydrogen atom or an alkyl group having 1 to 9 carbon atoms; R5 represents a hydrogen atom or a methyl group; n represents 1 or 2; and M represents an alkali metal when n is 1, or Al(OH) when n is 2).

公开(公告)号：US20150152248A1

公开(公告)日：2015-06-04

申请号：US14407494

申请日：2013-05-30

申请人： ADEKA CORPORATION

发明人： Naoshi Kawamoto ,  Takashi Ayabe ,  Atsushi Sakai ,  Tetsuya Seguchi

IPC分类号： C08K5/56 ,  C08J3/22 ,  C08K5/20 ,  C08F2/44

CPC分类号： C08K5/56 ,  C08F2/44 ,  C08F110/06 ,  C08J3/22 ,  C08J5/18 ,  C08J2323/12 ,  C08J2423/12 ,  C08K5/0083 ,  C08K5/20 ,  C08K5/527 ,  C08F10/00 ,  C08L23/12

摘要： Provided is a method of producing a nucleator masterbatch, by which a nucleator masterbatch capable of improving the transparency and the physical properties of an olefin resin can be produced. This method is a method of producing a masterbatch in which a nucleator is blended in an olefin polymer, the method being characterized by comprising the step of polymerizing an olefin monomer with incorporation of a nucleator component, which is dissolved in an organoaluminum compound or in an organoaluminum compound and an organic solvent, before or during polymerization of the olefin monomer such that the nucleator component is blended in an amount of 0.05 to 20 parts by mass with respect to 100 parts by mass of the olefin polymer obtained by the polymerization of the olefin monomer.

摘要翻译： 提供一种生产成核剂母料的方法，通过该方法可以制备能够提高烯烃树脂的透明度和物理性能的成核剂母料。 该方法是一种生产母体的方法，其中将成核剂混合在烯烃聚合物中，该方法的特征在于包括使烯烃单体聚合并引入成核剂组分的步骤，所述成核剂组分溶于有机铝化合物或在 有机铝化合物和有机溶剂，在烯烃单体聚合之前或期间，相对于100质量份通过烯烃聚合得到的烯烃聚合物，将成核剂组分的配合量为0.05〜20质量份 单体。

公开(公告)号：US20150096918A1

公开(公告)日：2015-04-09

申请号：US14400276

申请日：2013-05-07

申请人： ADEKA CORPORATION

发明人： Takuya Maeda ,  Atsushi Sakai ,  Naoko Tanji ,  Naoshi Kawamoto

IPC分类号： C08K5/527 ,  B65D1/02

摘要： Provided is a clarifying agent composition which is capable of yielding a molded article having excellent transparency whose initial coloration is suppressed. The clarifying agent composition is characterized by comprising 1.0 to 10 parts by mass of a colorant with respect to 100 parts by mass of a clarifying agent represented by the following Formula (1): (wherein, R1 to R4 each independently represent a hydrogen atom or an alkyl group having 1 to 9 carbon atoms; R5 represents a hydrogen atom or a methyl group; n represents 1 or 2; and M represents an alkali metal when n is 1, or Al(OH) when n is 2).

摘要翻译： 提供一种澄清剂组合物，其能够产生具有优异的透明度的模制品，其初始着色被抑制。 澄清剂组合物的特征在于，相对于100质量份由下式（1）表示的澄清剂，含有1.0〜10质量份着色剂：（其中，R 1〜R 4各自独立地表示氢原子或 具有1至9个碳原子的烷基; R 5表示氢原子或甲基; n表示1或2; M表示n为1时的碱金属或n为2时的Al（OH））。

公开(公告)号：US20140364563A1

公开(公告)日：2014-12-11

申请号：US14366920

申请日：2012-12-07

申请人： ADEKA CORPORATION

发明人： Naoshi Kawamoto ,  Tsuyoshi Urushihara ,  Tetsuya Seguchi ,  Kohei Okamoto

IPC分类号： C08K5/56 ,  C08K5/52 ,  C08K5/13

CPC分类号： C08K5/56 ,  C08K5/13 ,  C08K5/49 ,  C08K5/52 ,  C08L23/02

摘要： The present invention provides a method of producing an olefin resin composition by which an olefin resin composition in which reduction in the physical properties and occurrence of yellowing after a sterilization treatment by irradiation with radiation are suppressed can be produced.The method of producing an olefin resin composition according to the present invention is a method of producing an olefin resin composition for a molded article to be used after a sterilization treatment by irradiation with radiation, the method comprising: blending, before or during polymerization of an olefin monomer, a phenolic antioxidant, which is represented by the following Formula (1) and masked with an organoaluminum compound, in an amount of 0.001 to 0.5 parts by mass with respect to 100 parts by mass of an olefin resin obtained by the polymerization; and blending, at any one point of before, during or after the polymerization of the olefin monomer, a phosphorus-based antioxidant in an amount of 0.001 to 3 parts by mass with respect to 100 parts by mass of the olefin resin obtained by the polymerization: (wherein, R represents, for example, an alkyl group having 12 to 24 carbon atoms which is optionally branched and/or substituted).

摘要翻译： 本发明提供了一种制备烯烃树脂组合物的方法，通过该方法可以制备抑制通过照射辐射消毒处理后物理性能降低和发黄的烯烃树脂组合物。 本发明的烯烃系树脂组合物的制造方法是在辐射照射后的灭菌处理后使用的成型体用烯烃系树脂组合物的制造方法，其特征在于， 相对于100质量份通过聚合获得的烯烃树脂，以0.001〜0.5质量份的量，由下式（1）表示的酚类抗氧化剂和有机铝化合物掩蔽的酚类抗氧化剂; 在烯烃单体的聚合之前，之前或之后的任意一点，相对于100质量份通过聚合得到的烯烃树脂，以0.001〜3质量份的量配合磷系抗氧化剂 （其中，R表示例如可以具有支链和/或取代的碳原子数为12〜24的烷基）。

公开(公告)号：US20150119513A1

公开(公告)日：2015-04-30

申请号：US14396986

申请日：2013-05-23

申请人： ADEKA CORPORATION

发明人： Naoshi Kawamoto ,  Yoshinori Negishi ,  Takashi Ayabe ,  Tsuyoshi Urushihara ,  Tomomasa Teduka ,  Shingo Yamada

IPC分类号： C09K15/14

CPC分类号： C09K15/14 ,  C08K5/375 ,  C08L101/00 ,  C08L23/06

摘要： The present invention provides a stabilizer composition comprising a monoester and diester of alkylmercapto carboxylic acid of bisphenol sulfide, which is capable of maintaining good ease of handling without causing precipitation of solids even in low temperature environments. The stabilizer composition according to the present invention comprises: a diester represented by the following Formula (1): (wherein, R1, R2 and R3 each independently represent a hydrogen atom or the like; and R4 and R5 each independently represent a linear or branched alkyl group having 3 to 30 carbon atoms which is optionally substituted); and a monoester represented by the following Formula (2): (wherein, R1, R2 and R3 each independently represent a hydrogen atom or the like; and R6 represents a linear or branched alkyl group having 3 to 30 carbon atoms which is optionally substituted) wherein the content of the diester represented by the Formula (1) is more than 65 parts by mass and less than 80 parts by mass in a total of 100 parts by mass of the diester represented by the Formula (1) and the monoester represented by the Formula (2).

摘要翻译： 本发明提供一种稳定剂组合物，其包含双酚硫化物的烷基巯基羧酸的单酯和二酯，即使在低温环境中也能保持良好的操作便利性而不引起固体沉淀。 根据本发明的稳定剂组合物包含：由下式（1）表示的二酯：（其中，R 1，R 2和R 3各自独立地表示氢原子等; R 4和R 5各自独立地表示直链或支链 任选取代的具有3-30个碳原子的烷基）; 和由下式（2）表示的单酯：（其中，R 1，R 2和R 3各自独立地表示氢原子等; R 6表示任选被取代的碳原子数3〜30的直链或支链烷基） 其中由式（1）表示的二酯的含量相对于由式（1）表示的二酯100质量份和由式（1）表示的单酯的总量超过65质量份且小于80质量份， 公式（2）。

公开(公告)号：US09212307B2

公开(公告)日：2015-12-15

申请号：US14396986

申请日：2013-05-23

申请人： ADEKA CORPORATION

发明人： Naoshi Kawamoto ,  Yoshinori Negishi ,  Takashi Ayabe ,  Tsuyoshi Urushihara ,  Tomomasa Tezuka ,  Shingo Yamada

IPC分类号： C09K15/14 ,  C08K5/375 ,  C08L101/00

CPC分类号： C09K15/14 ,  C08K5/375 ,  C08L101/00 ,  C08L23/06

摘要： The present invention provides a stabilizer composition comprising a monoester and diester of alkylmercapto carboxylic acid of bisphenol sulfide, which is capable of maintaining good ease of handling without causing precipitation of solids even in low temperature environments. The stabilizer composition according to the present invention comprises: a diester represented by the following Formula (1): (wherein, R1, R2 and R3 each independently represent a hydrogen atom or the like; and R4 and R5 each independently represent a linear or branched alkyl group having 3 to 30 carbon atoms which is optionally substituted); and a monoester represented by the following Formula (2): (wherein, R1, R2 and R3 each independently represent a hydrogen atom or the like; and R6 represents a linear or branched alkyl group having 3 to 30 carbon atoms which is optionally substituted) wherein the content of the diester represented by the Formula (1) is more than 65 parts by mass and less than 80 parts by mass in a total of 100 parts by mass of the diester represented by the Formula (1) and the monoester represented by the Formula (2).

摘要翻译： 本发明提供一种稳定剂组合物，其包含双酚硫化物的烷基巯基羧酸的单酯和二酯，即使在低温环境中也能保持良好的操作便利性而不引起固体沉淀。 根据本发明的稳定剂组合物包含：由下式（1）表示的二酯：（其中，R 1，R 2和R 3各自独立地表示氢原子等; R 4和R 5各自独立地表示直链或支链 任选取代的具有3-30个碳原子的烷基）; 和由下式（2）表示的单酯：（其中，R 1，R 2和R 3各自独立地表示氢原子等; R 6表示任选被取代的碳原子数为3〜30的直链或支链烷基） 其中由式（1）表示的二酯的含量相对于由式（1）表示的二酯100质量份和由式（1）表示的单酯的总量超过65质量份且小于80质量份， 公式（2）。

公开(公告)号：US09243127B2

公开(公告)日：2016-01-26

申请号：US14407494

申请日：2013-05-30

申请人： ADEKA CORPORATION

发明人： Naoshi Kawamoto ,  Takashi Ayabe ,  Atsushi Sakai ,  Tetsuya Seguchi

IPC分类号： C08F2/44 ,  C08J3/22 ,  C08K5/098 ,  C08K5/527 ,  C08L23/00 ,  C08K5/56 ,  C08K5/00 ,  C08J5/18 ,  C08K5/20 ,  C08F110/06

CPC分类号： C08K5/56 ,  C08F2/44 ,  C08F110/06 ,  C08J3/22 ,  C08J5/18 ,  C08J2323/12 ,  C08J2423/12 ,  C08K5/0083 ,  C08K5/20 ,  C08K5/527 ,  C08F10/00 ,  C08L23/12

摘要： Provided is a method of producing a nucleator masterbatch, by which a nucleator masterbatch capable of improving the transparency and the physical properties of an olefin resin can be produced. This method is a method of producing a masterbatch in which a nucleator is blended in an olefin polymer, the method being characterized by comprising the step of polymerizing an olefin monomer with incorporation of a nucleator component, which is dissolved in an organoaluminum compound or in an organoaluminum compound and an organic solvent, before or during polymerization of the olefin monomer such that the nucleator component is blended in an amount of 0.05 to 20 parts by mass with respect to 100 parts by mass of the olefin polymer obtained by the polymerization of the olefin monomer.

摘要翻译： 提供一种生产成核剂母料的方法，通过该方法可以制备能够提高烯烃树脂的透明度和物理性能的成核剂母料。 该方法是一种生产母体的方法，其中将成核剂混合在烯烃聚合物中，该方法的特征在于包括使烯烃单体聚合并引入成核剂组分的步骤，所述成核剂组分溶于有机铝化合物或在 有机铝化合物和有机溶剂，在烯烃单体聚合之前或期间，相对于100质量份通过烯烃聚合得到的烯烃聚合物，将成核剂组分的配合量为0.05〜20质量份 单体。

公开(公告)号：US20150065649A1

公开(公告)日：2015-03-05

申请号：US14387465

申请日：2013-02-15

申请人： ADEKA CORPORATION

发明人： Naoshi Kawamoto ,  Tsuyoshi Urushihara ,  Kohei Okamoto ,  Tetsuya Seguchi

IPC分类号： C08K5/20 ,  C08K5/56 ,  C08K5/526 ,  C08F110/06

CPC分类号： C08K5/20 ,  C08F110/06 ,  C08K5/524 ,  C08K5/526 ,  C08K5/56 ,  C08L23/12 ,  C08F10/00 ,  C08F2/44

摘要： The present invention provides a method capable of producing an olefin resin composition for a home electric appliance materials and automotive interior materials that has good color tone and shows excellent fogging resistance, in which method the total amount of stabilizer(s) to be added is reduced and cost reduction can thus be attained. The method of producing an olefin resin composition for an automotive interior material by polymerization of an olefin monomer according to the present invention is characterized by comprising the step of adding, before or during the polymerization of an olefin monomer, 0.001 to 0.5 parts by mass of a phenolic antioxidant, which is represented by the following Formula (1) and masked with an organoaluminum compound, with respect to 100 parts by mass of an olefin resin obtained by the polymerization: (wherein, R represents an alkyl group having 1 to 30 carbon atoms which is optionally branched, a cycloalkyl group having 3 to 12 carbon atoms which is optionally substituted or an aryl group having 6 to 18 carbon atoms which is optionally substituted).

摘要翻译： 本发明提供一种能够制造家用电器材料的烯烃树脂组合物和具有良好的色调并且具有优异的抗雾性的汽车内部材料的方法，其中加入的稳定剂的总量降低 从而可以实现成本降低。 通过本发明的烯烃单体的聚合制造汽车内部材料的烯烃树脂组合物的方法的特征在于包括在烯烃单体的聚合之前或期间加入0.001至0.5质量份的 相对于100质量份通过聚合得到的烯烃树脂，其由下式（1）表示并被有机铝化合物掩蔽的酚类抗氧化剂（其中，R表示具有1〜30个碳原子的烷基 任选支化的原子，任选取代的具有3至12个碳原子的环烷基或任选被取代的具有6至18个碳原子的芳基）。