公开(公告)号：US3697562A

公开(公告)日：1972-10-10

申请号：US3697562D

申请日：1969-10-17

Applicant: ALLIED CHEM

Inventor： BEYLEVELD WILHELMUS M ,  OXENRIDER BRYCE C ,  WOOLF CYRIL

IPC: C09K3/00 ,  C08G18/00 ,  C08G18/71 ,  C08K5/20 ,  C08K5/21 ,  C08K5/3477 ,  C08L77/00 ,  D01F6/90 ,  C07C103/30

CPC classification number: C08G18/00 ,  C08G18/712 ,  C08K5/20 ,  C08K5/21 ,  C08K5/3477 ,  C08L77/02 ,  C08L77/06 ,  C08L23/12 ,  C08L33/20 ,  C08L67/00

Abstract: Novel fluorocarbon diamides useful as oil- and water- repellent agents have the formula
WHEREIN R is a covalent bond, an alkyl diradical of one to 12 carbon atoms, an alkylene diradical of two to 12 carbon atoms, a phenyl diradical having from zero to four chlorine substituents, or a dicarboxy phenyl diradical having the formula ; Q IS AN INTEGER FROM 1 TO 6; AND Rf is a radical having the formula

公开(公告)号：US3705917A

公开(公告)日：1972-12-12

申请号：US3705917D

申请日：1970-02-26

Applicant: ALLIED CHEM

Inventor： WOOLF CYRIL ,  OXENRIDER BRYCE C ,  BEYLEVELD WILHELMUS M

IPC: C07C263/12 ,  C07C119/04

CPC classification number: C07C263/00 ,  C07C249/02 ,  C07C265/04 ,  C07C251/12 ,  C07C265/14

Abstract: FLUOROPERHALOALKYL ISOCYANATES AND FLUOROPERHALOAZAOLEFINS ARE PREPARED BY REACTING A FLUOROPERHALOGENATED CARBONYL COMPOUND WITH A CYANOGEN HALIDE AND AN IONIZABLE FLUORIDE SALT IN THE PRESENCE OF AN APROTIC, POLAR LIQUID REACTION MEDIUM. FOR EXAMPLE, (CF3)2CFNO AND

(CF3>2CFN=C(CF3)2

ARE PREPARED BY REACTING HEXAFLUOROACETONE WITH CYANOGEN CHLORIDE AND POTASSIUM FLUORIDE IN THE PRESENCE OF ACETONITRILE. A SEPARATE MIXTURE OF THE ISOCYANATE AND THE AZAOLEFIN IS NORMALLY OBTAINED, BUT THE REACTION CONDITIONS CAN BE CONTROLLED TO FAVOR FORMATION OF EITHER PRODUCT.

公开(公告)号：US3629255A

公开(公告)日：1971-12-21

申请号：US3629255D

申请日：1969-03-19

Applicant: ALLIED CHEM

Inventor： BEYLEVELD WILHELMUS M ,  OXENRIDER BRYCE C ,  WOOLF CYRIL

IPC: C07D55/38

CPC classification number: C07D251/32 ,  C07D251/34

Abstract: THIS INVENTION RELATES TO A NOVEL CLASS OF FLUORINE CONTAINING ISOCYANURATE ESTERS DERIVED FROM REACTING TRIS(2HYDROXYETHYL)ISOCYANURATE WITH HEREINAFTER DEFINED FLUORO ACIDS, AND TRIS(2-CARBOXYETHYL)ISOCYANURATE WITH HEREINAFTER DEFINED FLUORO ALCOHOLS.