Water-soluble block copolymer and use thereof as a support material for 3D printing

    公开(公告)号:US10577447B2

    公开(公告)日:2020-03-03

    申请号:US16653140

    申请日:2019-10-15

    Applicant: Arkema France

    Abstract: The invention relates to a novel type of sacrificial polymer or support material for 3D printing, comprising a block copolymer consisting of: at least one partially or totally hydrophilic elastomeric block, with a Tg of less than 30° C. and comprising at least one hydrophilic monomer, and at least one water-soluble thermoplastic block with a Tg of greater than 30° C. and comprising at least one monomer bearing a carboxyl group, said copolymer being extrudable and granulable, said copolymer being partially or totally soluble in water or in aqueous medium, and the mass proportion of the thermoplastic block being greater than 50% of the weight of said copolymer.

    WATER-SOLUBLE BLOCK COPOLYMER AND USE THEREOF AS A SUPPORT MATERIAL FOR 3D PRINTING

    公开(公告)号:US20200040120A1

    公开(公告)日:2020-02-06

    申请号:US16653140

    申请日:2019-10-15

    Applicant: Arkema France

    Abstract: The invention relates to a novel type of sacrificial polymer or support material for 3D printing, comprising a block copolymer consisting of:at least one partially or totally hydrophilic elastomeric block, with a Tg of less than 30° C. and comprising at least one hydrophilic monomer, andat least one water-soluble thermoplastic block with a Tg of greater than 30° C. and comprising at least one monomer bearing a carboxyl group, said copolymer being extrudable and granulable, said copolymer being partially or totally soluble in water or in aqueous medium, and the mass proportion of the thermoplastic block being greater than 50% of the weight of said copolymer.

    WATER-SOLUBLE COPOLYMER COMPOSITION WITH NEUTRAL PH

    公开(公告)号:US20200369808A1

    公开(公告)日:2020-11-26

    申请号:US16766926

    申请日:2018-11-23

    Applicant: Arkema France

    Abstract: The present invention relates to the field of copolymers which are water-soluble or water-dispersible at neutral pH or near-neutral pH, that is to say between 5.5 and 9.5, comprising at least one random copolymer comprising methacrylic acid, butyl acrylate, styrene and a monomer chosen from styrenesulfonic acid or salts thereof, vinylbenzoic acid or salts thereof, 2-acrylamido-2-methanesulfonic acid or salts thereof, N-vinylpyrrolidone, alone or in combination.

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