公开(公告)号：US20170267855A1

公开(公告)日：2017-09-21

申请号：US15531742

申请日：2015-12-03

Applicant: Arkema Inc.

Inventor： Feng-Jon CHANG ,  William P. PAVLEK ,  Leonard H. PALYS ,  Peter R. DLUZNESKI ,  Marina DESPOTOPOULOU ,  Alfredo DEFRANCISCI ,  Joseph M. BRENNAN ,  Michael B. ABRAMS ,  Isabelle TARTARIN

IPC: C08L23/16 ,  C08J3/24

Abstract: An organic peroxide formulation includes at least one organic peroxide and at least one cellulose compound. Embodiments of the organic peroxide formulations significant improvements in surface tackiness (often including but not limited to tack-free surfaces) when curing elastomers in the presence of oxygen. Embodiments of the present invention relate to organic peroxide formulations that can cure solid elastomers in the full or partial presence of oxygen using, for example, a hot air oven or tunnel, molten salt bath, or steam autoclave. Embodiments of the invention also relate to crosslinkable elastomer compositions, processes for curing the elastomers, and products made by such processes.

公开(公告)号：US20210070931A1

公开(公告)日：2021-03-11

申请号：US16956650

申请日：2018-12-18

Applicant: Arkema Inc.

Inventor： Robert D. HEROLD ,  Marco HERRERA ,  Thomas H. KOZEL ,  Leonard H. PALYS ,  Brandy SLEZAK ,  Bruno Georges VAN HEMELRYCK

IPC: C08G64/02 ,  C08G64/22 ,  C08F18/24

Abstract: The present invention is directed to a polymerizable composition comprising (A) a reaction product of: (a) diethyleneglycol bischloroformate, ethyleneglycol bischloroformate, or combinations thereof; (b) allyl alcohol; (c) optionally, a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups; and (B) an organic peroxide comprising at least three peroxide groups. A polymerizate and/or an optical article comprising the polymerizable compositions of the invention are also provided.

公开(公告)号：US20230113977A1

公开(公告)日：2023-04-13

申请号：US17914377

申请日：2021-04-08

Applicant: Arkema Inc.

Inventor： Peter R. DLUZNESKI ,  William P. PAVLEK ,  Leonard H. PALYS ,  Michael B. Abrams ,  Marina DESPOTOPOULOU

IPC: C08L97/02 ,  C08L23/06 ,  C08K5/14 ,  C08J3/22

Abstract: Non-polymeric coupling agent formulation for producing wood-polymer composites include at least one organic peroxide and a non-polymeric bio-based additive that includes at least one of a bio-based oil or a bio-based acid or derivatives of bio-based oils or acid is provided. The coupling agent formulations are capable of producing polymer matrix composites having improved strength and aging characteristics. The improved strength may be related to physical properties such as improved stiffness, toughness or tensile strength. A masterbatch utilizing the non-polymeric coupling agent formulation is provided, as well as a method making the masterbatch.

公开(公告)号：US20200299469A1

公开(公告)日：2020-09-24

申请号：US16897469

申请日：2020-06-10

Applicant: Arkema Inc.

Inventor： Leonard H. PALYS ,  Peter R. DLUZNESKI ,  William P. PAVLEK ,  Alfredo DEFRANCISCI ,  Feng-Jon CHANG ,  Marina DESPOTOPOULOU ,  Michael B. ABRAMS ,  Joseph M. BRENNAN ,  Isabelle TARTARIN

IPC: C08J3/24 ,  C08K5/08 ,  C08K5/205 ,  C08K5/32 ,  C08K5/3435 ,  C08K5/36 ,  C08K5/524 ,  C08K5/11 ,  C08K5/14 ,  C08K5/3437 ,  C08K5/3492

Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).

公开(公告)号：US20190338086A1

公开(公告)日：2019-11-07

申请号：US16465158

申请日：2017-12-14

Applicant: Arkema Inc.

Inventor： Leonard H. PALYS ,  Marina DESPOTOPOULOU ,  Peter R. DLUZNESKI

IPC: C08J3/24 ,  C08F10/02 ,  B29C41/00

Abstract: An organic peroxide composition is provided which is liquid or near liquid at 25° C. or a low melting solid and which includes at least one ethylenically unsaturated organic peroxide (i.e., an organic peroxide containing at least one carbon-carbon double bond) and at least one saturated organic peroxide. The organic peroxide composition may further include at least one mono- and/or poly-unsaturated compound and at least one free-radical trap. The organic peroxide can be blended into a polymer such as a powdered or granular polyethylene resin. This peroxide-containing polymer can be used in rotational molding, wherein the polymer is added to a mold which is heated in an oven with rotation, thereby melting the polymer and coating the inside of the mold.

公开(公告)号：US20230113267A1

公开(公告)日：2023-04-13

申请号：US17914379

申请日：2021-04-08

Applicant: Arkema Inc.

Inventor： Leonard H. PALYS ,  Peter R. DLUZNESKI ,  Michael B. ABRAMS ,  Marina DESPOTOPOULOU ,  William P. PAVLEK

IPC: C08K5/14 ,  C08L67/04

Abstract: Formulations for producing modified bio-based polymers, especially bio-based polyesters like PLA and/or biodegradable polymers like PBAT, include at least one organic peroxide and at least one bio-based reactive additive. The at least one organic peroxide and/or the at least one bio-based reacted additive are capable of reacting with a bio-based polymer and/or biodegradable polymer to produce the modified bio-based and/or modified biodegradable polymer. The modified bio-based and/or modified biodegradable polymers have improved properties compared to non-modified bio-based and/or biodegradable polymers. The improved properties may related to processability, especially improved melt strength which results in easier processing while producing foamed polymers, thin films, such as blown film, cast film, tentered film and the like. The improved properties may be related to physical properties such as improved stiffness, toughness or tensile strength.

公开(公告)号：US20190256671A1

公开(公告)日：2019-08-22

申请号：US16400276

申请日：2019-05-01

Applicant: Arkema Inc.

Inventor： Leonard H. PALYS ,  Peter R. DLUZNESKI ,  William P. PAVLEK ,  Alfredo DEFRANCISCI ,  Feng-Jon CHANG ,  Marina DESPOTOPOULOU ,  Michael B. ABRAMS ,  Joseph M. BRENNAN ,  Isabelle TARTARIN

IPC: C08J3/24 ,  C08K5/08 ,  C08K5/3437 ,  C08K5/3492 ,  C08K5/14 ,  C08K5/524 ,  C08K5/36 ,  C08K5/3435 ,  C08K5/32 ,  C08K5/205 ,  C08K5/11

Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).

公开(公告)号：US20170267834A1

公开(公告)日：2017-09-21

申请号：US15531740

申请日：2015-12-04

Applicant: Arkema Inc.

Inventor： Leonard H. PALYS ,  William P. PAVLEK ,  Peter R. DLUZNESKI

IPC: C08K5/3435 ,  C08J3/24 ,  C08F110/02 ,  C08F118/08 ,  C08K5/14 ,  C08K5/08

CPC classification number: C08K5/3435 ,  C08F110/02 ,  C08F118/08 ,  C08F2810/20 ,  C08J3/242 ,  C08J2323/06 ,  C08J2331/04 ,  C08K5/08 ,  C08K5/14 ,  C08K5/32 ,  C08L23/0853

Abstract: Embodiments of organic peroxide formulations provide longer scorch time protection and require fewer additives. The peroxide formulations may include, for example, at least one organic peroxide, at least one nitroxide-containing compound (e.g., 4-hydroxy-TEMPO), and at least one quinone-containing compound (e.g., mono-tert-butylhydroquinone). Embodiments of the present invention relate to organic peroxide compositions comprising scorch retarders. Embodiments of the invention also relate to crosslinkable elastomer compositions, processes for curing the elastomers, and products made by such processes.

公开(公告)号：US20170260343A1

公开(公告)日：2017-09-14

申请号：US15531746

申请日：2015-12-03

Applicant: Arkema Inc.

Inventor： Leonard H. PALYS ,  Peter R. DLUZNESKI ,  William P. PAVLEK ,  Alfredo DEFRANCISCI ,  Feng-Jon CHANG ,  Marina DESPOTOPOULOU ,  Michael B. ABRAMS ,  Joseph M. BRENNAN ,  Isabelle TARTARIN

IPC: C08J3/24 ,  C08K5/3437 ,  C08K5/11 ,  C08K5/14 ,  C08K5/3492 ,  C08K5/47 ,  C08K5/40

CPC classification number: C08J3/242 ,  C08J2323/16 ,  C08K5/08 ,  C08K5/11 ,  C08K5/14 ,  C08K5/205 ,  C08K5/32 ,  C08K5/3435 ,  C08K5/3437 ,  C08K5/34924 ,  C08K5/36 ,  C08K5/40 ,  C08K5/47 ,  C08K5/524 ,  C08K2201/019 ,  C08L21/00

Abstract: Embodiments of organic peroxide formulations provide significant improvements in surface tackiness (often including tack-free surfaces) when curing elastomers in the presence of oxygen. The peroxide formulations may include, for example, one or more compounds selected from sulfur-containing compounds, organophosphite compounds, HALS (Hindered Amine Light Stabilizer) compounds, aliphatic allyl urethane compounds, and blends comprising nitroxides (e.g., 4-hydroxy-TEMPO) and quinones (e.g., mono-tert-butylhydroquinone).

公开(公告)号：US20230110618A1

公开(公告)日：2023-04-13

申请号：US17914385

申请日：2021-04-08

Applicant: Arkema Inc.

Inventor： Leonard H. PALYS

IPC: C08K5/14 ,  C08K5/08

Abstract: Embodiments of organic peroxide formulations provide longer scorch time protection and require fewer additives. The peroxide formulations may include, for example, at least one organic peroxide, and at least one scorch retardant additive selected from the group consisting of vitamin K1 (phlloquinone), K2 (menaquinone), K3 (menadione), olive leaf oil (oleuropein), and mixtures thereof.