摘要:
Disclosed are trans-1,2-cyclohexane bis(urea-urethane) compounds of the formulae wherein R1 and R′1 each, independently of the other, is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, R2 and R′2 each, independently of the other, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, R3 and R′3 each, independently of the other, is a hydrogen atom or an alkyl group, R4 and R′4 each, independently of the other, is a hydrogen atom, a fluorine atom, an alkyl group, or a phenyl group, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl group, an aryl group, an arylalkyl group, an alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group.
摘要:
Disclosed are phase change inks comprising a phase change ink carrier and a trans-1,2-cyclohexane bis(urea-urethane) compound of the formula or mixtures thereof, wherein R1 and R′1 each, independently of the other, is an alkylene group, an arylene group, an arylalkylene group, or an alkylarylene group, R2 and R′2 each, independently of the other, is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, R3 and R′3 each, independently of the other, is a hydrogen atom or an alkyl group, R4 and R′4 each, independently of the other, is a hydrogen atom, a fluorine atom, an alkyl group, or a phenyl group, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl group, an aryl group, an arylalkyl group, an alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group.
摘要:
Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising (A) a urethane which is the reaction product of a mixture comprising (1) an isocyanate; and (2) an alcohol selected from the group consisting of 1,4 butanediol vinyl ether, 2-allyloxy ethanol, 1,4-cyclohexanedimethanol vinyl ether, ethylene glycol vinyl ether, di(ethylene glycol) vinyl ether, and mixtures thereof; (B) a compound which is the reaction product of a mixture comprising (1) an isocyanate; and (2) a component comprising (a) an amine having at least one ethylenic unsaturation; (b) an acid having at least one ethylenic unsaturation; (c) a mixture of an amine having at least one ethylenic unsaturation and an alcohol having at least one ethylenic unsaturation; (d) a mixture of an acid having at least one ethylenic unsaturation and an alcohol having at least one ethylenic unsaturation; or (e) mixtures thereof; or (C) a mixture of (A) and (B); said ink being curable upon exposure to ultraviolet radiation.
摘要:
Curable trans-1,2-cyclohexane bis(urea-urethane) compounds of the formulae wherein R1 and R′1 each, independently of the other, are alkylene, arylene, arylalkylene, or alkylarylene groups, R2 and R′2 each, independently of the other, are alkyl, aryl, arylalkyl, or alkylaryl groups, R3 and R′3 each, independently of the other, are hydrogen atoms or alkyl groups, R4 and R′4 each, independently of the other, are hydrogen atoms, fluorine atoms, alkyl groups, or phenyl groups, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl, aryl, arylalkyl, or alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group, provided that at least one of R1, R′1, R2, R′2, R3, R′3, R4, R′4, or one or more of R5 is an alkyl, alkylene, arylalkyl, arylalkylene, alkylaryl, or alkylarylene group containing an ethylenic unsaturation rendering the compound curable upon exposure to heat and/or actinic radiation.
摘要:
Phase change inks comprising a phase change ink carrier and one or more curable trans-1,2-cyclohexane bis[urea-urethane] compounds of the formulae wherein R1 and R′1 are alkylene, arylene, arylalkylene, or alkylarylene groups, R2 and R′2 are alkyl, aryl, arylalkyl, or alkylaryl groups, R3 and R′3 are hydrogen atoms or alkyl groups, R4 and R′4 are hydrogen atoms, fluorine atoms, alkyl groups, or phenyl groups, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl, aryl, arylalkyl, or alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group, provided that at least one of R1, R′1, R2, R′2, R3, R′3, R4, R′4, or one or more of R5 is an alkyl, alkylene, arylalkyl, arylalkylene, alkylaryl, or alkylarylene group containing an ethylenic unsaturation rendering the compound curable upon exposure to heat and/or actinic radiation.
摘要翻译:相变油墨,其包含相变油墨载体和一种或多种下式的可固化的反式-1,2-环己烷双[尿素 - 氨基甲酸酯]化合物,其中R 1和R 2 < R 2是亚烷基,亚芳基,芳基亚烷基或烷基亚芳基,R 2和R“2是烷基,芳基,芳基烷基或烷基芳基, R 3和R 3'是氢原子或烷基,R 4和R“4是氢原子,氟原子,烷基 或苯基,n是0,1,2,3或4的整数,并且R 5是烷基,芳基,芳基烷基或烷基芳基,或除烷基以外的取代基 ,芳基,芳基烷基或烷基芳基,条件是R 1,R'1,R 2,R 2,R',SUB中的至少一个 R 2,R 3,R 4,R 4,或者R 3,R 3, R 5中的一个或多个是含有烯属不饱和键的烷基,亚烷基,芳基烷基,芳基亚烷基,烷基芳基或烷基亚芳基,使得c 在暴露于热和/或光化辐射下可固化。
摘要:
Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising (A) a compound which is the reaction product of a mixture comprising (1) an isocyanate; and (2) a component comprising (a) an alcohol having at least one ethylenic unsaturation; (b) an amine having at least one ethylenic unsaturation; (c) an acid having at least one ethylenic unsaturation; or (d) mixtures thereof, (B) a phase change inducing component, said phase change inducing component containing at least one hydroxyl group, said phase change inducing component having a melting point of about 40° C. or higher, and (C) an optional curable viscosity modifying ester, said ink being curable upon exposure to ultraviolet radiation.
摘要:
Compounds of the formulae wherein Z is —OR1, —SR1, —NR1R2, Y is —OR3, —SR3, or —NR3R4, at least one of R1, R2, R3, R4, R5, and R6 is hydrogen, at least one of R1, R2, R3, R4, R5, and R6 is other than hydrogen, at least one Z or Y within the compound is —NR1R2 or —NR3R4, R1, R2, R3, R4, R5, R6, and R7 each, independently of the others, is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, and wherein R7 can also be alkoxy, aryloxy, arylalkyloxy, alkylaryloxy, polyalkyleneoxy, polyaryleneoxy, polyarylalkyleneoxy, polyalkylaryleneoxy, silyl, siloxane, polysilylene, polysiloxane, or wherein X is a direct bond, oxygen, sulfur, —NR40— wherein R40 is hydrogen, alkyl, aryl, arylalkyl, alkylaryl, or —CR50R60— wherein R50 and R60 each, independently of the other, is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl.
摘要翻译:下式的化合物其中Z为-OR 1,-SR 1,-NR 1 R 2,Y 是-OR 3,-SR 3或-NR 3 R 4,R 1,R 3, R 1,R 2,R 3,R 4,R 5,R 3,R 5,R 5, R 6是氢,R 1,R 2,R 3,R 4中的至少一个是 R 5,R 6和R 6不是氢,化合物中至少一个Z或Y是-NR 1 N, R 2或-NR 3 R 4,R 1,R 2,R 2, R 3,R 4,R 5,R 6和R 7, 各自独立地为氢,烷基,芳基,芳基烷基或烷基芳基,并且其中R 7也可以是烷氧基,芳氧基,芳基烷氧基,烷芳基氧基,聚亚烷氧基,聚亚芳基氧基,聚芳基亚烷氧基,聚烷基亚芳基氧基,甲硅烷基 ,硅氧烷,聚亚硅烷基,聚硅氧烷,或其中X是直接键,氧,硫,-NR 40 - , - R 40是氢,烷基,芳基,芳烷基,烷基芳基或-CR 50 R 60 - ,其中R 50是氢, 各自独立地是氢,烷基,芳基,芳基烷基或烷基芳基。
摘要:
An ink preferably used in piezoelectric ink jet devices includes an ink vehicle that includes at least one curable monomer, at least one polymerizable organic gelator, at least one initiator, at least one colorant and optionally at least one low molecular mass non-reactive organic gelator and/or at least one thermal solvent. The use of the curable gelator enables the ink to form a gel state having a viscosity of at least 102.5 cps at very low temperatures of about 30° C. to about 50° C. The ink may thus be jetted at low temperatures of about 50° C. to about 90° C. The ink is heated to a first temperature above the gel point of the ink, jetted onto a surface maintained at a second temperature at which the ink forms a gel state, and when on the image receiving substrate, is exposed to radiation energy to polymerize the polymerizable components of the ink.
摘要:
Compounds of the formulae wherein, provided that at least one of R1, R2, and R3 is not a hydrogen atom, R1, R2, and R3 each, independently of the other, is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, and wherein R1 and R2 can also be alkoxy aryloxy, arylalkyloxy, alkylaryloxy, polyalkyleneoxy, polyaryleneoxy, polyarylalkyleneoxy, polyalkylaryleneoxy, silyl, siloxane, polysilylene, polysiloxane, or a group of the formula wherein r and s are integers representing a number of repeat —CH2— groups, and wherein X is a direct bond, oxygen, sulfur, —NR40— wherein R40 is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, or —CR50R60— wherein R50 and R60 each, independently of the other, is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, and R10 and R11 each, independently of the other, is alkylene, arylene, arylalkylene, or alkylarylene, and wherein R10 can also be alkyleneoxy, polyaryleneoxy, polyarylalkyleneoxy, polyalkylaryleneoxy, silylene, siloxane, polysilylene, or polysiloxane.
摘要:
Disclosed is a hand-held photochromic marking implement including a photochromic colorant and solid phase colorant carrier which can be used in direct-to-media marking and a method of forming same.