公开(公告)号：US4421895A

公开(公告)日：1983-12-20

申请号：US329596

申请日：1981-12-10

申请人： Adolf Echte ,  Hermann Gausepohl ,  Karl Gerberding

发明人： Adolf Echte ,  Hermann Gausepohl ,  Karl Gerberding

IPC分类号： C08F2/06 ,  C08F279/02 ,  C08F279/04 ,  C08F287/00 ,  C08F291/02

CPC分类号： C08F291/02 ,  C08F279/02 ,  C08F279/04 ,  C08F287/00

摘要： A process for making ABS polymer particles comprising continuous polymerization of a mixture of at least one of each of (a) an aromatic vinyl monomer, and (b) an ethylenically unsaturated monomer in a weight ratio of (a):(b) of 90:10 to 10:90 in the presence of at least one of each of (c) a rubber-like polymer in an amount of 3 to 35 percent by weight relative to the total weight of the monomers (a) and (b), (d) a solvent, (e) a radical initiator and (f) an optional chain transfer agent. The process is carried out at temperatures between 80.degree. C. to 180.degree. C. in two or more reaction zones while the reaction mixture is stirred and while the monomers and solvents are removed in a degassing zone. The rubber-like polymer (c) has a solution viscosity of less than 80 mPa.s and a ratio of the solution viscosity of (c) to a percent of solvent expressed by 100[(d)/(a+b+c+d)] equal to or less than 2.5 mPa.s/percent of solvent.

摘要翻译： 制备ABS聚合物颗粒的方法，包括（a）芳族乙烯基单体和（b）烯属不饱和单体中的至少一种（a）：（b）为90的混合物的混合物的连续聚合 在（c）相对于单体（a）和（b）的总重量为3〜35重量％的量的橡胶状聚合物中的至少一种存在下，10〜10:90， （d）溶剂，（e）自由基引发剂和（f）任选的链转移剂。 该方法在两个或更多个反应区中在80℃至180℃的温度下进行，同时搅拌反应混合物，同时在脱气区中除去单体和溶剂。 橡胶状聚合物（c）的溶液粘度小于80mPa.s，溶液粘度（c）与溶剂百分比的比例由100 [（d）/（a + b + c + d）]等于或小于2.5mPa.s /％的溶剂。

公开(公告)号：US4567232A

公开(公告)日：1986-01-28

申请号：US650568

申请日：1984-09-13

申请人： Adolf Echte ,  Hermann Gausepohl ,  Juergen Hambrecht ,  Karl Gerberding

发明人： Adolf Echte ,  Hermann Gausepohl ,  Juergen Hambrecht ,  Karl Gerberding

IPC分类号： C08F2/02 ,  C08F2/06 ,  C08F279/02 ,  C08F291/02

CPC分类号： C08F279/02 ,  C08F291/02

摘要： A process for the continuous preparation of rubber-modified polymers of vinyl-aromatics, wherein a mixture which contains a monomeric aromatic vinyl compound and from 3 to 30% by weight, based on the monomer, of an elastomeric polymer, with or without a solvent, is polymerized, in the presence of a free radical initiator and in the presence or absence of a mercaptan as chain transfer agent, at from 80.degree. to 180.degree. C., with stirring, in a cascade of two or more isothermally operated reaction zones and of one or more additional reaction zones which can be operated isothermally or with a rising temperature profile in such a way that the residence time of the reactants in the first reaction zone is .ltoreq.35 minutes. The polymer obtained is freed from vinyl-aromatic monomer, and from any solvent, in a devolatilization zone. The product is useful for the production of injection moldings.

摘要翻译： 用于连续制备乙烯基芳族化合物的橡胶改性聚合物的方法，其中含有单体芳族乙烯基化合物和基于单体的3-30重量％的弹性体聚合物的混合物，具有或不具有溶剂 在存在自由基引发剂的情况下，在作为链转移剂的硫醇存在或不存在下，在80-180℃下，在搅拌下，在两个或更多个等温操作的反应区的级联中聚合 以及一个或多个另外的反应区，其可以等温或以升高的温度曲线操作，使得反应物在第一反应区中的停留时间为35分钟。 获得的聚合物在脱挥发分区域中不含乙烯基芳族单体和任何溶剂。 该产品可用于生产注射成型品。

公开(公告)号：US4696996A

公开(公告)日：1987-09-29

申请号：US797884

申请日：1985-11-14

申请人： Hermann Brandt ,  Hermann Fischer ,  Hermann Dreher ,  Eduard Heil ,  Juergen Hambrecht ,  Herbert Naarmann ,  Adolf Echte ,  Hermann Gausepohl ,  Peter Siebel ,  Johann Swoboda ,  Gerd Schwoebel ,  Albert Nikles

发明人： Hermann Brandt ,  Hermann Fischer ,  Hermann Dreher ,  Eduard Heil ,  Juergen Hambrecht ,  Herbert Naarmann ,  Adolf Echte ,  Hermann Gausepohl ,  Peter Siebel ,  Johann Swoboda ,  Gerd Schwoebel ,  Albert Nikles

IPC分类号： B01J10/00 ,  B01J19/18 ,  C08G65/44 ,  C08G65/38

CPC分类号： C08G65/44 ,  B01J19/1862 ,  B01J19/1881 ,  B01J2219/00094 ,  B01J2219/00103 ,  B01J2219/0011

摘要： Polyphenylene ethers are prepared from monohydric phenols, which possess alkyl substituents in the two ortho-positions and, if desired, in the meta-position, but not in the para-position, by an oxidative coupling reaction with oxygen at from 15.degree. to 50.degree. C. and under from 1 to 10 bar in the presence of a catalyst complex, of a solvent and, if required, of an activator, by a method in which the conversion of the phenols is carried out in two more reaction zones, in which some or all of the solvent, the catalyst complex and the phenols and, where relevant, the activator is initially taken and is circulated by means of a conveying unit, and about 60-100% of the stoichiometric amount of oxygen required for the oxidative coupling is introduced into the first reaction zone and from 0 to about 40% of the said stoichiometric amount is introduced into the second reaction zone.

摘要翻译： 聚苯醚由单羟基苯酚制得，它们在两个邻位具有烷基取代基，如果需要，在间位，而不是在对位，通过与15至50的氧的氧化偶联反应， 在催化剂配合物存在下，在溶剂和如果需要的情况下，活化剂存在下，在1至10巴下，通过酚的转化在两个更多的反应区中进行，在 其中一些或全部溶剂，催化剂络合物和酚，并且在相关的情况下，活化剂最初被摄取并通过输送单元循环，并且约60-100％的化学计量量的氧化所需的氧 将偶联引入第一反应区，并将0至约40％的所述化学计量量引入第二反应区。

公开(公告)号：US4412037A

公开(公告)日：1983-10-25

申请号：US302040

申请日：1981-09-14

申请人： Franz Brandstetter ,  Adolf Echte ,  Hermann Gausepohl ,  Herbert Naarmann

发明人： Franz Brandstetter ,  Adolf Echte ,  Hermann Gausepohl ,  Herbert Naarmann

IPC分类号： C08L25/00 ,  C08L7/00 ,  C08L21/00 ,  C08L51/00 ,  C08L51/02 ,  C08L51/04 ,  C08L71/00 ,  C08L71/12 ,  C08L61/04

CPC分类号： C08L51/04 ,  C08L71/123

摘要： Thermoplastic molding materials based on styrene polymers which have been made impact-resistant and on polyphenylene ethers, wherein the particles of the soft component of the styrene polymer which has been made impact-resistant have a mean diameter of more than 1 micron, and wherein the proportion of particles which have a diameter of less than 0.6 micron is not less than 40% by weight and the proportion of particles which have a diameter of from 0.6 to 3 microns is less than 3% by weight.

摘要翻译： 基于已经制成抗冲击性的苯乙烯聚合物和聚苯醚的热塑性成型材料，其中已经制成抗冲击性的苯乙烯聚合物的软组分的颗粒具有大于1微米的平均直径，并且其中 直径小于0.6微米的颗粒的比例不小于40重量％，直径为0.6至3微米的颗粒的比例小于3重量％。

公开(公告)号：US4330641A

公开(公告)日：1982-05-18

申请号：US204527

申请日：1980-11-06

申请人： Adolf Echte ,  Hermann Gausepohl ,  Helmut Jenne ,  Hans Mittnacht

发明人： Adolf Echte ,  Hermann Gausepohl ,  Helmut Jenne ,  Hans Mittnacht

IPC分类号： C08F255/06 ,  C08F279/02 ,  C08F279/04 ,  C08F279/06

CPC分类号： C08F255/06 ,  C08F279/02

摘要： Thermoplastic molding materials which contain a copolymer which has been made impact-resistant with a rubber. The copolymer is produced by polymerizing a mixture of a monovinyl-aromatic compound and an acrylic acid derivative or methacrylic acid derivative in the presence of a rubber. The folding materials contain a specific proportion of soft component. The diameter of the particles of the soft component, and the swelling index of the soft component, lie within a specific range, and the tensile strength of the molding material is higher than the yield strength.

摘要翻译： 含有已经用橡胶抗冲击的共聚物的热塑性成型材料。 共聚物通过在橡胶存在下聚合单乙烯基 - 芳族化合物和丙烯酸衍生物或甲基丙烯酸衍生物的混合物来制备。 折叠材料含有特定比例的软组分。 软组分的颗粒直径和软组分的溶胀指数在特定范围内，成型材料的拉伸强度高于屈服强度。

公开(公告)号：US4493922A

公开(公告)日：1985-01-15

申请号：US573853

申请日：1984-01-25

申请人： Adolf Echte ,  Hermann Gausepohl

发明人： Adolf Echte ,  Hermann Gausepohl

IPC分类号： C08L51/04 ,  C08L55/02 ,  C08L53/02

CPC分类号： C08L51/04 ,  Y10S525/901

摘要： An impact-resistant thermoplastic molding material, containing polystyrene as the matrix, and, dispersed therein, two elastomeric polymers or copolymers I and II composed entirely or predominantly of 1,3-dienes and containing particles of different mean size, namely, in I, particles from 0.2 to 0.6 .mu.m in size and having capsule particle morphology, and, in II, particles from 2 to 8 .mu.m in size, having cell particle or coil particle morphology.

摘要翻译： 一种抗冲击热塑性成型材料，其包含聚苯乙烯作为基体，并分散在其中，两个完全或主要由1,3-二烯构成并含有不同平均尺寸的颗粒的弹性聚合物或共聚物I和II，即I， 颗粒尺寸为0.2至0.6微米，具有胶囊颗粒形态，II型颗粒尺寸为2至8微米，具有细胞颗粒或线粒体形态。

公开(公告)号：US4427826A

公开(公告)日：1984-01-24

申请号：US273689

申请日：1981-06-15

申请人： Adolf Echte ,  Hermann Gausepohl ,  Hermann P. Hofmann ,  Hans Mittnacht

发明人： Adolf Echte ,  Hermann Gausepohl ,  Hermann P. Hofmann ,  Hans Mittnacht

IPC分类号： C08F2/38 ,  C08F4/00 ,  C08F279/02

CPC分类号： C08F279/02

摘要： A process, carried out without a diluent or in solution, in more than 2 reaction zones, for the continuous preparation of rubber-modified polymers of vinylaromatics, wherein a monomeric aromatic vinyl compound and an elastomeric polymer, in an amount of from 3 to 16% by weight based on the monomer, are polymerized, in the absence of a free radical initiator, but in the presence of a mercaptan as a chain transfer agent, at from 80.degree. to 180.degree. C. in a first reaction zone, with stirring, up to a maximum monomer conversion, U.sub.max, given by the equationU.sub.max =K-1where K is the amount of rubber in % by weight based on monomer, and, in a second reaction zone, polymerization is continued, with stirring, to a conversion of up to about 50% by weight, after which a chain transfer agent is introduced in an amount of from 0.01 to 0.2% by weight, based on vinyl-aromatic monomer, and polymerization is continued, if appropriate in more than one reaction zone, up to a monomer conversion of less than 85% by weight. The polymer is treated in a devolatilization zone to remove vinyl-aromatic monomer and solvent, if any, and these constituents are recycled to the process. The process produces products which exhibit good gloss coupled with good mechanical properties, and which can be employed for conventional applications.

摘要翻译： 用于连续制备乙烯基芳族化合物的橡胶改性聚合物的方法，其中没有稀释剂或在溶液中，在多于2个反应区中进行，其中单体芳族乙烯基化合物和弹性体聚合物的量为3-16 基于单体的重量％在不存在自由基引发剂的情况下，在作为链转移剂的硫醇存在下，在第一反应区中在80-180℃下进行聚合，同时搅拌 ，达到最大单体转化率，Umax，由方程式Umax = K-1给出，其中K是基于单体的以重量％计的橡胶量，并且在第二反应区中，在搅拌下继续聚合至 高达约50重量％的转化率，之后以基于乙烯基芳族单体的0.01至0.2重量％的量引入链转移剂，并且如果适当的话在多于一个反应中继续聚合 区域，单体转化率小于 85重量％。 将聚合物在脱挥发区进行处理以除去乙烯基芳族单体和溶剂（如果有的话），并将这些组分再循环到该方法中。 该方法产生具有良好光泽性和良好机械性能的产品，并且其可用于常规应用。

公开(公告)号：US4061858A

公开(公告)日：1977-12-06

申请号：US703955

申请日：1976-07-09

申请人： Hans Wild ,  Rudolf Jung ,  Adolf Echte ,  Johann Zizlsperger ,  Hermann Gausepohl

发明人： Hans Wild ,  Rudolf Jung ,  Adolf Echte ,  Johann Zizlsperger ,  Hermann Gausepohl

IPC分类号： C08F6/00 ,  C08F6/02 ,  C08F20/44 ,  C07C121/30

CPC分类号： C07C253/34

摘要： Acrylonitrile or monomer mixtures containing acrylonitrile are purified by treating them with alkaline reacting compounds followed by distillation. The products are particularly suitable for the manufacture of acrylonitrile polymers showing improved color stability.

摘要翻译： 通过用碱性反应化合物处理丙烯腈或丙烯腈的单体混合物，然后蒸馏纯化。 该产品特别适用于制备显示改进的颜色稳定性的丙烯腈聚合物。

公开(公告)号：US4418180A

公开(公告)日：1983-11-29

申请号：US296849

申请日：1981-08-27

申请人： Gerhard Heinz ,  Burghard Schmitt ,  Ingo H. Dorn ,  Hermann Gausepohl ,  Karl Gerberding ,  Rudolf H. Jung ,  Hans Mittnacht ,  Jurgen Pohrt ,  Paul Witimer

发明人： Gerhard Heinz ,  Burghard Schmitt ,  Ingo H. Dorn ,  Hermann Gausepohl ,  Karl Gerberding ,  Rudolf H. Jung ,  Hans Mittnacht ,  Jurgen Pohrt ,  Paul Witimer

IPC分类号： C08F297/04

CPC分类号： C08F297/044

摘要： A process for the preparation of branched block copolymers of from 60 to 95% by weight of a monovinyl-aromatic monomer and from 40 to 5% by weight of a conjugated diene by polymerizing the monomers in an inert solvent in the presence of a monolithium-hydrocarbon as the initiator, wherein, in a first process stage (a), from 50 to 80, or where necessary at most 90, % by weight of the total amount of monovinyl-aromatic compound are polymerized to virtually complete conversion in the presence of a relatively small amount of the monolithium-hydrocarbon. This stage is carried out by starting with from 30 to 70% by weight of the vinyl-aromatic monomer and adding from 70 to 30% by weight in the feed, during the polymerization, in such a way that the polymerization temperature, which at the start of the polymerization is from 30.degree. to 40.degree. C., is kept at from 45.degree. to 70.degree. C., with use of reflux cooling. After all the monomer feed has been added, the reaction temperature is lowered to 30.degree.-40.degree. C. by evaporative cooling. In a second process stage (b), an additional amount of initiator is added to the reaction solution, after which from 1 to 30% by weight of the total amount of monovinyl-aromatic monomer can be added, the sum of the amounts of monovinyl-aromatic monomer added in the first and second process stages being at most 90% by weight of the total amount of monovinyl-aromatic monomer. The monovinyl-aromatic monomer added in the second process stage is polymerized to virtually complete conversion, employing the temperature profile described for stage (a). In process stage (c), the remainder of the monovinyl-aromatic monomer and all of the conjugated diene are added, at least predominantly in the form of a mixture, and polymerized so that the reaction temperature does not rise above 90.degree.-110.degree. C. Finally, after virtually complete conversion of the monomers, and preferably without prior cooling, a suitable liquid polyfunctional coupling agent is run in undiluted and the mixture of the linear block copolymers obtained, which still contain active terminal lithium-carbon bonds, is coupled, with stirring, to form branched block copolymers. The products prepared according to the invention are used for injection molding.

公开(公告)号：US4647621A

公开(公告)日：1987-03-03

申请号：US625689

申请日：1984-06-28

申请人： Juergen Pohrt ,  Ruediger Matern ,  Helmut Jenne ,  Hermann Gausepohl ,  Karl Gerberding

发明人： Juergen Pohrt ,  Ruediger Matern ,  Helmut Jenne ,  Hermann Gausepohl ,  Karl Gerberding

IPC分类号： C08L53/02 ,  C08L5/00 ,  C08L5/04

CPC分类号： C08L53/02 ,  Y10S525/905

摘要： A thermoplastic molding material comprises copolymers I and II.Copolymer I is a high-impact (graft) copolymer which is derived from a monovinyl-aromatic monomer and a polymer or copolymer predominantly containing polymerized 1,3-diene units, and is present in a proportion of 0.1-1.0% by weight, based on the molding material.Copolymer II is a block copolymer with star-shaped branching, ie. a radial block copolymer, having an average of more than two branches per molecule. It is substantially derived from 55-80% by weight of a monovinyl-aromatic monomer and 20-45% by weight of a 1,3-diene monomer.The molding material may contain conventional assistants and is used for the production of blown film.

摘要翻译： 热塑性成型材料包括共聚物I和II。 共聚物I是衍生自单乙烯基 - 芳族单体和主要含有聚合的1,3-二烯单元的聚合物或共聚物的高冲击（接枝）共聚物，并且以按重量计为0.1-1.0％ 在成型材料上。 共聚物II是具有星形分支的嵌段共聚物，即 每个分子平均具有多于两个分支的径向嵌段共聚物。 其基本上衍生自单乙烯基 - 芳族单体的55-80重量％和1,3-二烯单体的20-45重量％。 成型材料可以包含常规助剂，并且用于生产吹塑薄膜。