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    Polyisobutylene-based block anionomers and cationomers and synthesis thereof
    2.
    发明申请
    Polyisobutylene-based block anionomers and cationomers and synthesis thereof 有权
    聚异丁烯类嵌段阴离子和阳离子及其合成

    公开(公告)号：US20070203302A1

    公开(公告)日：2007-08-30

    申请号：US11605025

    申请日：2006-11-28

    申请人： Joseph Kennedy ,  Zheng Fang

    发明人： Joseph Kennedy ,  Zheng Fang

    IPC分类号： C08F293/00

    CPC分类号： C08F297/00 ,  C08F8/06 ,  C08F8/12 ,  C08F8/22 ,  C08F293/005 ,  C08F2438/01 ,  C08F2810/30 ,  C08F2810/40 ,  Y10S525/901 ,  C08F112/12 ,  C08F8/42 ,  C08F110/10

    摘要： Various novel block cationomers comprising polyisobutylene (PIB) and poly(2-dimethylamino)ethyl methacrylate) (PDMAEMA) segments have been synthesized and characterized. The specific targets were various molecular weight diblocks (PDMAEMA+) and triblocks (PDMAEMA+-b-PIB-b-PDMAEMA+) with the PIB blocks in the DPn=50-200 (Mn=3,000-9,000 g/mol) range connected to blocks of PDMAEMA+ cations in the DPn=5-20 range. The overall synthetic strategy for the preparation of these block cationomers comprised four steps: 1) Synthesis by living cationic polymerization of mono- and di-allyltelechelic polyisobutylenes, 2) End group transformation to obtain PIBs fitted with termini capable of mediating the atom transfer radical polymerization (ATRP) of DMAEMA, 3) ATRP of DMAEMA and 4) Quaternization of PDMAEMA to PDMAEMA+I− by CH3I. Kinetic and model experiments provided guidance to develop convenient synthesis methods. The microarchitecture of PIB-PDMAEMA di-and triblock and the corresponding block cationomers were confirmed by 1H NMR and FTIR spectroscopy and solubility studies.

    摘要翻译： 已经合成了各种包含聚异丁烯（PIB）和聚（2-二甲基氨基）乙基甲基丙烯酸酯）（PDMAEMA）链段的新型嵌段阳离子。 具体目标是各种分子量二嵌段（PDMAEMA +）和三嵌段（PDMAEMA-SUP-B-PIB-b-PDMAEMA +）以及 与PDMAEMA +阳离子的嵌段连接的DPA块中的PIB嵌段（DPN-N）= 50-200（M n n = 3,000-9,000g / mol） 在DP = 5-20范围内。 制备这些嵌段阳离子的总体合成策略包括四个步骤：1）通过单 - 和二 - 烯丙基可可聚异丁烯的阳离子聚合合成2）端基转化获得配有能够介导原子转移自由基聚合的末端的PIB （ATRP），3）DMAEMA的ATRP和4）通过CH 3 N取代PDMAEMA与PDMAEMA的反应。 动力学和模型实验为开发方便的合成方法提供了指导。 通过1 H NMR和FTIR光谱和溶解度研究证实了PIB-PDMAEMA二 - 和三嵌段的微结构和相应的嵌段阳离子。

    Crosslinked rubber particles and rubber compositions
    3.
    发明授权
    Crosslinked rubber particles and rubber compositions 有权
    交联橡胶颗粒和橡胶组合物

    公开(公告)号：US06977286B2

    公开(公告)日：2005-12-20

    申请号：US10762357

    申请日：2004-01-23

    申请人： Tomohisa Konno ,  Toshihiro Tadaki ,  Yoshiyuki Udagawa ,  Hiroshi Akema

    发明人： Tomohisa Konno ,  Toshihiro Tadaki ,  Yoshiyuki Udagawa ,  Hiroshi Akema

    IPC分类号： C08L9/06 ,  C08L21/00 ,  C08F118/00

    CPC分类号： C08L21/00 ,  C08L9/00 ,  C08L9/02 ,  C08L9/06 ,  C08L15/00 ,  C08L19/006 ,  C08L23/16 ,  C08L33/066 ,  C08L2205/22 ,  C08L2312/00 ,  Y10S525/901 ,  Y10S525/914 ,  Y10S526/909 ,  C08L2666/08

    摘要： An objective of the invention is to provide a rubber composition which has satisfactory processability and dimension stability, and the like, gives a vulcanized rubber exhibiting excellent wearing resistance and tensile strength, and the like, and thus is useful in a belt, a hose and a tire and the like, as well as a crosslinked rubber particle for obtaining such rubber composition. A rubber composition of the invention comprises [1] a crosslinked rubber particle comprising as repeating units (a) 30 to 94.89% by weight of a conjugated diene unit, (b) 5 to 69.89% by weight of an aromatic vinyl unit, (c) 0.01 to 10% by weight of a monomer unit having at least two polymerizable unsaturated group, (d) one polymerizable unsaturated group and an amino group, a hydroxyl group and an epoxy group and (e) 0.1 to 30% by weight of a monomer unit having one polymerizable unsaturated group and a carboxylic group and having a particle size of 10 to 500 nm and a toluene-insolubles of 80% by weight or more and [2] a non-crosslinked rubber component whose toluene-insolubles is less than 20% by weight.

    摘要翻译： 本发明的目的是提供一种具有令人满意的加工性和尺寸稳定性等的橡胶组合物，得到具有优异的耐磨性和拉伸强度的硫化橡胶等，因此可用于带，软管和 轮胎等，以及用于获得这种橡胶组合物的交联橡胶颗粒。 本发明的橡胶组合物包含[1]交联橡胶颗粒，其包含作为重复单元（a）30至94.89重量％的共轭二烯单元，（b）5至69.89重量％的芳族乙烯基单元，（c ）0.01〜10重量％的具有至少2个聚合性不饱和基团的单体单元，（d）1个聚合性不饱和基团和氨基，羟基和环氧基，（e）0.1〜30重量％ 具有一个聚合性不饱和基团和羧基的单体单元，其粒径为10〜500nm，甲苯不溶物为80重量％以上，[2]甲苯不溶物的非交联橡胶组分小于 20重量％。

    Elastomer - Modified thermoplastic olefin polymer compositions
    6.
    发明授权
    Elastomer - Modified thermoplastic olefin polymer compositions 失效
    弹性体 - 改性的热塑性烯烃聚合物组合物

    公开(公告)号：US5585441A

    公开(公告)日：1996-12-17

    申请号：US446163

    申请日：1995-05-22

    申请人： Ellen B. Brandes ,  Margaret D. Monahan ,  Steven L. Schafer

    发明人： Ellen B. Brandes ,  Margaret D. Monahan ,  Steven L. Schafer

    IPC分类号： C08L9/00 ,  C08L15/00 ,  C08L23/10 ,  C08L23/12 ,  C08L53/00 ,  C08L47/00

    CPC分类号： C08L15/00 ,  C08L23/10 ,  C08L23/12 ,  C08L53/005 ,  C08L2207/04 ,  C08L9/00 ,  Y10S525/901

    摘要： A thermoplastic composition comprising a crystalline propylene polymer and as a modifying elastomer, a hydrogenated butadiene polymer which is either an essentially linear hydrogenated butadiene homopolymer or a star-branched polymer, the arms of which are an essentially linear hydrogenated butadiene homopolymer, such hydrogenated butadiene polymer containing from about 20 to about 90% of polymerized butadiene units with the 1,2-microstructure and having a polydispersity index (P.I.) of about 1.01 to 1.50. The compositions have a superior combination of processing and mechanical properties such as flexural strength, impact resistance, and melt flow.

    摘要翻译： 包含结晶丙烯聚合物和改性弹性体的热塑性组合物，氢化丁二烯聚合物，其是基本上为线性的氢化丁二烯均聚物或星形支化聚合物，其臂是基本上线性的氢化丁二烯均聚物，这种氢化丁二烯聚合物 含有约20至约90％的具有1,2-微结构并且多分散指数（PI）为约1.01至1.50的聚合丁二烯单元。 组合物具有优良的加工和机械性能的组合，例如弯曲强度，抗冲击性和熔体流动性。

    Butadiene-base polymer and a process for producing the same
    8.
    发明授权
    Butadiene-base polymer and a process for producing the same 失效
    丁二烯基聚合物及其制备方法

    公开(公告)号：US4540744A

    公开(公告)日：1985-09-10

    申请号：US701438

    申请日：1985-02-12

    申请人： Noboru Oshima ,  Isamu Shimizu ,  Yoshito Yoshimura

    发明人： Noboru Oshima ,  Isamu Shimizu ,  Yoshito Yoshimura

    IPC分类号： C08F4/00 ,  C08C19/44 ,  C08F4/42 ,  C08F8/42 ,  C08F36/00 ,  C08F36/04 ,  C08F236/00 ,  C08F236/10 ,  C08L9/00 ,  C08L21/00

    CPC分类号： C08C19/44 ,  C08F36/04 ,  Y10S525/901

    摘要： A butadiene-base polymer containing a branched polymer through tin-carbon bond and a process for producing the same are disclosed. The butadiene-base polymer is produced by polymerizing 1,3-butadiene alone or 1,3-butadiene and aromatic vinyl compound in a hydrocarbon solvent in the presence of a Lewis base using an organolithium compound as an initiator and then coupling with a tin halide, and satisfies the following requirements:(1) a content of a bound aromatic vinyl compound in the butadiene-base polymer is 0-40% by weight;(2) a ratio of vinyl bond-containing butadiene unit in the toal butadiene unit of the butadiene-base polymer is 30-90%;(3) a ratio of the branched polymer in the butadiene-base polymer is at least 30% by weight; and(4) a ratio of a component having a molecular weight of less than 100,000 as polystyrene in the molecular weight distribution as measured by a gel permeation chromatography is 10-20% by weight.

    摘要翻译： 公开了含有通过锡 - 碳键的支化聚合物的丁二烯基聚合物及其制备方法。 丁二烯基聚合物通过使用有机锂化合物作为引发剂在路易斯碱存在下在烃溶剂中在单独的1,3-丁二烯和1,3-丁二烯和芳香族乙烯基化合物上聚合，然后与卤化锡 ，并且满足以下要求：（1）丁二烯基聚合物中结合的芳香族乙烯基化合物的含量为0〜40重量％ （2）丁二烯类聚合物的丁二烯单元中的含乙烯基键的丁二烯单元的比例为30〜90％。 （3）丁二烯类聚合物中的支链聚合物的比例为30重量％以上。 和（4）通过凝胶渗透色谱法测定的分子量分布中聚苯乙烯的分子量小于100,000的成分的比例为10〜20重量％。

    Impact-resistant thermoplastic molding material
    10.
    发明授权
    Impact-resistant thermoplastic molding material 失效
    耐冲击热塑性成型材料

    公开(公告)号：US4493922A

    公开(公告)日：1985-01-15

    申请号：US573853

    申请日：1984-01-25

    申请人： Adolf Echte ,  Hermann Gausepohl

    发明人： Adolf Echte ,  Hermann Gausepohl

    IPC分类号： C08L51/04 ,  C08L55/02 ,  C08L53/02

    CPC分类号： C08L51/04 ,  Y10S525/901

    摘要： An impact-resistant thermoplastic molding material, containing polystyrene as the matrix, and, dispersed therein, two elastomeric polymers or copolymers I and II composed entirely or predominantly of 1,3-dienes and containing particles of different mean size, namely, in I, particles from 0.2 to 0.6 .mu.m in size and having capsule particle morphology, and, in II, particles from 2 to 8 .mu.m in size, having cell particle or coil particle morphology.

    摘要翻译： 一种抗冲击热塑性成型材料，其包含聚苯乙烯作为基体，并分散在其中，两个完全或主要由1,3-二烯构成并含有不同平均尺寸的颗粒的弹性聚合物或共聚物I和II，即I， 颗粒尺寸为0.2至0.6微米，具有胶囊颗粒形态，II型颗粒尺寸为2至8微米，具有细胞颗粒或线粒体形态。