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公开(公告)号：US4976864A
公开(公告)日：1990-12-11
申请号：US418227
申请日：1989-10-06
CPC分类号： C02F9/00 , C02F1/025 , C02F1/469 , C02F2101/36 , C02F3/286 , Y10S210/908
摘要： Process for the treatment of aqueous effluents from the production of epoxy resins, which effluents contain as their main impurities chlorohydrins, glycidol, isopropyl alcohol and sodium chloride, which process comprises the following steps:(a) hydrolytic treatment of the effluent under alkaline conditions, until the effluent's content of epichlorohydrin in reduced down to values of about 75 ppm, and the effluent's glycidol content is reduced to values lower than about 4,000 ppm;(b) removal of about 90% of sodium chloride from the hydrolyzed effluent; and(c) anaerobic digestion of the hydrolyzed, sodium chloride-deprived effluent, after preliminary dilution, neutralization and integration with nitrogen and phosphorus sources.The (b) step can be carried out by means of a process of concentration of the effluent, in order to cause sodium chloride to precipitate, or by submitting the same effluent to a treatment of electrodialysis.
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公开(公告)号：US20060251571A1
公开(公告)日：2006-11-09
申请号：US10538925
申请日：2003-12-04
申请人： Roberto Gianna , Umberto Barberini , Mario Valdiserri , Francesco Crescenzi , Andrea Robertiello
发明人： Roberto Gianna , Umberto Barberini , Mario Valdiserri , Francesco Crescenzi , Andrea Robertiello
IPC分类号： C01B17/02
CPC分类号： C01B17/05 , B01D53/1468 , B01D53/52 , B01D53/84 , B01D2258/05 , C12M47/18 , Y02A50/2358 , Y10S423/17
摘要： The present application relates to a process for removing hydrogen sulfide H2S from a gas (1) by contacting said gas with a liquid solution (2) containing ferric sulfate in an absorption column (RC). Ferric sulfate and H2S react at room temperature and at a pressure ranging from 1 to 1.2 atm. Ferric ions being reduced to two-valent iron and sulfide oxidised to elemental sulfur. The liquid (4) coming out of the absorption column is filtered in two steps, the retentate (6, 8) comprising elemental sulfur, the filtrate (5, 7) containing the iron ions. The filtrate is sent to a bioreactor (RB) for regeneration, i.e. oxidation of iron to Fe3+ by means of thiobacillus ferroxidans and air injection (10). The regenerated solution is reused in the absorption column (RC). The process faces the problems relating to the alignment between the chemical step and the biological step in order to obtain a process which can stably run continuously.
摘要翻译： 本申请涉及通过在吸收塔（RC）中使所述气体与含有硫酸铁的液体溶液（2）接触从气体（1）除去硫化氢H 2 S的方法。 硫酸铁和H 2 S在室温和1至1.2atm的压力下反应。 铁离子还原成二价铁和硫化物氧化成元素硫。 从吸收塔出来的液体（4）分两个步骤过滤，包含元素硫的渗余物（6,8），含有铁离子的滤液（5,7）。 将滤液送到生物反应器（RB）进行再生，即通过硫杆菌硫氧芽孢杆菌和空气注射（10）将铁氧化成Fe 3+。 再生溶液在吸收塔（RC）中重复使用。 该方法面临与化学步骤和生物学步骤之间的对准有关的问题，以获得可以稳定地连续运行的方法。
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公开(公告)号：US4414333A
公开(公告)日：1983-11-08
申请号：US315473
申请日：1981-10-27
CPC分类号： C02F3/344 , B09C1/10 , Y10S210/922 , Y10S210/925 , Y10S516/07
摘要： Compositions are disclosed, which are adapted to depollute fresh and sea water bodies from crude oil and petroleum product pollution by microbial action. The growth of micro-organisms capable of metabolizing hydrocarbons is exalted by certain combination of nutrients, such as lecithin as a phosphorus source, hydantoins, amides allophanates, polyamines, acyl-ureas and esters of the hydantoic and allantoic acids as the nitrogen sources. Ureido-derivatives of amides are also contemplated as additional nutrients.
摘要翻译： 公开了适用于通过微生物作用对原油和石油产品污染对新鲜海水体和海水体产生污染的组合物。 能够代谢碳氢化合物的微生物的生长由作为磷源的卵磷脂，乙内酰脲，酰胺脲基甲酸酯，多胺，酰基脲和乙酸和尿囊酸的酯作为氮源的营养物质的某些组合而得以提高。 酰胺的脲基衍生物也被考虑作为额外的营养物质。
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4.发明授权
公开(公告)号：US4230562A
公开(公告)日：1980-10-28
申请号：US823043
申请日：1977-08-08
CPC分类号： C02F3/344 , B09C1/10 , Y10S210/922 , Y10S210/925 , Y10S516/07
摘要： A method and a few compositions are disclosed, which are adapted to depollute fresh and sea water bodies from crude oil and petroleum product pollution by microbial action. The growth of micro-organisms capable of metabolizing hydrocarbons is exalted by certain combination of nutrients, such as lecithin as a phosphorus source, hydantoins, amides allophanates, polyamines, acyl-ureas and esters of the hydantoic and allantoic acids as the nitrogen sources. Ureido-derivatives of amides are also contemplated as additional nutrients.
摘要翻译： 公开了一种方法和一些组合物，其适用于通过微生物作用对来自原油和石油产品污染的新鲜海水体和海水体进行破坏。 能够代谢碳氢化合物的微生物的生长由作为磷源的卵磷脂，乙内酰脲，酰胺脲基甲酸酯，多胺，酰基脲和乙酸和尿囊酸的酯作为氮源的营养物质的某些组合而得以提高。 酰胺的脲基衍生物也被考虑作为额外的营养物质。
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公开(公告)号：US4087356A
公开(公告)日：1978-05-02
申请号：US738697
申请日：1976-11-04
IPC分类号： C02F1/40 , C02F1/68 , C02F3/34 , C02F103/08 , C02B9/02
CPC分类号： C02F1/681 , C02F3/34 , Y10S210/922
摘要： A method is disclosed, for depolluting fresh and sea waters from hydrocarbonaceous pollutants, the improvement consisting in that the usual microorganism cultures used for oxidizing the hydrocarbons are integrated by lipophilic and floating compounds which contain slow-release nitrogen in a form which can be assimilated by such micro-organisms. Ureidic derivatives of higher aldehydes are the preferred compounds. Inert supports can be used, if necessary, and still better results are achieved when using also nonionic dispersants and freeze-dried hydrocarbon-oxidizing microorganisms.
摘要翻译： 公开了一种用于从含烃污染物污染新鲜海水和海水的方法，其改进包括用于氧化烃的通常微生物培养物通过亲脂性和漂浮的化合物整合，其中含有缓释氮，其形式可以被 这样的微生物。 较高级醛的尿素衍生物是优选的化合物。 如果需要，可以使用惰性载体，并且当使用非离子分散剂和冷冻干燥的烃氧化微生物时，还可获得更好的结果。
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6.发明授权Process for the biological treatment of solid waste and mud contaminated by hydrocarbons 失效用碳氢化合物污染的固体废物和泥土的生物处理工艺
公开(公告)号：US5551987A
公开(公告)日：1996-09-03
申请号：US327240
申请日：1994-10-21
摘要： Process for the biological treatment of mud and oily residues obtained fromhe processing or extraction of crude oil. This process can be applied to mud alone, its mixtures and to suitable combinations of mud and oily emulsions.
摘要翻译： 从原油加工或提取获得的泥浆和油性残渣的生物处理工艺。 该方法可以应用于泥土，其混合物以及泥浆和油性乳液的合适组合。
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公开(公告)号：US5874295A
公开(公告)日：1999-02-23
申请号：US807368
申请日：1997-02-27
申请人： Eugenio Fascetti , Ezio D'Addario , Roberto Gianna , Pasquale Sacceddu , Luca Serbolisca , Andrea Robertiello
发明人： Eugenio Fascetti , Ezio D'Addario , Roberto Gianna , Pasquale Sacceddu , Luca Serbolisca , Andrea Robertiello
CPC分类号： C12R1/06 , C10G32/00 , Y10S435/83
摘要： The invention relates to a strain of Arthrobacter sp. CBS 208.96 capable of selectively effecting the opening of the C-S bond of sulfurated organic molecules present in carbonaceous materials and its use in a process for the selective removal of organic sulfur from fossil fuels contained therein.
摘要翻译： 本发明涉及节杆菌属菌株 CBS 208.96能够选择性地实现碳质材料中存在的硫化有机分子的C-S键的打开，以及其用于从其中所含的化石燃料中选择性除去有机硫的方法。
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公开(公告)号：US4604125A
公开(公告)日：1986-08-05
申请号：US619038
申请日：1984-06-11
IPC分类号： C05F5/00
CPC分类号： C05F5/006
摘要： There is provided a solid composition of an organic fertilizer which is the solid product obtained by desalting a vinasse with phosphoric acid in the presence of ethanol. The product contains at least 1.5% of nitrogen, at least 4% of P.sub.2 O.sub.5, at least 5% of K.sub.2 O and at least 8% of carbon. Another composition, this one comprising a mixture of the foregoing with one or more inorganic or organic nitrogen, phosphorus or potassium compounds to yield a complex organo-mineral fertilizer, is also described.
摘要翻译： 提供了一种有机肥料的固体组合物，它是通过在乙醇存在下用磷酸对葡萄酒进行脱盐得到的固体产物。 产物含有至少1.5％的氮，至少4％的P 2 O 5，至少5％的K 2 O和至少8％的碳。 还描述了另一种组合物，该组合物包含前述物质与一种或多种无机或有机氮，磷或钾化合物的混合物，以产生复合有机矿物肥料。
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公开(公告)号：US4273659A
公开(公告)日：1981-06-16
申请号：US74742
申请日：1979-09-12
申请人： Andrea Robertiello , Ludwig Degen
发明人： Andrea Robertiello , Ludwig Degen
CPC分类号： C12F3/10 , A23K10/38 , Y02P60/873 , Y10S210/902 , Y10S426/807
摘要： For removing potassium salts from distiller's wash, an acid the potassium salts of which are poorly soluble and an organic solvent are added to the wash, whereafter the precipitated salts are collected on a filter and the solvent is recovered by distillation.
摘要翻译： 为了从蒸馏器的洗涤中除去钾盐，将其钾盐难溶的酸和有机溶剂加入到洗涤液中，然后将沉淀的盐收集在过滤器上，并通过蒸馏回收溶剂。
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公开(公告)号：US07438886B2
公开(公告)日：2008-10-21
申请号：US10538925
申请日：2003-12-04
申请人： Roberto Gianna , Umberto Barberini , Mario Galileo Valdiserri , Francesco Crescenzi , Andrea Robertiello
发明人： Roberto Gianna , Umberto Barberini , Mario Galileo Valdiserri , Francesco Crescenzi , Andrea Robertiello
CPC分类号： C01B17/05 , B01D53/1468 , B01D53/52 , B01D53/84 , B01D2258/05 , C12M47/18 , Y02A50/2358 , Y10S423/17
摘要： The present application relates to a process for removing hydrogen sulfide H2S from a gas (1) by contacting said gas with a liquid solution (2) containing ferric sulfate in an absorption column (RC). Ferric sulfate and H2S react at room temperature and at a pressure ranging from 1 to 1.2 atm. Ferric ions being reduced to two-valent iron and sulfide oxidised to elemental sulfur. The liquid (4) coming out of the absorption column is filtered in two steps, the retentate (6, 8) comprising elemental sulfur, the filtrate (5, 7) containing the iron ions. The filtrate is sent to a bioreactor (RB) for regeneration, i.e. oxidation of iron to Fe3+ by means of thiobacillus ferroxidans and air injection (10). The regenerated solution is reused in the absorption column (RC). The process faces the problems relating to the alignment between the chemical step and the biological step in order to obtain a process which can stably run continuously.
摘要翻译： 本申请涉及通过在吸收塔（RC）中使所述气体与含有硫酸铁的液体溶液（2）接触从气体（1）除去硫化氢H 2 S的方法。 硫酸铁和H 2 S在室温和1至1.2atm的压力下反应。 铁离子还原成二价铁和硫化物氧化成元素硫。 从吸收塔出来的液体（4）分两个步骤过滤，包含元素硫的渗余物（6,8），含有铁离子的滤液（5,7）。 将滤液送到生物反应器（RB）进行再生，即通过硫杆菌硫氧芽孢杆菌和空气注射（10）将铁氧化成Fe 3+。 再生溶液在吸收塔（RC）中重复使用。 该方法面临与化学步骤和生物学步骤之间的对准有关的问题，以获得可以稳定地连续运行的方法。
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