公开(公告)号：US06368473B1

公开(公告)日：2002-04-09

申请号：US09530110

申请日：2000-04-25

申请人： Nagakazu Furuya ,  Akihiro Sakata ,  Koji Saiki ,  Hiroaki Aikawa ,  Shinji Katayama ,  Kenzo Yamaguchi

发明人： Nagakazu Furuya ,  Akihiro Sakata ,  Koji Saiki ,  Hiroaki Aikawa ,  Shinji Katayama ,  Kenzo Yamaguchi

IPC分类号： C25B910

CPC分类号： C25B9/08 ,  C25B1/46 ,  C25B11/035

摘要： A sodium chloride electrolytic cell is provided, comprising a gas diffusion electrode that allows smooth supply and discharge of catholyte for electrolyzing sodium chloride and allows oxygen gas to come in good contact therewith. The sodium chloride electrolytic cell comprises an anode chamber having an anode into which an aqueous solution of sodium chloride and a cathode chamber having the foregoing gas diffusion electrode for producing an alkaline aqueous solution, the anode chamber and the cathode chamber being divided by an ion exchange membrane. The sodium chloride electrolytic cell is arranged to effect electrolysis in such a manner that there occurs no pressure differential between the catholyte chamber and the gas chamber in the gas diffusion electrode. Further, a nickel mesh substance is fitted in a concave portion having the same size as that of the gas diffusion electrode formed in the central portion of a thin nickel plate.

摘要翻译： 提供了一种氯化钠电解池，包括气体扩散电极，其允许阴极电解液的电解氯化钠的平滑供应和排出，并使氧气与其良好接触。 氯化钠电解槽包括具有阳极的阳极室，其中氯化钠水溶液和具有上述气体扩散电极的阴极室用于生产碱性水溶液，阳极室和阴极室被离子交换 膜。 氯化钠电解槽被设置为以不会在气体扩散电极中的阴极电解液室与气室之间发生压差的方式进行电解。 此外，将镍网状物体配合在与形成在薄镍板的中央部的气体扩散电极相同尺寸的凹部中。

公开(公告)号：US06383349B1

公开(公告)日：2002-05-07

申请号：US09701418

申请日：2000-11-29

申请人： Akihiro Sakata ,  Koji Saiki ,  Hiroaki Aikawa ,  Shinji Katayama ,  Kenzo Yamaguchi

发明人： Akihiro Sakata ,  Koji Saiki ,  Hiroaki Aikawa ,  Shinji Katayama ,  Kenzo Yamaguchi

IPC分类号： C25B908

CPC分类号： C25B11/035 ,  C25B9/04 ,  C25B9/08 ,  C25B15/08

摘要： An electrolytic cell using an oxygen cathode, for use in an ion-exchange membrane electrolytic soda process or the like, the electrolytic cell having; a structure, wherein, for effective supply and discharge of a caustic liquid and for an effective handling of a caustic liquid leakage, provided on an outer-side edge of the electrolytic cell are an upper chamber as a caustic liquid discharge outlet, a lower chamber as a caustic liquid introduction inlet, and a caustic-liquid room frame connected via a caustic liquid passage to thereby reduce a caustic liquid leakage; a structure, wherein a lower gas chamber is provided at the lower outer end of a cathode element to thereby handle a caustic liquid leakage from a gas diffusion electrode to a gas room; or a structure which uses a gas-liquid permeating gas diffusion electrode to supply an oxygen gas from an upper chamber communicating with a gas room and discharge a gas and a caustic liquid into a lower chamber.

摘要翻译： 一种使用氧阴极的电解槽，用于离子交换膜电解苏打工艺等，所述电解槽具有： 其特征在于，在所述电解槽的外侧缘设置有用于有效地供给和排出苛性液体以及有效地处理苛性液体泄漏的结构，作为苛性液体排出口的上部室，下部室 作为苛性液体引入入口，以及通过苛性液体通道连接的苛性液体室框架，从而减少苛性液体泄漏; 一种结构，其中在阴极元件的下外端处设置下气室，从而处理苛性液体从气体扩散电极泄漏到气室; 或使用气液渗透气体扩散电极从与气室连通的上室供给氧气并将气体和苛性液体排出到下室的结构。

公开(公告)号：US06372102B1

公开(公告)日：2002-04-16

申请号：US09581430

申请日：2000-10-16

申请人： Akihiro Sakata ,  Koji Saiki ,  Hiroaki Aikawa ,  Shinji Katayama ,  Kenzo Yamaguchi

发明人： Akihiro Sakata ,  Koji Saiki ,  Hiroaki Aikawa ,  Shinji Katayama ,  Kenzo Yamaguchi

IPC分类号： C25B1103

CPC分类号： C25B11/03 ,  C25B9/04

摘要： An electricity leading method for a gas diffusion electrode is provided, by which a gas diffusion electrode is easily fixed to a cathode current collecting frame, the contact part has reduced electrical resistance, even an electrically insulating mesh sheet can be utilized as a gas chamber, and only the gas diffusion electrode can be replaced in renewal of the electrode. The method includes preparing a gas diffusion electrode by sandwiching a conductor made of a highly conductive metallic mesh or spongy processed material in catalyst layers or attaching a catalyst layer onto the conductor while leaving the conductor exposed in the outer periphery of the electrode, and electrically connecting the exposed part of the conductor to a cathode chamber current collecting frame.

摘要翻译： 提供了一种用于气体扩散电极的电引导方法，其中气体扩散电极容易地固定到阴极集电框架，接触部分具有降低的电阻，甚至电绝缘网片也可以用作气体室， 并且只能在更换电极时更换气体扩散电极。 该方法包括通过将由导电金属网或海绵状处理材料制成的导体夹在催化剂层中或者将催化剂层附着在导体上而制备气体扩散电极，同时使导体暴露在电极的外周，并将电连接 导体的暴露部分到阴极室集电框架。

公开(公告)号：US5493766A

公开(公告)日：1996-02-27

申请号：US118217

申请日：1993-09-09

申请人： Shin-ichiro Yamakawa ,  Takeshi Hanada ,  Toshiyuki Tsuge ,  Kenichi Takakura ,  Masahiro Takeda ,  Kenzo Yamaguchi ,  Takemi Suzuki

发明人： Shin-ichiro Yamakawa ,  Takeshi Hanada ,  Toshiyuki Tsuge ,  Kenichi Takakura ,  Masahiro Takeda ,  Kenzo Yamaguchi ,  Takemi Suzuki

IPC分类号： B21B1/26 ,  C21D7/13 ,  C21D8/00 ,  C21D9/00 ,  B21B1/00

CPC分类号： C21D7/13 ,  C21D9/0081 ,  C21D2211/002 ,  Y10T29/49988 ,  Y10T29/49991

摘要： A process for hot working a continuous-cast bloom or a steel ingot, the process comprising the steps of: (1) cooling a bloom produced by continuous casting or a steel ingot produced with a mold to bring the surface temperature thereof to 50.degree. to 150.degree. C. higher than the Ar.sub.3 transformation point thereof; (2) quenching the bloom or the steel ingot in such a way that its interior remains red hot while the surface is transformed to have a bainite structure; and (3) heating the bloom or the steel ingot in a furnace followed by hot shaping.

摘要翻译： 一种用于对连续铸造的坯料或钢锭进行热加工的方法，该方法包括以下步骤：（1）冷却通过连续铸造产生的坯料或用模具生产的钢锭，使其表面温度为50℃至 比其Ar3相变点高150℃; （2）以使其内部保持红热同时将表面转化为具有贝氏体结构的方式淬火大块或钢锭; 和（3）在炉中加热花岗岩或钢锭，然后热成型。

公开(公告)号：US4421614A

公开(公告)日：1983-12-20

申请号：US326624

申请日：1981-12-02

申请人： Kenzo Yamaguchi ,  Yoshinari Take ,  Akiyoshi Manabe

发明人： Kenzo Yamaguchi ,  Yoshinari Take ,  Akiyoshi Manabe

IPC分类号： C25B15/00

CPC分类号： C25B15/00

摘要： The method for bypassing the electric current of at least one cell of an electrolytic apparatus includes a series combination of a resistor and a switch connected in parallel to the terminals of the cell to be repaired or replaced. In another embodiment a plurality of said series combinations may be connected in parallel to each other and be connected in parallel to the terminals of the cell to be bypassed.

摘要翻译： 用于绕过电解设备的至少一个电池的电流的方法包括电阻器和与要修理或更换的电池的端子并联连接的开关的串联组合。 在另一个实施例中，多个所述串联组合可以彼此并联连接并且并联连接到要旁路的单元的端子。

公开(公告)号：US4417970A

公开(公告)日：1983-11-29

申请号：US437598

申请日：1982-10-29

申请人： Kenzo Yamaguchi ,  Teruo Ichisaka ,  Tadao Ikegami ,  Isao Kumagai

发明人： Kenzo Yamaguchi ,  Teruo Ichisaka ,  Tadao Ikegami ,  Isao Kumagai

IPC分类号： C25B9/00 ,  C25B1/46 ,  C25B9/08 ,  C25B11/03 ,  C25B13/02 ,  C25B15/08

CPC分类号： C25B9/08

摘要： An electrolytic cell having a plurality of porous and tubular cathodes, a plurality of porous anodes and a plurality of bag-shaped molds being formed by a cation exchange membrane in at least the portions facing and between the vertical faces of the anode and cathodes. The anode accommodating bag-shaped molds have apertures at the bottom through which anode connected electroconductive bars extend, said bars being inserted through and secured at corresponding cell bottom plate apertures by flanges. A partition plate, on the top of the cell main body, has a plurality of openings which correspond to the open tops of the bag-shaped molds. The open top edges of the bag-shaped molds are secured to the partition plate openings by a plurality of lid members.

摘要翻译： 一种具有多个多孔和管状阴极的电解池，多个多孔阳极和多个袋形模具，其至少在面对阳极和阴极的垂直面之间的部分中由阳离子交换膜形成。 阳极容纳袋状模具在底部具有孔，阳极连接的导电杆通过该孔延伸，所述杆通过法兰插入并固定在相应的单元底板孔处。 在电池主体的顶部上的隔板具有与袋状模具的开口顶部对应的多个开口。 袋形模具的敞开的顶部边缘通过多个盖构件固定到隔板开口。

公开(公告)号：US4409084A

公开(公告)日：1983-10-11

申请号：US292464

申请日：1981-08-13

申请人： Kenzo Yamaguchi ,  Teruo Ichisaka ,  Tadao Ikegami

发明人： Kenzo Yamaguchi ,  Teruo Ichisaka ,  Tadao Ikegami

IPC分类号： C25B9/00 ,  C25B1/46 ,  C25B9/08 ,  C25B13/00 ,  C25B11/03 ,  C25B13/02 ,  C25B13/08

CPC分类号： C25B13/00 ,  C25B9/08

摘要： An electrolytic cell for the ion exchange membrane method, which comprises:(a) an electrolytic cell main body;(b) a lid covering the(c) porous and hollow tubular cathodes disposed in the body;(d) a bottom plate having apertures through which an electrically conductive bar can be extended;(e) electrically conductive bars provided with a flange at a lower portion thereof, each inserted through the apertures of the bottom plate into the interior of the body and secured to the bottom plate by the flange;(f) porous anodes each connected to the electrically conductive bar and placed vertically in a face-face relation to the cathode, and disposed between the cathodes;(g) bag-shaped elements, portions of which facing the anodes and the cathodes are formed by a cation exchange membrane, the bottom of which has at least one aperture through which the electrically conductive bar can be extended, and which have each an open top; and(h) a partition plate having openings, which plate is on the top of the body,whereinone or more anodes are in the bag-shaped element,the bottom of the bag-shaped element is secured to the bottom plate together with the electrically conductive bar extending through the aperture of the bottom of the bag-shaped element by the flange of the electrically conductive bar so that an anode compartment is defined in the bag-shaped element, andthe opening of the top of the bag-shaped element is secured to the opening of the partition plate by a gasket and a gasket cap.

摘要翻译： 一种离子交换膜方法用电解槽，其特征在于，包括：（a）电解槽主体; （b）覆盖设置在本体中的（c）多孔和中空管状阴极的盖子; （d）具有孔的底板，可以延伸导电棒; （e）在其下部设置有凸缘的导电杆，每个通过底板的孔插入主体的内部并通过凸缘固定到底板; （f）多孔阳极，每个阳极各自连接到导电棒并且以与阴极面对面的关系垂直放置并设置在阴极之间; （g）袋形元件，其部分面向阳极和阴极由阳离子交换膜形成，阳离子交换膜的底部具有至少一个孔，导电棒可以延伸通过该孔，并且每个开口 最佳; 和（h）具有开口的隔板，该板位于主体的顶部，其中一个或多个阳极位于袋状元件中，袋状元件的底部与 导电棒通过导电棒的凸缘延伸穿过袋形元件的底部的孔，使得在袋状元件中限定阳极室，并且袋状元件的顶部的开口 通过垫圈和垫圈盖固定到隔板的开口。