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    Polythiourethane-based polymerizable composition and optical resin obtained from the same
    2.
    发明授权
    Polythiourethane-based polymerizable composition and optical resin obtained from the same 有权
    聚硫氨酯类聚合性组合物和由其得到的光学树脂

    公开(公告)号：US08304506B2

    公开(公告)日：2012-11-06

    申请号：US11990616

    申请日：2006-08-04

    申请人： Akinori Ryu ,  Mamoru Tanaka ,  Kunio Okumura

    发明人： Akinori Ryu ,  Mamoru Tanaka ,  Kunio Okumura

    IPC分类号： C08G18/00

    CPC分类号： C08G18/757 ,  C08G18/3876 ,  G02B1/041 ,  C08L75/04 ,  C08L81/00

    摘要： Provided are a polymerizable composition for giving a resin which has a high refractive index and low dispersion, and is especially excellent in impact resistance and tintability; and a resin and an optical component each obtained by curing the composition. There used a polymerizable composition comprising (A) a compound represented by Formula (1) and/or by Formula (2), at least one compound as the following component (B), and at least one compound as the following component (C): (B) polythiol compounds optionally having at least one (poly)sulfide bond in a molecule, and (C) compounds represented by Formula (3): HO—[R1-(Y)n]m—R2-X  (3) (in above Formula (3), X is an OH group or a SH group; Y is an oxygen atom or a sulfur atom; R1 and R2 are each independently an optionally substituted methylene group or an optionally substituted alkylene group having carbon atoms of not smaller than 2 and not larger than 4; n is an integer of 0 or 1 when Y is an oxygen atom, or 0 or an integer of not smaller than 1 and not larger than 2 when Y is a sulfur atom; and m is 0 or an integer of not smaller than 1 and not larger than 3, provided that (carbon number of R1+n)×m+(carbon number of R2) is 3 or larger).

    摘要翻译： 提供一种用于赋予折射率高，分散性低的树脂的聚合性组合物，其耐冲击性和着色性特别优异; 以及通过固化该组合物而获得的树脂和光学部件。 使用包含（A）由式（1）表示的化合物和/或式（2）表示的化合物，至少一种下述成分（B）的化合物和至少一种下述成分（C）的化合物的聚合性组合物， ：（B）分子中任选具有至少一个（多）硫键的多硫醇化合物，和（C）由式（3）表示的化合物：HO- [R1-（Y）n] m-R2-X（3） （上述式（3）中，X为OH基或SH基; Y为氧原子或硫原子; R 1和R 2各自独立地为任选取代的亚甲基或碳原子的任选取代的亚烷基 小于2且不大于4;当Y为氧原子时，n为0或1的整数，当Y为硫原子时，为0或1以上2以下的整数，m为0 （R1 + n的碳数）×m +（碳数R2）为3以上）的1或更大的3以上的整数。

    Polyurethane/thiourethane-based optical resin and process for producing the same
    4.
    发明申请
    Polyurethane/thiourethane-based optical resin and process for producing the same 有权
    聚氨酯/硫代氨基甲酸酯类光学树脂及其制造方法

    公开(公告)号：US20090227745A1

    公开(公告)日：2009-09-10

    申请号：US11990644

    申请日：2006-08-04

    申请人： Osamu Kohgo ,  Junichi Mohri ,  Akinori Ryu ,  Mamoru Tanaka ,  Kunio Okumura

    发明人： Osamu Kohgo ,  Junichi Mohri ,  Akinori Ryu ,  Mamoru Tanaka ,  Kunio Okumura

    IPC分类号： C08G18/87

    CPC分类号： C08G18/3876 ,  C08G18/4825 ,  C08G18/757 ,  G02B1/041 ,  C08L75/04 ,  C08L81/00

    摘要： Provided is a process which can be carried out upon the production of a polyurethane/thiourethane-based resin with the use of a polyisocyanate compound, a polyol compound, and a polythiol compound, without causing abrupt heat generation or viscosity increase. At least one polyol compound having at least one ether bond and two or more hydroxy groups in a molecule is used as the polyol compound, whereby a large heat generation or an abrupt viscosity increase are prevented from occurring upon blending monomer.

    摘要翻译： 提供了可以在使用多异氰酸酯化合物，多元醇化合物和多硫醇化合物制备聚氨酯/硫代氨基甲酸酯类树脂的同时进行，而不会引起突然发热或粘度增加的方法。 在分子中使用至少一种具有至少一个醚键和两个或多个羟基的多元醇化合物作为多元醇化合物，由此在共混单体时可以防止发生大的发热或突然的粘度增加。

    Polythiourethane-based polymerizable composition and optical resin obtained from the same
    7.
    发明申请
    Polythiourethane-based polymerizable composition and optical resin obtained from the same 有权
    聚硫氨酯类聚合性组合物和由其得到的光学树脂

    公开(公告)号：US20090099329A1

    公开(公告)日：2009-04-16

    申请号：US11990616

    申请日：2006-08-04

    申请人： Akinori Ryu ,  Mamoru Tanaka ,  Kunio Okumura

    发明人： Akinori Ryu ,  Mamoru Tanaka ,  Kunio Okumura

    IPC分类号： C08G18/30

    CPC分类号： C08G18/757 ,  C08G18/3876 ,  G02B1/041 ,  C08L75/04 ,  C08L81/00

    摘要： Provided are a polymerizable composition for giving a resin which has a high refractive index and low dispersion, and is especially excellent in impact resistance and tintability; and a resin and an optical component each obtained by curing the composition. There used a polymerizable composition comprising (A) a compound represented by Formula (1) and/or by Formula (2), at least one compound as the following component (B), and at least one compound as the following component (C): (B) polythiol compounds optionally having at least one (poly)sulfide bond in a molecule, and (C) compounds represented by Formula (3): HO—[R1-(Y)n]m—R2-X  (3) (in above Formula (3), X is an OH group or a SH group; Y is an oxygen atom or a sulfur atom; R1 and R2 are each independently an optionally substituted methylene group or an optionally substituted alkylene group having carbon atoms of not smaller than 2 and not larger than 4; n is an integer of 0 or 1 when Y is an oxygen atom, or 0 or an integer of not smaller than 1 and not larger than 2 when Y is a sulfur atom; and m is 0 or an integer of not smaller than 1 and not larger than 3, provided that (carbon number of R1+n)×m+(carbon number of R2) is 3 or larger).

    摘要翻译： 提供一种用于赋予折射率高，分散性低的树脂的聚合性组合物，其耐冲击性和着色性特别优异; 以及通过固化该组合物而获得的树脂和光学部件。 使用包含（A）由式（1）表示的化合物和/或式（2）表示的化合物，至少一种下述成分（B）的化合物和至少一种下述成分（C）的化合物的聚合性组合物， ：（B）分子中任选具有至少一个（多）硫键的多硫醇化合物，和（C）式（3）表示的化合物：<？在线式描述=“在线式”末端=“ 引线“→HO- [R1-（Y）n] m-R2-X（3）<？in-line-formula description =”In-line Formulas“end =”tail“？> ），X是OH基或SH基; Y是氧原子或硫原子; R 1和R 2各自独立地是任选取代的亚甲基或任选取代的碳原子数不小于2且不大于2的亚烷基 当Y为氧原子时，n为0或1的整数，Y为硫原子时为0或1以上2以下的整数，m为0以下的整数。 1以上3以下 （碳数R1 + n）×m +（碳数R2）为3以上）。