摘要:
Provided is a process which can be carried out upon the production of a polyurethane/thiourethane-based resin with the use of a polyisocyanate compound, a polyol compound, and a polythiol compound, without causing abrupt heat generation or viscosity increase. At least one polyol compound having at least one ether bond and two or more hydroxy groups in a molecule is used as the polyol compound, whereby a large heat generation or an abrupt viscosity increase are prevented from occurring upon blending monomer.
摘要:
Provided is a process which can be carried out upon the production of a polyurethane/thiourethane-based resin with the use of a polyisocyanate compound, a polyol compound, and a polythiol compound, without causing abrupt heat generation or viscosity increase. At least one polyol compound having at least one ether bond and two or more hydroxy groups in a molecule is used as the polyol compound, whereby a large heat generation or an abrupt viscosity increase are prevented from occurring upon blending monomer.
摘要:
The present invention provides an olefin polymer having a narrow molecular weight distribution and a specific molecular weight, an olefin polymer having a functional group introduced at the terminal, a tapered polymer containing a segment wherein monomer composition continuously changes in the polymer chain, an olefin polymer having different segments which are bonded to each other, and a process for preparing these polymers. The olefin polymers of the invention are polymers of olefins of 2 to 20 carbon atoms and have a number-average molecular weight of not less than 500 and Mw/Mn of not more than 1.5. In the process for preparing an olefin polymer, an olefin of 2 to 20 carbon atoms is polymerized in the presence of an olefin polymerization catalyst comprising a transition metal compound represented by, for example, the following formula (I): LmMXn (I) wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table, m is 1 to 5, n is a number satisfying a valence of M, L is a ligand coordinated to the central metal M and is a ligand containing a heteroatom having no direct bond to the central metal, and X is a halogen atom, a hydrocarbon group or the like.
摘要:
Copolymers when used as lubricating oil viscosity modifiers enable lubricating oils to show excellent low-temperature properties. Processes for producing the copolymers are disclosed. Lubricating oil viscosity modifiers and lubricating oil compositions contain the copolymers.A copolymer includes structural units derived from ethylene and structural units derived from a C3-20 α-olefin and satisfies the following requirements (1) to (8): (1) the melting point (Tm) according to DSC is in the range of 0 to 60° C.; (2) the melting point (Tm) and the density D (g/cm3) satisfy the equation: Tm≧1073×D−893; (3) Mw/Mn according to GPC is from 1.6 to 5.0; (4) the half-value width (ΔThalf) of a melting peak measured by DSC is not more than 90° C.; (5) the half-value width (ΔThalf) and the melting point (Tm) satisfy the equation: ΔThalf≦−0.71×Tm+101.4; (6) the heat of fusion (ΔH) as measured by DSC is not more than 60 J/g; (7) the crystallization temperature (Tc) measured by DSC is not more than 70° C.; (8) the heat of fusion (ΔH), the crystallization temperature (Tc), each measured by DSC and the crystallization temperature measured by a CRYSTAF method (Tcrystaf) satisfy the equation: Tc−Tcrystaf≧0.028×ΔH+25.3.
摘要:
A copolymer containing a constituent unit derived from ethylene and a constituent unit derived from an α-olefin having 3 to 20 carbon atoms and satisfying the following requirements (1) to (5): (1) the copolymer has a melting point (Tm) of −20° C. to 100° C.; (2) the melting point (Tm) and the density D (g/cm3) satisfy the following expression Tm≧1073×D−893 (1); (3) the copolymer has a molecular weight distribution (Mw/Mn) measured by GPC of 1.6 to 5.0; (4) the copolymer has a half-width (ΔThalf) of a melting peak measured by DSC of 90° C. or less; and (5) the half-width (ΔThalf) and the melting point (Tm) satisfy the relationship shown by the following expression ΔThalf≦−0.71×Tm+101.4. (2)
摘要:
The present invention provides an olefin polymer having a narrow molecular weight distribution and a specific molecular weight, an olefin polymer having a functional group introduced at the terminal, a tapered polymer containing a segment wherein monomer composition continuously changes in the polymer chain, an olefin polymer having different segments which are bonded to each other, and a process for preparing these polymers. The olefin polymers of the invention are polymers of olefins of 2 to 20 carbon atoms and have a number-average molecular weight of not less than 500 and Mw/Mn of not more than 1.5. In the process for preparing an olefin polymer, an olefin of 2 to 20 carbon atoms is polymerized in the presence of an olefin polymerization catalyst comprising a transition metal compound represented by, for example, the following formula (I): LmMXn (I) wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table, m is 1 to 5, n is a number satisfying a valence of M, L is a ligand coordinated to the central metal M and is a ligand containing a heteroatom having no direct bond to the central metal, and X is a halogen atom, a hydrocarbon group or the like.
摘要:
Olefin polymer with narrow molecular weight distribution and specific molecular weight, olefin polymer having functional group introduced at terminal, tapered polymer containing segment wherein monomer composition continuously changes in the polymer chain, olefin polymer having different segments bonded to each other, and process for preparing these polymers. The olefin polymers are polymers of C2-20 carbon atom olefins and have a number-average molecular weight of ≧500 and Mw/Mn of ≦1.5. In syntheses, an olefin of 2-20 carbon atoms is polymerized in the presence of a catalyst comprising a transition metal compound represented by the formula LmMXn wherein M is a transition metal atom of Group 3-11, m is 1-5, n is a number satisfying a valence of M, L is a ligand—coordinated to the central metal M—which contains a heteroatom having no direct bond to the central metal, and X is e.g. halogen or a hydrocarbon.
摘要:
The present invention provides an olefin polymer having a narrow molecular weight distribution and a specific molecular weight, an olefin polymer having a functional group introduced at the terminal, a tapered polymer containing a segment wherein monomer composition continuously changes in the polymer chain, an olefin polymer having different segments which are bonded to each other, and a process for preparing these polymers. The olefin polymers of the invention are polymers of olefins of 2 to 20 carbon atoms and have a number-average molecular weight of not less than 500 and Mw/Mn of not more than 1.5. In the process for preparing an olefin polymer, an olefin of 2 to 20 carbon atoms is polymerized in the presence of an olefin polymerization catalyst comprising a transition metal compound represented by, for example, the following formula (I): LmMXn (I) wherein M is a transition metal atom of Group 3 to Group 11 of the periodic table, m is 1 to 5, n is a number satisfying a valence of M, L is a ligand coordinated to the central metal M and is a ligand containing a heteroatom having no direct bond to the central metal, and X is a halogen atom, a hydrocarbon group or the like.
摘要:
Copolymers when used as lubricating oil viscosity modifiers enable lubricating oils to show excellent low-temperature properties. Processes for producing the copolymers are disclosed. Lubricating oil viscosity modifiers and lubricating oil compositions contain the copolymers.A copolymer includes structural units derived from ethylene and structural units derived from a C3-20 α-olefin and satisfies the following requirements (1) to (8): (1) the melting point (Tm) according to DSC is in the range of 0 to 60° C.; (2) the melting point (Tm) and the density D (g/cm3) satisfy the equation: Tm≧1073×D−893; (3) Mw/Mn according to GPC is from 1.6 to 5.0; (4) the half-value width (ΔThalf) of a melting peak measured by DSC is not more than 90° C.; (5) the half-value width (ΔThalf) and the melting point (Tm) satisfy the equation: ΔThalf≦−0.71×Tm+101.4; (6) the heat of fusion (ΔH) as measured by DSC is not more than 60 J/g; (7) the crystallization temperature (Tc) measured by DSC is not more than 70° C.; (8) the heat of fusion (ΔH), the crystallization temperature (Tc), each measured by DSC and the crystallization temperature measured by a CRYSTAF method (Tcrystaf) satisfy the equation: Tc−Tcrystaf≧0.028×ΔH+25.3.
摘要:
A copolymer containing a constituent unit derived from ethylene and a constituent unit derived from an α-olefin having 3 to 20 carbon atoms and satisfying the following requirements (1) to (5): (1) the copolymer has a melting point (Tm) of −20° C. to 100° C.; (2) the melting point (Tm) and the density D (g/cm3) satisfy the following expression Tm≧1073×D−893 (1); (3) the copolymer has a molecular weight distribution (Mw/Mn) measured by GPC of 1.6 to 5.0; (4) the copolymer has a half-width (ΔThalf) of a melting peak measured by DSC of 90° C. or less; and (5) the half-width (ΔThalf) and the melting point (Tm) satisfy the relationship shown by the following expression ΔThalf≦−0.71×Tm+101.4 (2).