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公开(公告)号：US20100234543A1
公开(公告)日：2010-09-16
申请号：US12734585
申请日：2008-10-15
申请人： Alain Berardi , Andre Frederich , Jan Dominique , Jean-Jacques Kuhlburger , Anthony Sgard , Alain Van Daele
发明人： Alain Berardi , Andre Frederich , Jan Dominique , Jean-Jacques Kuhlburger , Anthony Sgard , Alain Van Daele
IPC分类号： C08F4/50
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6492 , C08F4/6426 , C08F2500/12 , C08F210/14
摘要： The present invention relates to a process for polymerisation of ethylene, in particular a process which comprises using a catalyst system comprising comprising a catalyst system comprising: i) a solid catalyst comprising Ti, Mg and halogen, ii) a first activator which is at least one trialkylaluminium compound of the formula AIR3, where each R is independently a C2 to C20 alkyl radical, and iii) a second activator which is at least one alkylaluminium chloride of the formula AlR′2Cl, where each R′ is independently a C2 to C20 alkyl radical, characterised in that the second activator is introduced directly in the polymerisation reactor, without precontact with the solid catalyst, continuously or semi-continuously and at a maximum rate of introduction at any time corresponding to less than 10 ppm by weight of chlorine relative to the rate of polyethylene production.
摘要翻译： 本发明涉及一种聚合乙烯的方法，特别是包括使用包括催化剂体系的催化剂体系的方法，所述催化剂体系包含：i）包含Ti，Mg和卤素的固体催化剂，ii）至少第一活化剂 一种式为AIR3的三烷基铝化合物，其中每个R独立地为C 2至C 20烷基，和iii）第二活化剂，其为至少一种式AlR'2Cl的烷基氯化铝，其中每个R'独立地为C 2至C 20 烷基，其特征在于，第二活化剂直接在聚合反应器中引入，不与固体催化剂预接触，连续或半连续并且以最大引入速率在任何时间对应于小于10ppm重量的氯相对 达到聚乙烯生产率。
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公开(公告)号：US08293857B2
公开(公告)日：2012-10-23
申请号：US12734585
申请日：2008-10-15
申请人： Alain Berardi , Andre Frederich , Dominique Jan , Jean-Jacques Kuhlburger , Anthony Sgard , Alain Van Daele
发明人： Alain Berardi , Andre Frederich , Dominique Jan , Jean-Jacques Kuhlburger , Anthony Sgard , Alain Van Daele
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6492 , C08F4/6426 , C08F2500/12 , C08F210/14
摘要： Process for polymerization of ethylene using a catalyst system including (i) a solid catalyst of Ti, Mg and halogen, (ii) a first activator which is at least one trialkylaluminium compound of the formula AlR3, where each R is independently a C2 to C20 alkyl radical, and (iii) a second activator which is at least one alkylaluminium chloride of the formula AlR′2Cl, where each R′ is independently a C2 to C20 alkyl radical. The second activator is introduced directly into the polymerization reactor, without precontact with the solid catalyst, continuously or semi-continuously, and at a maximum rate of introduction at any time corresponding to less than 10 ppm by weight of chlorine relative to the rate of polyethylene production.
摘要翻译： 使用包括（i）Ti，Mg和卤素的固体催化剂的催化剂体系聚合乙烯的方法，（ii）第一活化剂，其为至少一种式AlR 3的三烷基铝化合物，其中每个R独立地为C 2至C 20 烷基，和（iii）第二活化剂，其为至少一种式AlR'2Cl的烷基氯化铝，其中每个R'独立地为C 2至C 20烷基。 将第二活化剂直接引入聚合反应器中，无需与固体催化剂预连接，连续或半连续，并且在任何相应于低于10ppm重量的氯的聚合物的最大引入速率相对于聚乙烯的速率 生产。
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公开(公告)号：US06462152B1
公开(公告)日：2002-10-08
申请号：US09698258
申请日：2000-10-30
IPC分类号： C08F201
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , Y10S526/901 , C08F4/025 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F2500/24 , C08F4/60089 , C08F4/7042
摘要： A process for the polymerization of 1-olefins which comprises the steps of a) preparing a prepolymer-based catalyst by contacting one or more 1-olefins with a catalyst system, and b) contacting the prepolymer-based catalyst with one or more 1-olefins, wherein the catalyst system comprises (1) a compound of formula (I) wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], RU[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4, R5, R6 and R7 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two or more of R1-R7 are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; optionally (2) an activator, and also optionally (3) a compound of the formula AlR3, wherein each R is independently C1-C12 alkyl or halo.
摘要翻译： 一种用于1-烯烃聚合的方法，其包括以下步骤：a）通过使一种或多种1-烯烃与催化剂体系接触来制备预聚物基催化剂，和b）使预聚物基催化剂与一种或多种1- 烯烃，其中所述催化剂体系包含（1）其中M是Fe [II]，Fe [III]，Co [I]，Co [II]，Co [III]，Mn [I]， Mn [II]，Mn [III]，Mn [IV]，Ru [II]，RU [III]或Ru [IV] X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4，R 5，R 6和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; 并且当R 1 -R 7中的任何两个或更多个是烃基，取代的烃基，杂烃基或取代的杂烃基时，所述两个或更多个可以连接以形成一个或多个环状取代基; 任选地（2）活化剂，并且还任选地（3）式AlR 3的化合物，其中每个R独立地是C 1 -C 12烷基或卤素。
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公开(公告)号：US06677267B2
公开(公告)日：2004-01-13
申请号：US09830229
申请日：2001-04-24
IPC分类号： B01J3118
CPC分类号： C08F110/02 , C08F10/00 , Y10S526/901 , Y10S526/905 , C08F4/695 , C08F4/025 , C08F2500/12 , C08F2500/07 , C08F4/7042
摘要： The present invention relates to a process for the polymerization and copolymerization of 1-olefins and to a catalyst to be used in said process wherein the catalyst comprises (1) a complex having formula (I) wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the metal M; T is the oxidation state of the metal; b is the valency of the atom or group X; and R 1 to R 7 are each independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl, substituted heterohydrocarbyl or SiR′ 3 where each R′ is independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl, substituted heterohydrocarbyl; and when any two or more of R 1 to R 7 are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; (2) an activator which is an alkylalumoxane; and (3) a support material, wherein the atomic ratio of aluminium in the alkylalumoxane (2) to transition metal M in (1) is from 6:1 to 25:1.
摘要翻译： 本发明涉及一种用于所述方法中使用的1-烯烃和催化剂的聚合和共聚方法，其中催化剂包含（1）式（I）的络合物，其中M是Fe [II]，Fe [ III]，Co [I]，Co [II]，Co [III]，Mn [I]，Mn [II]，Mn [III]，Mn [Ⅳ]，Ru [II] IV]; X表示与金属M共价或离子键合的原子或基团; T是金属的氧化态; b是原子或基团X的化合价; R 1至R 7各自独立地选自氢，卤素，烃基，取代的烃基，杂烃基，取代的杂烃基或SiR 3，其中每个R'独立地选自氢，卤素，烃基，取代的烃基，杂烃基，取代的杂烃基; 当R 1至R 7中的任何两个或更多个为烃基，取代的烃基，杂烃基或取代的杂烃基时，所述两个或多个可以连接形成一个或多个环状取代基; （2）作为烷基铝氧烷的活化剂; 和（3）支撑材料，其中烷基铝氧烷（2）中的铝与（1）中的过渡金属M的原子比为6：1至25：1。
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