公开(公告)号：US06383230B1

公开(公告)日：2002-05-07

申请号：US09484994

申请日：2000-01-18

Applicant: Alain Genet ,  Alan Lagrange

Inventor： Alain Genet ,  Alan Lagrange

IPC: A61K713

CPC classification number: C07D295/13 ,  C07C211/63 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08

Abstract: The invention relates to novel monobenzenic dyes including at least one cationic group Z, Z chosen from quaternized aliphatic chains, aliphatic chains including at least one quaternized saturated ring and aliphatic chains including at least one quaternized unsaturated ring, to their use as oxidation-dye precursors for the oxidation-dyeing of keratin fibers, to dye compositions containing them and to oxidation-dyeing processes using them.

Abstract translation: 本发明涉及包括至少一种选自季铵化脂族链的阳​​离子基团Z，Z，包括至少一个季铵化饱和环的脂族链和包含至少一个季铵化不饱和环的脂族链，用作氧化 - 染料前体的新型单苯染料 用于角蛋白纤维的氧化染色，含有它们的染料组合物和使用它们的氧化 - 染色方法。

公开(公告)号：US06458167B1

公开(公告)日：2002-10-01

申请号：US09484998

申请日：2000-01-18

Applicant: Alain Genet ,  Alan Lagrange

Inventor： Alain Genet ,  Alan Lagrange

IPC: A61K713

CPC classification number: A61K8/4946 ,  A61K8/40 ,  A61Q5/065

Abstract: The invention relates to dyeing compositions containing phenyl-azo-benzene compounds comprising at least one cationic group Z, Z being chosen from quaternized aliphatic chains, aliphatic chains comprising at least one quaternized saturated ring and aliphatic chains comprising at least one quaternized unsaturated ring, to the use of such compositions as direct dyes in dyeing applications for keratin substances, in particular human keratin fibers and especially the hair, and to the direct dyeing processes employing these compositions.

Abstract translation: 本发明涉及包含苯基 - 偶氮苯化合物的染色组合物，其包含至少一个阳离子基团Z，Z选自季铵化脂族链，包含至少一个季铵化饱和环的脂族链和包含至少一个季铵化不饱和环的脂族链， 使用这种组合物作为直接染料在用于角蛋白物质，特别是人角蛋白纤维，特别是毛发的染色应用中，以及使用这些组合物的直接染色方法。

公开(公告)号：US06645259B2

公开(公告)日：2003-11-11

申请号：US10190518

申请日：2002-07-09

Applicant: Alain Genet ,  Alain Lagrange

Inventor： Alain Genet ,  Alain Lagrange

IPC: A61K713

CPC classification number: A61K8/355 ,  A61Q5/065 ,  C09B1/207

Abstract: Cationic aminoanthraquinones in which at least one cationic charge is delocalized on a 5-membered unsaturated polynitrogen-containing heterocycle, their use as a direct dye in dyeing compositions for keratinous materials, in particular for human keratinous fibers such as hair, dyeing compositions containing them, and dyeing methods using these compositions.

公开(公告)号：US06554872B2

公开(公告)日：2003-04-29

申请号：US09450218

申请日：1999-11-29

Applicant: Alain Genet ,  Alain Lagrange

Inventor： Alain Genet ,  Alain Lagrange

IPC: A61K718

CPC classification number: A61Q5/10 ,  A61K8/355 ,  C09B1/207

Abstract: The invention relates to cationic aminodianthraquinones containing at least one cationic group Z, Z being chosen from quaternized aliphatic chains, aliphatic chains containing at least one quaternized saturated ring and aliphatic chains containing at least one quaternized unsaturated ring, their use as direct dye in compositions for dyeing keratinous materials, in particular human keratinous fibers such as hair, the dyeing compositions containing them, as well as the dyeing methods using them.

Abstract translation: 本发明涉及含有至少一个阳离子基团Z，Z选自季铵化脂族链，含有至少一个季铵化饱和环的脂族链和至少含有一个季铵化不饱和环的脂族链的阳​​离子氨基蒽醌，它们用作组合物中的直接染料 染色角质材料，特别是人角质纤维如毛发，含有它们的染色组合物，以及使用它们的染色方法。

公开(公告)号：US06464731B1

公开(公告)日：2002-10-15

申请号：US09479079

申请日：2000-01-07

Applicant: Alain Genet ,  Alain Lagrange

Inventor： Alain Genet ,  Alain Lagrange

IPC: A61K713

CPC classification number: C07D231/12 ,  C07D233/56 ,  C07D249/08

Abstract: The subject of the invention is cationic monobenzene nitrophenylenediamines having at least one cationic charge delocalized over an unsaturated 5-membered polynitrogenous heterocycle, to their use as direct dye in dyeing compositions for keratinous substances, in particular for human keratinous fibers, such as the hair, to the dyeing compositions comprising them and to the dyeing processes employing these compositions.

Abstract translation: 本发明的主题是具有至少一种阳离子电荷的阳离子单苯基硝基苯二胺，其具有在不饱和5元多氮杂环上离域的至少一种阳离子电荷，其用作角质物质特别是人角质纤维例如头发的染色组合物中的直接染料， 涉及包含它们的染色组合物和使用这些组合物的染色方法。

公开(公告)号：US5534037A

公开(公告)日：1996-07-09

申请号：US456814

申请日：1995-06-01

Applicant: Alex Junino ,  Alain Genet ,  Alain Lagrange

Inventor： Alex Junino ,  Alain Genet ,  Alain Lagrange

IPC: C07C233/03 ,  C07C323/32 ,  C07C323/36 ,  A61K7/13

CPC classification number: A61Q5/10 ,  A61K8/46 ,  C07C323/36

Abstract: The invention relates to a dye composition for keratinic fibers comprising an oxidation colorant precursor of the type ortho and/or para and a sulfured metaphenylenediamine having formula (I) ##STR1## wherein Z is alkyl, aralkyl, monohydroxyalkyl or polyhydroxyalkyl, aryl or aminoalkyl, as well as the acid salts thereof, with the condition that R.sub.1 and R.sub.2 do not represent simultaneously hydrogen when Z is alkyl or hydroxyalkyl, as well as the acid salts corresponding to the compounds of formula (I).

Abstract translation: 本发明涉及用于角蛋白纤维的染料组合物，其包含邻位和/或对位的氧化着色剂前体和具有式（I）的硫代偏苯二胺其中Z是烷基，芳烷基，单羟基烷基或多羟基烷基，芳基 或氨基烷基，以及其酸式盐，其中当Z是烷基或羟烷基时，R1和R2不同时代表氢，以及与式（I）化合物相应的酸式盐。

公开(公告)号：US5534036A

公开(公告)日：1996-07-09

申请号：US357745

申请日：1994-12-16

Applicant: Alex Junino ,  Alain Lagrange ,  Alain Genet

Inventor： Alex Junino ,  Alain Lagrange ,  Alain Genet

IPC: A61K8/00 ,  A61K8/33 ,  A61K8/40 ,  A61K8/41 ,  A61K8/46 ,  A61K8/49 ,  A61Q5/10 ,  C07C323/36 ,  C07C323/41 ,  A61K7/13

CPC classification number: A61Q5/10 ,  A61K8/411 ,  A61K8/46 ,  C07C323/36 ,  C07C323/41

Abstract: The present invention provides compositions of sulfated metaphenylenediamines for dyeing keratinous fibers and methods for their use.

Abstract translation: 本发明提供用于染色角质纤维的硫酸化偏苯二胺的组合物及其使用方法。

公开(公告)号：US5364413A

公开(公告)日：1994-11-15

申请号：US974903

申请日：1992-11-12

Applicant: Alex Junino ,  Alain Genet ,  Gerard Lang

Inventor： Alex Junino ,  Alain Genet ,  Gerard Lang

IPC: A61K8/00 ,  A61K8/33 ,  A61K8/40 ,  A61K8/41 ,  A61K8/46 ,  A61K8/49 ,  A61Q5/10 ,  C07C205/37 ,  C07C217/26 ,  C07C217/84 ,  C07C323/36 ,  D06P3/00 ,  A61K7/13 ,  C07C211/00 ,  C07C215/00

CPC classification number: A61K8/415 ,  A61Q5/10 ,  C07C205/37 ,  C07C217/84 ,  C07C323/36

Abstract: 3-Substituted para-aminophenols, process for preparing them, their use for dyeing keratinous fibres and the intermediate compounds used in the process of preparation.3-Substituted para-aminophenols, of general formula: ##STR1## where X.dbd.H, halogen; Y.dbd.O--, --S--; R.dbd.alkyl, hydroxyalkyl, C.sub.1-4 aminoalkyl or C.sub.3 -C.sub.6 polyhydroxyalkyl;with the proviso that, when X.dbd.H, R is not methyl, and when X.dbd.H and Y.dbd.O, R is not ethyl;process #or preparing them, intermediate compounds of formula: ##STR2## where X.sup.1 .dbd.halogen, Y and R have the meaning stated above; with the proviso that, when Y.dbd.O, R is not methyl, and when R.dbd.aminoalkyl, X.sub.1 can also denote hydrogen;dyeing compositions containing one or more compounds of formula (I), and a process for dyeing human hair.

Abstract translation: 3-取代的对氨基苯酚，其制备方法，它们用于染色角质纤维和在制备过程中使用的中间体化合物的用途。 3-取代的对氨基苯酚，其通式如下：其中X = H，卤素; Y = O-，-S-; R =烷基，羟基烷基，C 1-4氨基烷基或C 3 -C 6多羟基烷基; 条件是当X = H时，R不是甲基，当X = H且Y = O时，R不是乙基; 制备它们的化合物，其中X1 =卤素，Y和R具有上述含义的下式的中间体化合物： 条件是当Y = O时，R不是甲基，当R =氨基烷基时，X1也可以表示氢; 含有一种或多种式（I）化合物的染色组合物和染发人发的方法。

公开(公告)号：US5084067A

公开(公告)日：1992-01-28

申请号：US316921

申请日：1989-02-28

Applicant: Alex Junino ,  Alain Genet ,  Gerard Lang

Inventor： Alex Junino ,  Alain Genet ,  Gerard Lang

IPC: A61K8/00 ,  A61K8/33 ,  A61K8/40 ,  A61K8/41 ,  A61K8/46 ,  A61K8/49 ,  A61Q5/10 ,  C07C205/37 ,  C07C217/26 ,  C07C217/84 ,  C07C323/36 ,  D06P3/00

CPC classification number: A61K8/415 ,  A61Q5/10 ,  C07C205/37 ,  C07C217/84 ,  C07C323/36

Abstract: 3-Substituted para-aminophenols of general formula: ##STR1## where X.dbd.H, halogen; Y.dbd.O--, --S--; R.dbd.alkyl, hydroxyalkyl, C.sub.1-4 aminoalkyl or C.sub.3 -C.sub.6 polyhydroxyalkyl;with the proviso that, when X.dbd.H, R is not methyl, and when X.dbd.H and Y.dbd.O, R is not ethyl;process for preparing them, intermediate compounds of formula: ##STR2## where X.sub.1 =halogen, Y and R have the meaning stated above; with the proviso that, when Y.dbd.O, R is not methyl, and when R=aminoalkyl, X.sub.1 can also denote hydrogen;dyeing compositions containing one or more compounds of formula (I), and a process for dyeing human hair.

Abstract translation: 3-取代的对位氨基苯酚，其通式如下：其中X = H，卤素; Y = O-，-S-; R =烷基，羟基烷基，C 1-4氨基烷基或C 3 -C 6多羟基烷基; 条件是当X = H时，R不是甲基，当X = H且Y = O时，R不是乙基; 制备它们的方法，式中的中间体化合物：其中X1 =卤素，Y和R具有上述含义; 条件是当Y = O时，R不是甲基，当R =氨基烷基时，X1也可以表示氢; 含有一种或多种式（I）化合物的染色组合物和染发人发的方法。

公开(公告)号：US4749379A

公开(公告)日：1988-06-07

申请号：US850692

申请日：1986-04-11

Applicant: Alex Junino ,  Gerard Lang ,  Alain Genet

Inventor： Alex Junino ,  Gerard Lang ,  Alain Genet

IPC: A61K8/00 ,  A61K8/34 ,  A61K8/35 ,  A61K8/40 ,  A61K8/41 ,  A61K8/49 ,  A61Q5/06 ,  A61Q5/10 ,  C07D317/66 ,  C09B51/00 ,  D06P3/04 ,  A61K7/13 ,  C07C87/60

CPC classification number: A61K8/418 ,  A61K8/4973 ,  A61Q5/065 ,  C07D317/66 ,  C09B51/00

Abstract: New nitroaminophenols, the process for preparation thereof and their use in dyeing keratinous fibres, and new intermediate nitroaminobenzenes and their use in dyeing keratinous fibres.The invention relates to a nitroaminophenol of formula: ##STR1## in which Z denotes --CH.sub.2 W, W denoting H, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl, C.sub.2 -C.sub.6 polyhydroxyalkyl, (C.sub.1 -C.sub.3), alkoxy(C.sub.1 -C.sub.6)alkyl or (C.sub.1 -C.sub.3)hydroxyalkoxy(C.sub.1 -C.sub.6)-alkyl and R denotes H, (C.sub.1 -C.sub.6)alkyl, C.sub.1 -C.sub.6 hy-droxyalkyl, C.sub.2 -C.sub.6 polyhydroxyalkyl or (C.sub.1 -C.sub.3)-alkoxy(C.sub.1 -C.sub.6)alkyl, and the process for preparation thereof, and the intermediate compound of formula: ##STR2## in which R' denotes C.sub.1 -C.sub.6 hydroxyalkyl, C.sup.2 -C.sub.6 polyhydroxyalkyl or (C.sub.1 -C.sub.3)alkoxy(C.sub.1 -C.sub.6)alkyl and the process for preparation thereof.The dyes of formulae (I) and (II') can be used in direct dyeing of keratinous fibres, in particular, human hair.

Abstract translation: 新的硝基氨基酚，其制备方法及其在染色角质纤维中的用途，以及新的中间硝基氨基苯及其在染色角质纤维中的用途。 本发明涉及下式的硝基氨基苯酚：其中Z表示-CH2W，W表示H，C1-C6烷基，C1-C6羟烷基，C2-C6多羟基烷基，（C1-C3），烷氧基（C1 -C 1-6）烷基或（C 1 -C 3）羟基烷氧基（C 1 -C 6） - 烷基，R表示H，（C 1 -C 6）烷基，C 1 -C 6羟基烷基，C 2 -C 6多羟基烷基或（C 1 -C 3） - 烷氧基 （C 1 -C 6）烷基及其制备方法，以及下式的中间体化合物：其中R'表示C 1 -C 6羟基烷基，C 2 -C 6多羟基烷基或（C 1 -C 3）烷氧基（C 1 -C 6） -C 6）烷基及其制备方法。 式（I）和（II'）的染料可用于角质纤维，特别是人类头发的直接染色。