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公开(公告)号：US20130131293A1
公开(公告)日：2013-05-23
申请号：US13813888
申请日：2011-08-04
申请人： Alessandro Mignogna , Davide Balbone , Antonio Cristofor , Simona Guidotti , Giampiero Morini , Jochem T.M. Pater
发明人： Alessandro Mignogna , Davide Balbone , Antonio Cristofor , Simona Guidotti , Giampiero Morini , Jochem T.M. Pater
IPC分类号： C08F4/649
CPC分类号： C08F10/06 , C08F110/06 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6545
摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of Formula (I) in which R, R1 and R4 groups, equal to or different from each other, are C1-C15 hydrocarbon groups and the R groups can be linked to form a cycle, R2-R3 groups, equal to or different from each other, are selected from hydrogen and C1-C15 hydrocarbon groups, the R1-R4 groups can optionally contain an heteroatom selected from halogen, P, S, N, O and Si, n is an integer from 0 to 5 and said electron donor and Ti atoms being present in an amount such that their molar ratio is equal to, or lower than, 0.65.
摘要翻译： 包含Mg，Ti和其中R，R 1和R 4基团彼此相同或不同的R，R 1和R 4基团的式（I）的电子给体的烯烃聚合用催化剂组分是C1-C15烃基，R基团可以连接 为了形成一个循环，相同或不同的R2-R3基团选自氢和C1-C15烃基，R1-R4基团可任选地含有选自卤素，P，S，N，O的杂原子 和Si，n为0至5的整数，并且所述电子给体和Ti原子的存在量使得它们的摩尔比等于或低于0.65。
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公开(公告)号：US20140046010A1
公开(公告)日：2014-02-13
申请号：US14111144
申请日：2012-03-29
申请人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T.M. Pater , Fabrizio Piemontesi , Diego Brita
发明人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T.M. Pater , Fabrizio Piemontesi , Diego Brita
IPC分类号： C08F4/16
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
摘要翻译： 一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于 事实上，ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或 等于0.60。
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公开(公告)号：US20140142262A1
公开(公告)日：2014-05-22
申请号：US14125502
申请日：2012-06-15
申请人： Alessandro Mignogna , Davide Balboni , Antonio Cristofori , Simona Guidotti , Giampiero Morini , Joachim T.M Peter
发明人： Alessandro Mignogna , Davide Balboni , Antonio Cristofori , Simona Guidotti , Giampiero Morini , Joachim T.M Peter
CPC分类号： C08F4/50 , C08F4/16 , C08F10/00 , C08F110/06 , C08F4/651 , C08F2500/12 , C08F4/6541
摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R1 to R4 groups, equal to or different from each other, are hydrogen, C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, R6 group is selected from C1-C15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si, and R5 is selected from phenyl groups mono or poly substituted with halogens, said groups R1-R4 being also optionally linked to form a saturated or unsaturated mono or poly cycle.
摘要翻译： 包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合的催化剂组分，其中相同或不同的R 1至R 4基团为氢，任选地含有 选自卤素，P，S，N和Si的杂原子，R6基团选自任选含有选自卤素，P，S，N和Si的杂原子的C 1 -C 15烃基，R 5选自苯基单取代或多取代 通过卤素，所述基团R 1 -R 4也任选连接形成饱和或不饱和的单或多环。
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公开(公告)号：US20130217844A1
公开(公告)日：2013-08-22
申请号：US13878712
申请日：2011-10-17
IPC分类号： C08F4/646
CPC分类号： C08F4/646 , C08F10/06 , C08F110/06 , C08F4/651 , C08F4/6543 , C08F2500/12
摘要： A process for the (co)polymerization of propylene carried out at a temperature ranging from 77 to 95° C. in the presence of a catalyst comprising the product obtained by reacting: —an organo-aluminium compound, with—-a solid catalyst component comprising Mg, Ti and electron donor compound selected from specific diolesters.
摘要翻译： 在丙烯存在下，在77至95℃的温度下进行丙烯（共）聚合的方法，该催化剂包括通过以下步骤获得的产物： - 有机铝化合物与 - 固体催化剂组分 包括选自特定二极体的Mg，Ti和电子给体化合物。
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公开(公告)号：US09593171B2
公开(公告)日：2017-03-14
申请号：US14111144
申请日：2012-03-29
申请人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T. M. Pater , Fabrizio Piemontesi , Diego Brita
发明人： Simona Guidotti , Giampiero Morini , Simona Esposito , Alessandro Mignogna , Joachim T. M. Pater , Fabrizio Piemontesi , Diego Brita
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor to the succinate donor is higher than, or equal to, 0.60.
摘要翻译： 一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于 事实上，ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或 等于0.60。
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公开(公告)号：US09034783B2
公开(公告)日：2015-05-19
申请号：US14125502
申请日：2012-06-15
申请人： Alessandro Mignogna , Davide Balboni , Antonio Cristofori , Simona Guidotti , Giampiero Morini , Joachim T. M. Pater
发明人： Alessandro Mignogna , Davide Balboni , Antonio Cristofori , Simona Guidotti , Giampiero Morini , Joachim T. M. Pater
IPC分类号： B01J37/00 , C08F4/02 , C08F4/60 , B01J27/06 , C08F4/44 , C08F2/00 , C08F4/50 , C08F10/00 , C08F4/16 , C08F110/06
CPC分类号： C08F4/50 , C08F4/16 , C08F10/00 , C08F110/06 , C08F4/651 , C08F2500/12 , C08F4/6541
摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R1 to R4 groups, equal to or different from each other, are hydrogen, C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, R6 group is selected from C1-C15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si, and R5 is selected from phenyl groups mono or poly substituted with halogens, said groups R1-R4 being also optionally linked to form a saturated or unsaturated mono or poly cycle.
摘要翻译： 包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合的催化剂组分，其中相同或不同的R 1至R 4基团为氢，任选地含有 选自卤素，P，S，N和Si的杂原子，R6基团选自任选含有选自卤素，P，S，N和Si的杂原子的C 1 -C 15烃基，R 5选自苯基单取代或多取代 通过卤素，所述基团R 1 -R 4也任选连接形成饱和或不饱和的单或多环。
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公开(公告)号：US08921253B2
公开(公告)日：2014-12-30
申请号：US14352251
申请日：2012-10-10
CPC分类号： C08F4/52 , C08F110/06 , C08F2500/12 , C08F4/651 , C08F4/6545
摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R to R4 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which may be linked to form a saturated or unsaturated mono or polycycle and R5 groups are selected from C1-C15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si.
摘要翻译： 用于包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合的催化剂组分其中R至R 4基团彼此相同或不同的是氢，卤素或C 1 -C 15烃基，任选地 含有选自卤素，P，S，N和Si的杂原子，其可以连接形成饱和或不饱和的单环或多环和R 5基团，其选自任选地含有选自卤素，P，S的杂原子的C 1 -C 15烃基 ，N和Si。
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公开(公告)号：US20130197173A1
公开(公告)日：2013-08-01
申请号：US13879333
申请日：2011-10-17
IPC分类号： C08F4/16
CPC分类号： C08F4/16 , C08F10/06 , C08F110/06 , C08F4/6543 , C08F4/6494 , C08F4/651 , C08F2/14 , C08F2500/03 , C08F2500/12
摘要： A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from diolesters of a specific formula (b) an alkylaluminum cocatalyst and (c) an ester of formula R′OOC—(CR″2)m—COOR′ in which m is an integer from 2 to 8, the R′ groups, equal to or different from each other, are C1-C10 alkyl groups and the R″ groups, independently, are hydrogen or C1-C15 hydrocarbon groups.
摘要翻译： 一种催化剂体系，其包括通过使（a）含有Mg，Ti，卤素和至少一种选自特定式（b）的二极体的电子给体化合物的（a）固体催化剂组分与烷基铝助催化剂和（c）式 R'OOC-（CR''2）m-COOR'，其中m为2至8的整数，R'基彼此相同或不同，为C 1 -C 10烷基和R“基团 独立地是氢或C 1 -C 15烃基。
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公开(公告)号：US20130203948A1
公开(公告)日：2013-08-08
申请号：US13879998
申请日：2011-10-17
IPC分类号： C08F10/06
CPC分类号： C08F10/06 , C08F4/651 , C08F4/6543
摘要： A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by reacting:—an organo-aluminium compound, with—a solid catalyst component comprising Mg, Ti and electron donor compound selected from specific diolesters, said process being carried out employing an organo-aluminum/propylene ratio equal to or lower than 1.75 mmole/kg.
摘要翻译： 一种制备高纯度丙烯聚合物的方法，该催化剂包括通过以下步骤获得的产物： - 有机铝化合物与包含Mg，Ti的固体催化剂组分和选自特定二极体的电子给体化合物 所述方法使用等于或低于1.75mmol / kg的有机铝/丙烯比进行。
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公开(公告)号：US20130102744A1
公开(公告)日：2013-04-25
申请号：US13806641
申请日：2011-06-06
申请人： Masaki Fushimi , Simona Guidotti , Marc Oliver Kristen , Alessandro Mignogna , Giampiero Morini , Joachim T.M. Pater
发明人： Masaki Fushimi , Simona Guidotti , Marc Oliver Kristen , Alessandro Mignogna , Giampiero Morini , Joachim T.M. Pater
IPC分类号： C08F4/649
CPC分类号： C08F4/6494 , C08F10/06 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F4/651
摘要： A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from 1,3-diethers; (b) an alkylaluminum cocatalyst; and (c) an ester of formula ROOC—(CH2)n—COOR in which n is an integer from 2 to 8, R groups, equal to or different from each other, are C1-C10 alkyl groups.
摘要翻译： 一种催化剂体系，其包含通过使（a）含有Mg，Ti，卤素和至少一种选自1,3-二醚的电子给体化合物的固体催化剂组分接触获得的产物; （b）烷基铝助催化剂; 和（c）式为ROOC-（CH 2）n -COOR的酯，其中n为2至8的整数，R基彼此相同或不同，为C 1 -C 10烷基。
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