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公开(公告)号：US20120316347A1
公开(公告)日：2012-12-13
申请号：US13505977
申请日：2010-11-05
CPC分类号： C08G61/02 , B01J31/066 , B01J31/1625 , B01J31/1683 , B01J31/1875 , B01J31/24 , B01J31/2409 , B01J2231/641 , B01J2231/70 , B01J2531/0211 , B01J2531/0288 , B01J2531/18 , B01J2540/10 , B01J2540/66 , C08G2261/226 , C08G2261/3424
摘要： The invention provides complexes in which ligands (e.g., calixarene-related compounds) are coordinated to a metal colloid, e.g. a gold colloid. In exemplary embodiments, two or more ligands complexed to the metal colloid are larger than the metal colloid, thus providing an accessible metal center. The complexes can be immobilized on a substrate. The complexes of the invention are useful as tunable and highly robust isolated metal colloids that find use in binding of molecules and catalysis of chemical reactions.
摘要翻译： 本发明提供配体（例如杯芳烃相关化合物）与金属胶体配位的配合物，例如。 金胶体。 在示例性实施方案中，与金属胶体络合的两个或更多个配体大于金属胶体，从而提供可接近的金属中心。 络合物可以固定在基底上。 本发明的配合物可用作可调和高度坚固的分离金属胶体，其用于结合分子和催化化学反应。
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公开(公告)号：US09441072B2
公开(公告)日：2016-09-13
申请号：US13505977
申请日：2010-11-05
CPC分类号： C08G61/02 , B01J31/066 , B01J31/1625 , B01J31/1683 , B01J31/1875 , B01J31/24 , B01J31/2409 , B01J2231/641 , B01J2231/70 , B01J2531/0211 , B01J2531/0288 , B01J2531/18 , B01J2540/10 , B01J2540/66 , C08G2261/226 , C08G2261/3424
摘要： The invention provides complexes in which ligands (e.g., calixarene-related compounds) are coordinated to a metal colloid, e.g. a gold colloid. In exemplary embodiments, two or more ligands complexed to the metal colloid are larger than the metal colloid, thus providing an accessible metal center. The complexes can be immobilized on a substrate. The complexes of the invention are useful as tunable and highly robust isolated metal colloids that find use in binding of molecules and catalysis of chemical reactions.
摘要翻译： 本发明提供配体（例如杯芳烃相关化合物）与金属胶体配位的配合物，例如。 金胶体。 在示例性实施方案中，与金属胶体络合的两个或更多个配体大于金属胶体，从而提供可接近的金属中心。 络合物可以固定在基底上。 本发明的配合物可用作可调和高度坚固的分离金属胶体，其用于结合分子和催化化学反应。
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公开(公告)号：US20130018199A1
公开(公告)日：2013-01-17
申请号：US13502590
申请日：2010-10-22
申请人： Alexander Katz , Namal De Silva , Andrew Solovyov , Alexander Kuperman , Cong-Yan Chen , Partha Nandi , Alexander Okrut , Igor Busygin
发明人： Alexander Katz , Namal De Silva , Andrew Solovyov , Alexander Kuperman , Cong-Yan Chen , Partha Nandi , Alexander Okrut , Igor Busygin
CPC分类号： B01J31/24 , B01J23/46 , B01J23/468 , B01J31/066 , B01J31/16 , B01J31/20 , B01J31/2273 , B01J31/2404 , B01J31/2447 , B01J31/2457 , B01J35/0013 , B01J37/086 , B01J2231/641 , B01J2231/645 , B01J2231/70 , B01J2531/0211 , B01J2531/827 , B01J2540/10 , B01J2540/50 , C07C5/03 , C07C2531/24 , C07F15/0033
摘要： The invention provides complexes in which a calixarene-related compound is coordinated to an iridium-containing metal colloid. The complexes can be immobilized on a substrate. The complexes of the invention are useful as tunable and highly robust isolated metal colloids that find use in binding of molecules and catalysis of chemical reactions.
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公开(公告)号：US08969607B2
公开(公告)日：2015-03-03
申请号：US13502590
申请日：2010-10-22
申请人： Alexander Katz , Namal De Silva , Andrew Solovyov , Alexander Kuperman , Cong-Yan Chen , Partha Nandi , Alexander Okrut , Igor Busygin
发明人： Alexander Katz , Namal De Silva , Andrew Solovyov , Alexander Kuperman , Cong-Yan Chen , Partha Nandi , Alexander Okrut , Igor Busygin
CPC分类号： B01J31/24 , B01J23/46 , B01J23/468 , B01J31/066 , B01J31/16 , B01J31/20 , B01J31/2273 , B01J31/2404 , B01J31/2447 , B01J31/2457 , B01J35/0013 , B01J37/086 , B01J2231/641 , B01J2231/645 , B01J2231/70 , B01J2531/0211 , B01J2531/827 , B01J2540/10 , B01J2540/50 , C07C5/03 , C07C2531/24 , C07F15/0033
摘要： The invention provides complexes in which a calixarene-related compound is coordinated to an iridium-containing metal colloid. The complexes can be immobilized on a substrate. The complexes of the invention are useful as tunable and highly robust isolated metal colloids that find use in binding of molecules and catalysis of chemical reactions.
摘要翻译： 本发明提供了一种其中杯芳烃相关化合物与含铱金属胶体配位的配合物。 络合物可以固定在基底上。 本发明的配合物可用作可调和高度坚固的分离金属胶体，其用于结合分子和催化化学反应。
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公开(公告)号：US08808655B2
公开(公告)日：2014-08-19
申请号：US12030200
申请日：2008-02-12
申请人： Andrew Solovyov , Alexander Katz , Enrique Iglesia
发明人： Andrew Solovyov , Alexander Katz , Enrique Iglesia
CPC分类号： B01D53/565 , B01D53/8628 , B01D2253/202
摘要： Immobilized nitronyl nitroxide active sites on the surface of a porous inorganic oxide support act as efficient and rapid oxidants for NO, reacting with >99% of the NO under flow conditions through a packed bed; and, in a parallel configuration with nitroxyl radical active sites, act to remove >99% of both NO and NO2 from a gas mixture, with >95% of the active sites participating in NOx trapping.
摘要翻译： 在多孔无机氧化物载体表面上固定的硝基氮氧化物活性位置作为NO的有效和快速氧化剂，在流动条件下通过填充床与> 99％的NO反应; 并且与硝酰自由基活性位点并联配置，可以从气体混合物中除去> 99％的NO和NO2，其中95％的活性位点参与NOx捕获。
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公开(公告)号：US08703083B2
公开(公告)日：2014-04-22
申请号：US12510861
申请日：2009-07-28
CPC分类号： B01D53/565 , B01D53/8628 , B01D2253/202
摘要： Immobilized nitronyl nitroxide active sites on the surface of a porous inorganic oxide support act as efficient and rapid oxidants for NO, reacting with >99% of the NO under flow conditions through a packed bed; and, in a parallel configuration with nitroxyl radical active sites, act to remove >99 % of both NO and NO2 from a gas mixture, with >95% of the active sites participating in NOx trapping.
摘要翻译： 在多孔无机氧化物载体表面上固定的硝基氮氧化物活性位置作为NO的有效和快速氧化剂，在流动条件下通过填充床与> 99％的NO反应; 并且与硝酰自由基活性位点并联配置，可以从气体混合物中除去> 99％的NO和NO2，其中95％的活性位点参与NOx捕获。
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公开(公告)号：US20090028768A1
公开(公告)日：2009-01-29
申请号：US12030200
申请日：2008-02-12
申请人： Andrew Solovyov , Alexander Katz , Enrique Iglesia
发明人： Andrew Solovyov , Alexander Katz , Enrique Iglesia
IPC分类号： B01D53/56
CPC分类号： B01D53/565 , B01D53/8628 , B01D2253/202
摘要： Immobilized nitronyl nitroxide active sites on the surface of a porous inorganic oxide support act as efficient and rapid oxidants for NO, reacting with >99% of the NO under flow conditions through a packed bed; and, in a parallel configuration with nitroxyl radical active sites, act to remove >99% of both NO and NO2 from a gas mixture, with >95% of the active sites participating in NOx trapping.
摘要翻译： 在多孔无机氧化物载体表面上固定的硝基氮氧化物活性位置作为NO的有效和快速氧化剂，在流动条件下通过填充床与> 99％的NO反应; 并且与硝酰自由基活性位点并联配置，可以从气体混合物中除去> 99％的NO和NO2，其中95％的活性位点参与NOx捕获。
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