公开(公告)号：US09441072B2

公开(公告)日：2016-09-13

申请号：US13505977

申请日：2010-11-05

申请人： Alexander Katz ,  Namal De Silva ,  Andrew Solovyov ,  Jeong-Myeong Ha

发明人： Alexander Katz ,  Namal De Silva ,  Andrew Solovyov ,  Jeong-Myeong Ha

IPC分类号： C08G61/02 ,  B01J31/24 ,  B01J31/06 ,  B01J31/16 ,  B01J31/18

CPC分类号： C08G61/02 ,  B01J31/066 ,  B01J31/1625 ,  B01J31/1683 ,  B01J31/1875 ,  B01J31/24 ,  B01J31/2409 ,  B01J2231/641 ,  B01J2231/70 ,  B01J2531/0211 ,  B01J2531/0288 ,  B01J2531/18 ,  B01J2540/10 ,  B01J2540/66 ,  C08G2261/226 ,  C08G2261/3424

摘要： The invention provides complexes in which ligands (e.g., calixarene-related compounds) are coordinated to a metal colloid, e.g. a gold colloid. In exemplary embodiments, two or more ligands complexed to the metal colloid are larger than the metal colloid, thus providing an accessible metal center. The complexes can be immobilized on a substrate. The complexes of the invention are useful as tunable and highly robust isolated metal colloids that find use in binding of molecules and catalysis of chemical reactions.

摘要翻译： 本发明提供配体（例如杯芳烃相关化合物）与金属胶体配位的配合物，例如。 金胶体。 在示例性实施方案中，与金属胶体络合的两个或更多个配体大于金属胶体，从而提供可接近的金属中心。 络合物可以固定在基底上。 本发明的配合物可用作可调和高度坚固的分离金属胶体，其用于结合分子和催化化学反应。

公开(公告)号：US20050202507A1

公开(公告)日：2005-09-15

申请号：US10914048

申请日：2004-08-06

申请人： Clark R. Landis ,  Wiechang Jin ,  Jonathan S. Owen ,  Thomas P. Clark ,  Ryan C. Nelson

发明人： Clark R. Landis ,  Wiechang Jin ,  Jonathan S. Owen ,  Thomas P. Clark ,  Ryan C. Nelson

IPC分类号： C07F20060101 ,  C07F1/08 ,  C07F9/02 ,  C07F9/94

CPC分类号： C07F9/6584 ,  B01J31/1658 ,  B01J31/2295 ,  B01J31/2466 ,  B01J31/2476 ,  B01J2231/321 ,  B01J2231/4261 ,  B01J2231/44 ,  B01J2231/645 ,  B01J2531/0205 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/828 ,  B01J2540/10 ,  B01J2540/442 ,  B01J2540/66 ,  C07F15/0066 ,  C07F15/008 ,  C07F15/0093

摘要： Diazaphosphacycles comprising compounds having the formula XI and salts of the compound are provided, wherein the variables W, T, R1, R14, and R15 are as described herein. Transition metal catalysts incorporating such diazaphosphacycles and methods of use thereof are also disclosed. There are further provided compositions comprising diazaphosphacycles covalently attached to a solid support and methods of use thereof.

摘要翻译： 提供了包含具有式XI的化合物和该化合物的盐的二亚磷杂环，其中变量W，T，R 1，R 14和R 15， SUP>如本文所述。 还公开了掺入这种二氮磷磷环的过渡金属催化剂及其使用方法。 还提供了组合物，其包含共价连接到固体支持物上的重氮磷酸循环及其使用方法。

公开(公告)号：US20190031697A1

公开(公告)日：2019-01-31

申请号：US16151446

申请日：2018-10-04

申请人： KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

发明人： M. Nasiruzzaman SHAIKH ,  Md. Abdul AZIZ ,  Aasif HELAL

IPC分类号： C07F15/02 ,  C07C45/50 ,  B01J35/02 ,  C07C201/12 ,  B01J35/00 ,  B01J31/28 ,  B01J31/22 ,  C07C2/86 ,  C07C41/30 ,  C07F17/02 ,  C07C17/269 ,  C07C47/228 ,  C07C47/24 ,  C07C47/277 ,  C07C15/52 ,  C07C43/215 ,  C07C25/24 ,  C07C205/16 ,  C07C205/44

CPC分类号： C07F15/02 ,  B01J23/745 ,  B01J23/8906 ,  B01J31/1625 ,  B01J31/2295 ,  B01J31/2414 ,  B01J31/28 ,  B01J35/0013 ,  B01J35/0033 ,  B01J37/0203 ,  B01J37/343 ,  B01J2231/321 ,  B01J2231/4261 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/842 ,  B01J2540/66 ,  C07C2/861 ,  C07C17/269 ,  C07C41/30 ,  C07C45/50 ,  C07C45/505 ,  C07C201/12 ,  C07C2531/22 ,  C07C2531/28 ,  C07F17/02 ,  C07C47/228 ,  C07C47/24 ,  C07C47/277 ,  C07C15/52 ,  C07C43/215 ,  C07C25/24 ,  C07C205/16 ,  C07C205/44

摘要： A functionalized magnetic nanoparticle including an organometallic sandwich compound and a magnetic metal oxide. The functionalized magnetic nanoparticle may be reacted with a metal precursor to fol in a catalyst for various C—C bond forming reactions. The catalyst may be recovered with ease by attracting the catalyst with a magnet.

公开(公告)号：US12109558B2

公开(公告)日：2024-10-08

申请号：US16991555

申请日：2020-08-12

申请人： William Marsh Rice University

发明人： Nancy Jean Halas ,  Peter Nordlander ,  Hossein Robatjazi ,  Dayne Francis Swearer ,  Chao Zhang ,  Hangqi Zhao ,  Linan Zhou

IPC分类号： B01J35/39 ,  B01J19/12 ,  B01J21/02 ,  B01J21/04 ,  B01J21/10 ,  B01J23/00 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J23/58 ,  B01J23/72 ,  B01J23/78 ,  B01J23/89 ,  B01J27/04 ,  B01J27/14 ,  B01J27/20 ,  B01J27/22 ,  B01J27/24 ,  B01J31/06 ,  B01J35/00 ,  B01J35/23 ,  B01J35/30 ,  B01J35/33 ,  B01J35/50 ,  B01J35/64 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08 ,  B01J37/34 ,  C01B3/04 ,  C01B3/40 ,  C01B4/00 ,  C01B5/00 ,  C01B21/02 ,  C01B32/40 ,  B01J31/16

CPC分类号： B01J35/39 ,  B01J19/123 ,  B01J19/127 ,  B01J21/02 ,  B01J21/04 ,  B01J21/10 ,  B01J23/002 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J23/58 ,  B01J23/72 ,  B01J23/78 ,  B01J23/8926 ,  B01J23/8946 ,  B01J27/04 ,  B01J27/14 ,  B01J27/20 ,  B01J27/22 ,  B01J27/24 ,  B01J31/06 ,  B01J35/19 ,  B01J35/23 ,  B01J35/30 ,  B01J35/33 ,  B01J35/393 ,  B01J35/397 ,  B01J35/50 ,  B01J35/651 ,  B01J37/0203 ,  B01J37/0225 ,  B01J37/03 ,  B01J37/031 ,  B01J37/035 ,  B01J37/08 ,  B01J37/344 ,  C01B3/047 ,  C01B3/40 ,  C01B4/00 ,  C01B5/00 ,  C01B21/02 ,  C01B32/40 ,  B01J31/1691 ,  B01J2219/00635 ,  B01J2523/00 ,  B01J2540/66 ,  C01B2203/0238 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1241 ,  B01J2523/00 ,  B01J2523/17 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/821

摘要： A multicomponent photocatalyst includes a reactive component optically, electronically, or thermally coupled to a plasmonic material. A method of performing a catalytic reaction includes loading a multicomponent photocatalyst including a reactive component optically, electronically, or thermally coupled to a plasmonic material into a reaction chamber; introducing molecular reactants into the reaction chamber; and illuminating the reaction chamber with a light source.

公开(公告)号：US20160023198A1

公开(公告)日：2016-01-28

申请号：US14775159

申请日：2014-03-11

申请人： RUTGERS, THE STATE UNIVERSITY OF NEW JERSEY

发明人： Xumu Zhang

IPC分类号： B01J31/24 ,  C07C201/12 ,  C07D307/38 ,  C07F17/02

CPC分类号： B01J31/2409 ,  B01J31/2414 ,  B01J2231/643 ,  B01J2231/645 ,  B01J2531/0205 ,  B01J2531/0263 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  B01J2531/26 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/84 ,  B01J2531/842 ,  B01J2540/22 ,  B01J2540/225 ,  B01J2540/66 ,  B01J2540/68 ,  C07B53/00 ,  C07C201/12 ,  C07C209/52 ,  C07C213/02 ,  C07D307/38 ,  C07F17/00 ,  C07F17/02 ,  C07C205/04 ,  C07C205/09 ,  C07C205/32 ,  C07C211/30 ,  C07C211/29 ,  C07C211/27 ,  C07C217/58

摘要： A ligand having the structure or its enantiomer; (I) wherein: each one of Ra, Rb, Rc and Rd is selected from alkyl, cycloalkyl, and aryl; the bridge group is selected from CH2NH; *CH(CH3)NH(C*,R); and the organocatalyst is an organic molecule catalyst covalently bound to the bridge group. Also, a catalyst having the structure or its enantiomer: (II) wherein: each one of Ra, Rb, Rc and Rd is selected from alkyl, cycloalkyl, and aryl; the bridge group is selected from CH2NH; *CH(CH3)NH(C*,R); and *CH(CH3)NH(C*,S); the organocatalyst is an organic molecule catalyst covalently bound to the bridge group; and M is selected from the group consisting of Rh, Pd, Cu, Ru, Ir, Ag, Au, Zn, Ni, Co, and Fe.

摘要翻译： 具有该结构或其对映异构体的配体; （I）其中：Ra，Rb，Rc和Rd中的每一个选自烷基，环烷基和芳基; 桥基选自CH 2 NH; * CH（CH3）NH（C *，R）; 有机催化剂是共价结合桥基的有机分子催化剂。 另外，具有结构或其对映异构体的催化剂：（II）其中：Ra，Rb，Rc和Rd中的每一个选自烷基，环烷基和芳基; 桥基选自CH 2 NH; * CH（CH3）NH（C *，R）; 和* CH（CH 3）NH（C *，S）; 有机催化剂是共价结合桥基的有机分子催化剂; M选自Rh，Pd，Cu，Ru，Ir，Ag，Au，Zn，Ni，Co和Fe组成的组。

公开(公告)号：US11958043B2

公开(公告)日：2024-04-16

申请号：US16612660

申请日：2018-05-11

申请人： William Marsh Rice University

发明人： Nancy Jean Halas ,  Peter Nordlander ,  Hossein Robatjazi ,  Dayne Francis Swearer ,  Chao Zhang ,  Hangqi Zhao ,  Linan Zhou

IPC分类号： B01J35/00 ,  B01J19/12 ,  B01J21/02 ,  B01J21/04 ,  B01J21/10 ,  B01J23/00 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J23/58 ,  B01J23/72 ,  B01J23/78 ,  B01J23/89 ,  B01J27/04 ,  B01J27/14 ,  B01J27/20 ,  B01J27/22 ,  B01J27/24 ,  B01J31/06 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08 ,  B01J37/34 ,  C01B3/04 ,  C01B3/40 ,  C01B4/00 ,  C01B5/00 ,  C01B21/02 ,  C01B32/40 ,  B01J31/16

CPC分类号： B01J35/004 ,  B01J19/123 ,  B01J19/127 ,  B01J21/02 ,  B01J21/04 ,  B01J21/10 ,  B01J23/002 ,  B01J23/38 ,  B01J23/44 ,  B01J23/50 ,  B01J23/52 ,  B01J23/58 ,  B01J23/72 ,  B01J23/78 ,  B01J23/8926 ,  B01J23/8946 ,  B01J27/04 ,  B01J27/14 ,  B01J27/20 ,  B01J27/22 ,  B01J27/24 ,  B01J31/06 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/0033 ,  B01J35/006 ,  B01J35/008 ,  B01J35/026 ,  B01J35/1066 ,  B01J37/0203 ,  B01J37/0225 ,  B01J37/03 ,  B01J37/031 ,  B01J37/035 ,  B01J37/08 ,  B01J37/344 ,  C01B3/047 ,  C01B3/40 ,  C01B4/00 ,  C01B5/00 ,  C01B21/02 ,  C01B32/40 ,  B01J31/1691 ,  B01J2219/00635 ,  B01J2523/00 ,  B01J2540/66 ,  C01B2203/0238 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1241 ,  B01J2523/00 ,  B01J2523/17 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/821

摘要： A method of making a multicomponent photocatalyst, includes inducing precipitation from a pre-cursor solution comprising a pre-cursor of a plasmonic material and a pre-cursor of a reactive component to form co-precipitated particles; collecting the co-precipitated particles; and annealing the co-precipitated particles to form the multicomponent photocatalyst comprising a reactive component optically, thermally, or electronically coupled to a plasmonic material.

公开(公告)号：US11918984B2

公开(公告)日：2024-03-05

申请号：US17276855

申请日：2019-09-19

申请人： President and Fellows of Harvard College

发明人： Theodore Alexander Betley ,  Alexandre Mikhailine ,  Claudia Kleinlein ,  Yuyang Dong ,  Yunjung Baek

IPC分类号： B01J31/18 ,  B01J31/22 ,  C07D207/06 ,  C07D209/04 ,  C07D209/44 ,  C07D209/54 ,  C07D211/70 ,  C07D263/04 ,  C07D401/04 ,  C07D403/04 ,  C07D471/04 ,  C07D471/08 ,  C07D487/08

CPC分类号： B01J31/1815 ,  B01J31/2243 ,  C07D207/06 ,  C07D209/04 ,  C07D209/44 ,  C07D209/54 ,  C07D211/70 ,  C07D263/04 ,  C07D401/04 ,  C07D403/04 ,  C07D471/04 ,  C07D471/08 ,  C07D487/08 ,  B01J2231/4283 ,  B01J2531/0216 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  B01J2540/66

摘要： Disclosed are compounds, methods, reagents, systems, and kits for the preparation and utilization of monomeric or polymeric metal-based compounds. These metal-based compounds are organometallic catalysts composed of substituted dipyrrin ligands bound to transition metals. C—H bond functionalization catalysis can be performed with the disclosed organometallic catalysts to yield C—N bonds to generate substituted bicyclic, spiro, and fused nitrogen-containing heterocycles, all common motifs in various pharmaceutical and bioactive molecules.

公开(公告)号：US09744528B2

公开(公告)日：2017-08-29

申请号：US14775159

申请日：2014-03-11

申请人： Rutgers, The State University Of New Jersey

发明人： Xumu Zhang

IPC分类号： C07C201/12 ,  B01J31/24 ,  C07D307/38 ,  C07F17/02 ,  C07C209/52 ,  C07C213/02 ,  C07B53/00 ,  C07F17/00

CPC分类号： B01J31/2409 ,  B01J31/2414 ,  B01J2231/643 ,  B01J2231/645 ,  B01J2531/0205 ,  B01J2531/0263 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/18 ,  B01J2531/26 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/84 ,  B01J2531/842 ,  B01J2540/22 ,  B01J2540/225 ,  B01J2540/66 ,  B01J2540/68 ,  C07B53/00 ,  C07C201/12 ,  C07C209/52 ,  C07C213/02 ,  C07D307/38 ,  C07F17/00 ,  C07F17/02 ,  C07C205/04 ,  C07C205/09 ,  C07C205/32 ,  C07C211/30 ,  C07C211/29 ,  C07C211/27 ,  C07C217/58

摘要： A ligand having the structure or its enantiomer; (I) wherein: each one of Ra, Rb, Rc and Rd is selected from alkyl, cycloalkyl, and aryl; the bridge group is selected from CH2NH; *CH(CH3)NH(C*,R); and the organocatalyst is an organic molecule catalyst covalently bound to the bridge group. Also, a catalyst having the structure or its enantiomer: (II) wherein: each one of Ra, Rb, Rc and Rd is selected from alkyl, cycloalkyl, and aryl; the bridge group is selected from CH2NH; *CH(CH3)NH(C*,R); and *CH(CH3)NH(C*,S); the organocatalyst is an organic molecule catalyst covalently bound to the bridge group; and M is selected from the group consisting of Rh, Pd, Cu, Ru, Ir, Ag, Au, Zn, Ni, Co, and Fe.

公开(公告)号：US20120316347A1

公开(公告)日：2012-12-13

申请号：US13505977

申请日：2010-11-05

申请人： Alexander Katz ,  Namal De Silva ,  Andrew Solovyov ,  Jeong-Myeong Ha

发明人： Alexander Katz ,  Namal De Silva ,  Andrew Solovyov ,  Jeong-Myeong Ha

IPC分类号： C07F1/12 ,  C22B5/00 ,  C07F19/00 ,  C07B31/00 ,  C07B33/00

CPC分类号： C08G61/02 ,  B01J31/066 ,  B01J31/1625 ,  B01J31/1683 ,  B01J31/1875 ,  B01J31/24 ,  B01J31/2409 ,  B01J2231/641 ,  B01J2231/70 ,  B01J2531/0211 ,  B01J2531/0288 ,  B01J2531/18 ,  B01J2540/10 ,  B01J2540/66 ,  C08G2261/226 ,  C08G2261/3424

摘要： The invention provides complexes in which ligands (e.g., calixarene-related compounds) are coordinated to a metal colloid, e.g. a gold colloid. In exemplary embodiments, two or more ligands complexed to the metal colloid are larger than the metal colloid, thus providing an accessible metal center. The complexes can be immobilized on a substrate. The complexes of the invention are useful as tunable and highly robust isolated metal colloids that find use in binding of molecules and catalysis of chemical reactions.

摘要翻译： 本发明提供配体（例如杯芳烃相关化合物）与金属胶体配位的配合物，例如。 金胶体。 在示例性实施方案中，与金属胶体络合的两个或更多个配体大于金属胶体，从而提供可接近的金属中心。 络合物可以固定在基底上。 本发明的配合物可用作可调和高度坚固的分离金属胶体，其用于结合分子和催化化学反应。

公开(公告)号：US07507820B2

公开(公告)日：2009-03-24

申请号：US10914048

申请日：2004-08-06

申请人： Clark R. Landis ,  Wiechang Jin ,  Jonathan S. Owen ,  Thomas P. Clark ,  Ryan C. Nelson

发明人： Clark R. Landis ,  Wiechang Jin ,  Jonathan S. Owen ,  Thomas P. Clark ,  Ryan C. Nelson

IPC分类号： C07F9/28 ,  C07F9/02

CPC分类号： C07F9/6584 ,  B01J31/1658 ,  B01J31/2295 ,  B01J31/2466 ,  B01J31/2476 ,  B01J2231/321 ,  B01J2231/4261 ,  B01J2231/44 ,  B01J2231/645 ,  B01J2531/0205 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/828 ,  B01J2540/10 ,  B01J2540/442 ,  B01J2540/66 ,  C07F15/0066 ,  C07F15/008 ,  C07F15/0093

摘要： Diazaphosphacycles comprising compounds having the formula XI and salts of the compound are provided, wherein the variables W, T, R1, R14, and R15 are as described herein. Transition metal catalysts incorporating such diazaphosphacycles and methods of use thereof are also disclosed. There are further provided compositions comprising diazaphosphacycles covalently attached to a solid support and methods of use thereof.

摘要翻译： 提供了包含具有式XI的化合物和化合物的盐的二亚磷酰环，其中变量W，T，R 1，R 14和R 15如本文所述。 还公开了掺入这种二氮磷磷环的过渡金属催化剂及其使用方法。 还提供了组合物，其包含共价连接到固体支持物上的重氮磷酸循环及其使用方法。