-
公开(公告)号：US20100188801A1
公开(公告)日：2010-07-29
申请号：US12752735
申请日：2010-04-01
申请人： Alexander Lyubomirskiy , Valeriy Valentinovich Pavlov , Alexander Mikhailovich Timonov , Sergey Anatolijevich Logvinov , Dmitriy Ivanovich Pivunov , Svetlana Viktorovna Vasiljeva , Nik Shkolnik , Sam Kogan
发明人： Alexander Lyubomirskiy , Valeriy Valentinovich Pavlov , Alexander Mikhailovich Timonov , Sergey Anatolijevich Logvinov , Dmitriy Ivanovich Pivunov , Svetlana Viktorovna Vasiljeva , Nik Shkolnik , Sam Kogan
CPC分类号： H01M4/137 , H01G9/0032 , H01G9/0036 , H01G9/04 , H01G11/48 , H01M4/0438 , H01M4/0466 , H01M4/60 , H01M4/66 , H01M4/663 , H01M4/667 , H01M4/668 , Y02E60/13
摘要： A method of preparing an energy-storage device is disclosed, which involves deposition of a redox polymer of the poly-Me(R-Salen) type onto a conducting substrate by electrochemical polymerization to prepare an electrode for use in the energy-storage device. Polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged in an electrolyte. The electrolyte contains an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/L within the range of potentials from −3.0 V to +1.5 V, and a metal complex polymer represented by the formula poly-[Me(R-Salen)] dissolved at a concentration of no less than 5×10−5 mol/L, wherein Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, and Salen is a residue of bis(salicylaldehyde)-ethylenediamine. Deposition of the redox polymer occurs in an electrolyte in which the cations have a diameter that is larger than the diameter of the cations of the electrolyte employed in the energy-storage device for which the electrode is manufactured.
摘要翻译： 公开了一种制备储能装置的方法，其包括通过电化学聚合将poly-Me（R- Salen）型氧化还原聚合物沉积到导电基底上，以制备用于储能装置的电极。 聚合发生在施加在基板和对电极之间的电压上，两者都被浸没在电解液中。 电解质含有有机溶剂，能够溶解在溶剂中的化合物，在-3.0V〜+1.5V的电位范围内，以不低于0.01mol / L的浓度形成电化学惰性离子的化合物，以及由 以不低于5×10 -5 mol / L的浓度溶解的聚[Me（R- Salen）]式，其中Me是具有至少两个不同氧化程度的过渡金属，R是给电子 取代基，Salen是双（水杨醛） - 乙二胺的残基。 氧化还原聚合物的沉积发生在其中阳离子的直径大于制造电极的储能装置中所用电解质的阳离子的直径的电解质中。
-
公开(公告)号：US20050258042A1
公开(公告)日：2005-11-24
申请号：US11100036
申请日：2005-04-06
申请人： Alexander Lyubomirskiy , Valeriy Pavlov , Alexander Timonov , Sergey Logvinov , Dmitriy Pivunov , Svetlana Vasiljeva , Nik Shkolnik , Sam Kogan
发明人： Alexander Lyubomirskiy , Valeriy Pavlov , Alexander Timonov , Sergey Logvinov , Dmitriy Pivunov , Svetlana Vasiljeva , Nik Shkolnik , Sam Kogan
CPC分类号： H01M4/137 , H01G9/0032 , H01G9/0036 , H01G9/04 , H01G11/48 , H01M4/0438 , H01M4/0466 , H01M4/60 , H01M4/66 , H01M4/663 , H01M4/667 , H01M4/668 , Y02E60/13
摘要： Deposition of a redox polymer of the poly-Me(R-Salen) type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte. The electrolyte contains an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/l within the range of potentials from −3.0 V to +1.5 V, and a metal complex poly-[Me(R-Salen)] dissolved at a concentration of no less than 5×10−5 mole/liter. Me is transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis(salicylaldehyde)-ethylenediamine in Schiff' s base). Deposition of the redox occurs in the electrolyte where the cations of the compounds have a diameter larger than that of the electrolyte cations of energy storing device containing the electrode.
摘要翻译： 公开了通过电化学聚合将poly-Me（R- Salen）型氧化还原聚合物沉积到导电基底上。 所述聚合发生在施加在基板和反电极之间的电压，两者都被浸没在电解质中。 电解质含有有机溶剂，能够溶解在溶剂中的化合物和在-3.0V至+1.5V的电位范围内以不低于0.01mol / l的浓度形成电化学惰性离子的化合物，以及金属络合物聚[ Me（R-Salen）]以不低于5×10 -5摩尔/升的浓度溶解。 Me是具有至少两个不同氧化程度的过渡金属，R是给电子取代基，Salen是Schiff碱中的双（水杨醛） - 乙二胺的残基）。 在电解质中发生氧化还原的沉积，其中化合物的阳离子的直径大于含有电极的储能装置的电解质阳离子的直径。
-
搜索结果
2 条记录 (耗时 0.029 秒)
