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    Phenoxyacetate peracid precursors and perhydrolysis systems therewith
    1.
    发明授权
    Phenoxyacetate peracid precursors and perhydrolysis systems therewith 失效
    苯氧乙酸盐过酸前体及其过水解体系

    公开(公告)号：US5049305A

    公开(公告)日：1991-09-17

    申请号：US543344

    申请日：1990-06-25

    申请人： Alfred G. Zielske ,  Ronald A. Fong

    发明人： Alfred G. Zielske ,  Ronald A. Fong

    IPC分类号： C07C69/712 ,  C07C409/24 ,  C07D207/46 ,  C07D209/48 ,  C11D3/39

    CPC分类号： C11D3/3907 ,  C07C309/00 ,  C07D207/46 ,  C07D209/48 ,  C11D3/3935

    摘要： A perhydrolysis system is provided which includes peroxyacid precursors and a source of peroxygen. Upon dissolution in water these compositions provide high yields of a novel peroxyacid having the structure ##STR1## where R is hydrogen or an alkyl of not more than 5 carbon atoms. The precursors may include hydroxyl nitrogen derivatives as leaving groups, since the .alpha.-substituted phenoxy moiety enhances carbonyl reactivity toward perhydroxyl anion.

    摘要翻译： 提供了一种过水解系统，其包括过氧酸前体和过氧源。 当溶解在水中时，这些组合物提供了高产率的具有结构“IMAGE”的新型过氧酸，其中R是氢或不超过5个碳原子的烷基。 前体可以包括作为离去基团的羟基氮衍生物，因为α-取代的苯氧基部分增强了对全羟基阴离子的羰基反应性。

    Polyglycolate peracid precursors
    2.
    发明授权
    Polyglycolate peracid precursors 失效
    聚乙醇酸过酸前体

    公开(公告)号：US5391812A

    公开(公告)日：1995-02-21

    申请号：US951238

    申请日：1992-09-25

    申请人： Richard R. Rowland ,  Ronald A. Fong ,  Richard J. Wiersema ,  Alfred G. Zielske

    发明人： Richard R. Rowland ,  Ronald A. Fong ,  Richard J. Wiersema ,  Alfred G. Zielske

    IPC分类号： C01B15/00 ,  C07C409/24 ,  C11D3/39 ,  C11D7/54 ,  D06L3/02 ,  D06L3/06 ,  C07C69/00

    CPC分类号： C11D3/3907

    摘要： Polyglycolate compounds are provided having the general structure: ##STR1## wherein n is an integer from 2 to about 10; R is C.sub.1-20 linear or branched alkyl, alkoxylated alkyl, cycloalkyl, aryl, alkylaryl, substituted aryl; R' and R" are independently H, C.sub.1-20 alkyl, aryl, C.sub.1-20 alkylaryl, substituted aryl, and NR.sub.3.sup..alpha.+, wherein R.sup..alpha. is C.sub.1-30 alkyl; and L is a leaving group displaceable in a peroxygen bleaching solution by perhydroxide anion. When this compound is combined with a source of peroxygen in aqueous solution, then a plurality of stain removing peracids are formed. Such peracids are formed substantially sequentially beginning with the carbonyl adjacent to the leaving group L. Thus, a first stain removing peracid having the structure ##STR2## will be formed in amounts approaching quantitative yield.

    摘要翻译： 提供了具有以下通用结构的聚乙醇酸酯化合物：其中n为2至约10的整数; R为C 1-20直链或支链烷基，烷氧基化烷基，环烷基，芳基，烷基芳基，取代芳基; R'和R“独立地为H，C 1-20烷基，芳基，C 1-20烷基芳基，取代的芳基和NR 3α+，其中Rα为C 1-30烷基; L是在过氧漂白溶液中通过全氢氧化物阴离子置换的离去基团。 当该化合物与水溶液中的过氧源组合时，形成多个去污过酸。 这样的过酸基本上是从与离去基团L相邻的羰基开始形成的。因此，具有接近定量收率的量的第一种去除污垢的过酸的结构将形成。

    Late peracid precursors
    4.
    发明授权
    Late peracid precursors 失效
    聚乙醇酸过酸前体

    公开(公告)号：US5182045A

    公开(公告)日：1993-01-26

    申请号：US329982

    申请日：1989-03-29

    申请人： Richard R. Rowland ,  Ronald A. Fong ,  Richard J. Wiersema ,  Alfred G. Zielske

    发明人： Richard R. Rowland ,  Ronald A. Fong ,  Richard J. Wiersema ,  Alfred G. Zielske

    IPC分类号： C01B15/00 ,  C07C409/24 ,  C11D3/39 ,  C11D7/54 ,  D06L3/02 ,  D06L3/06

    CPC分类号： C11D3/3907

    摘要： Polyglycolate compounds are provided having the general structure: ##STR1## wherein n is an integer from 2 to about 10; R is C.sub.1-20 linear or branched alkyl, alkoxylated alkyl, cycloalkyl, aryl, alkylaryl, substituted aryl; R' and R" are independently H, C.sub.1-20 alkyl, aryl, C.sub.1-20 alkylaryl, substituted aryl, and NR.sub.3.sup..alpha.+, wherein R.sup..alpha. is C.sub.1-30 alkyl; and L is a leaving group displaceable in a peroxygen bleaching solution by perhydroxide anion. When this compound is combined with a source of peroxygen in aqueous solution, then a plurality of stain removing peracids are formed. Such peracids are formed substantially sequentially beginning with the carbonyl adjacent to the leaving group L. Thus, a first stain removing peracid having the structure ##STR2## will be formed in amounts approaching quantitative yield.

    Polyglycolate peracid precursors
    7.
    发明授权
    Polyglycolate peracid precursors 失效
    聚乙醇酸过酸前体

    公开(公告)号：US5545748A

    公开(公告)日：1996-08-13

    申请号：US325050

    申请日：1994-10-18

    申请人： Richard R. Rowland ,  Ronald A. Fong ,  Richard J. Wiersema ,  Alfred G. Zielske

    发明人： Richard R. Rowland ,  Ronald A. Fong ,  Richard J. Wiersema ,  Alfred G. Zielske

    IPC分类号： C01B15/00 ,  C07C409/24 ,  C11D3/39 ,  C11D7/54 ,  D06L3/02 ,  D06L3/06 ,  C07C409/02 ,  C01B15/10

    CPC分类号： C11D3/3907

    摘要： Polyglycolate compounds are provided having the general structure: ##STR1## wherein n is an integer from 2 to about 10; R is C.sub.1-20 linear or branched alkyl, alkoxylated alkyl, cycloalkyl, aryl, alkylaryl, substituted aryl; R' and R" are independently H, C.sub.1-20 alkyl, aryl, C.sub.1-20 alkylaryl, substituted aryl, and NR.sub.3.sup..alpha.+, wherein R.sup..alpha. is C.sub.1-30 alkyl; and L is a leaving group displaceable in a peroxygen bleaching solution by perhydroxide anion. When this compound is combined with a source of peroxgen in aqueous solution, then a plurality of stain removing peracids are formed. Such peracids are formed substantially sequentially beginning with the carbonyl adjacent to the leaving group L. Thus, a first stain removing peracid having the structure ##STR2## will be formed in amounts approaching quantitative yield.

    摘要翻译： 提供了具有以下通用结构的聚乙醇酸酯化合物：其中n为2至约10的整数; R为C 1-20直链或支链烷基，烷氧基化烷基，环烷基，芳基，烷基芳基，取代芳基; R'和R“独立地为H，C 1-20烷基，芳基，C 1-20烷基芳基，取代的芳基和NR 3α+，其中Rα为C 1-30烷基; L是在过氧漂白溶液中通过全氢氧化物阴离子置换的离去基团。 当该化合物与水溶液中的过氧化物源组合时，形成多个去污过酸。 这样的过酸基本上是从与离去基团L相邻的羰基开始形成的。因此，具有接近定量收率的量的第一个去除污垢的过酸的结构将被形成。

    Diperoxyacid precursors and method
    10.
    发明授权
    Diperoxyacid precursors and method 失效
    二过氧酸前体和方法

    公开(公告)号：US4735740A

    公开(公告)日：1988-04-05

    申请号：US915133

    申请日：1986-10-03

    申请人： Alfred G. Zielske

    发明人： Alfred G. Zielske

    IPC分类号： C11D7/38 ,  C07C67/00 ,  C07C309/42 ,  C07C407/00 ,  C07C409/42 ,  C11D3/39 ,  C11D7/54 ,  D06L3/02 ,  C07C69/017

    CPC分类号： C07C309/00 ,  C11D3/3915

    摘要： Novel sulfonated phenyl esters of dicarboxylic acids are useful as diperoxyacid precursors in bleaching and laundering applications when combined with a source of peroxide. These diperoxyacid precursors can be produced by reacting a dicarboxylic acid, a phenol sulfonate, and a lower alkyl acid anhydride in an alkyl hydrocarbon solvent and removing a carboxylic acid byproduct through distillation. The diperoxyacid precursors have the structure: ##STR1## wherein n is an integer from about 4 to about 18 and M is an alkali metal, an alkaline earth metal, or ammonium. The diperoxyacid precursors have a high perhydrolysis profile coupled with a relatively low-to-moderate hydrolysis profile.