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公开(公告)号：US5391812A
公开(公告)日：1995-02-21
申请号：US951238
申请日：1992-09-25
CPC分类号： C11D3/3907
摘要： Polyglycolate compounds are provided having the general structure: ##STR1## wherein n is an integer from 2 to about 10; R is C.sub.1-20 linear or branched alkyl, alkoxylated alkyl, cycloalkyl, aryl, alkylaryl, substituted aryl; R' and R" are independently H, C.sub.1-20 alkyl, aryl, C.sub.1-20 alkylaryl, substituted aryl, and NR.sub.3.sup..alpha.+, wherein R.sup..alpha. is C.sub.1-30 alkyl; and L is a leaving group displaceable in a peroxygen bleaching solution by perhydroxide anion. When this compound is combined with a source of peroxygen in aqueous solution, then a plurality of stain removing peracids are formed. Such peracids are formed substantially sequentially beginning with the carbonyl adjacent to the leaving group L. Thus, a first stain removing peracid having the structure ##STR2## will be formed in amounts approaching quantitative yield.
摘要翻译： 提供了具有以下通用结构的聚乙醇酸酯化合物：其中n为2至约10的整数; R为C 1-20直链或支链烷基，烷氧基化烷基，环烷基，芳基，烷基芳基，取代芳基; R'和R“独立地为H，C 1-20烷基，芳基，C 1-20烷基芳基，取代的芳基和NR 3α+，其中Rα为C 1-30烷基; L是在过氧漂白溶液中通过全氢氧化物阴离子置换的离去基团。 当该化合物与水溶液中的过氧源组合时，形成多个去污过酸。 这样的过酸基本上是从与离去基团L相邻的羰基开始形成的。因此，具有接近定量收率的量的第一种去除污垢的过酸的结构将形成。
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公开(公告)号：US5235077A
公开(公告)日：1993-08-10
申请号：US674498
申请日：1991-03-25
摘要： An improved process for preparing phenyl esters of alkanoyloxyacetic acids in which phenyl chloroacetate is reacted with the salt of a carboxylic acid.
摘要翻译： 制备烷酰氧基乙酸苯酯的改进方法，其中氯乙酸苯酯与羧酸的盐反应。
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公开(公告)号：US4964870A
公开(公告)日：1990-10-23
申请号：US366192
申请日：1989-06-08
申请人： Ronald A. Fong , Stephen B. Kong
发明人： Ronald A. Fong , Stephen B. Kong
IPC分类号： C07C409/24 , C07C409/26 , C11D3/39
CPC分类号： C11D3/3907
摘要： The invention provides novel peracid precursors representative of which is the structure: ##STR1## wherein R.sup.1 is alkyl of 1 to 20 carbon atoms; R.sup.2 is OH, --O--R.sup.3, or ##STR2## and X.sup.1, X.sup.2, Y and Z are individually selected from H, SO.sub.3.sup.--, CO.sub.2.sup.--, NO.sub.2, NR.sub.4.sup.5+, halogen, R.sup.6 and mixtures thereof;wherein R.sup.3 of --O--R.sup.3 is alkyl of 1 to 20 carbon atoms; R.sup.4 of ##STR3## is alkyl of 1 to 20 carbon atoms; R.sup.5 of NR.sub.4.sup.5+ is selected from H, alkyl of 1 to 24 carbon atoms and mixtures thereof; and R.sup.6 is alkyl of 1 to 20 carbon atoms.In one embodiment of the invention, the novel peracid precursors are combined with a source of hydrogen peroxide and sufficient quantities of buffer to impact an alkaline pH when the composition is placed in aqueous solution. Preferred embodiments of the invention include wherein R.sup.2 is hydroxy, and R.sup.1 is alkyl of 1 to 20 carbon atoms (monoester); and wherein R.sup.2 is ##STR4## and R.sup.1 and R.sup.4 are alkyls of 1 to 20 carbon atoms (diester) and may be either symmetrical (i.e., R.sup.1 =R.sup.4) or mixed (i.e., R.sup.1 .noteq.R.sup.4). The mixed diester embodiment appears to provide benefits of mixed hydrophobic/hydrophilic peracid generation to oxidize both hydrophobic and hydrophilic soils. Various detergent adjuncts known to those skilled in the art may be added, such as surfactants, builders, fragrances, antimicrobial compounds and the like.
摘要翻译： 本发明提供新的过酸前体，其代表的结构是：其中R 1是1至20个碳原子的烷基; R 2是OH，-O-R 3或者X 3，X 1，X 2，Y和Z分别选自H，SO 3 - ，CO 2 - ，NO 2，NR 45 +，卤素，R 6及其混合物; 其中-O-R 3的R 3为1至20个碳原子的烷基;
的R4是1〜20个碳原子的烷基; NR45 +的R5选自H，1至24个碳原子的烷基及其混合物; R6为1〜20个碳原子的烷基。 在本发明的一个实施方案中，当将组合物置于水溶液中时，新型过酸前体与过氧化氢源和足够量的缓冲液组合以冲击碱性pH。 本发明的优选实施方案包括其中R 2为羟基，R 1为1至20个碳原子的烷基（单酯）; 并且其中R 2是R 1和R 4是具有1至20个碳原子的烷基（二酯），并且可以是对称的（即R1 = R4）或混合的（即，R 1等式R 4）。 混合二酯实施方案似乎提供混合的疏水/亲水过酸产生的优点，以氧化疏水性和亲水性的土壤。 可以加入本领域技术人员已知的各种洗涤助剂，例如表面活性剂，助洗剂，香料，抗微生物化合物等。 -
公开(公告)号：US4041006A
公开(公告)日：1977-08-09
申请号：US626897
申请日：1975-10-29
CPC分类号： C08F8/32 , C02F1/5227 , C02F1/54 , C08F8/44 , Y10S524/922
摘要： Oil-dispersed poly(vinylimidazoline) and poly(2-vinylimidazolinium) bisulfate flocculant compositions and process for in situ preparation of same.
摘要翻译： 油分散聚（乙烯基咪唑啉）和聚（2-乙烯基咪唑鎓）硫酸氢盐絮凝剂组合物及其制备方法。
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公开(公告)号：US5049305A
公开(公告)日：1991-09-17
申请号：US543344
申请日：1990-06-25
申请人： Alfred G. Zielske , Ronald A. Fong
发明人： Alfred G. Zielske , Ronald A. Fong
IPC分类号： C07C69/712 , C07C409/24 , C07D207/46 , C07D209/48 , C11D3/39
CPC分类号： C11D3/3907 , C07C309/00 , C07D207/46 , C07D209/48 , C11D3/3935
摘要： A perhydrolysis system is provided which includes peroxyacid precursors and a source of peroxygen. Upon dissolution in water these compositions provide high yields of a novel peroxyacid having the structure ##STR1## where R is hydrogen or an alkyl of not more than 5 carbon atoms. The precursors may include hydroxyl nitrogen derivatives as leaving groups, since the .alpha.-substituted phenoxy moiety enhances carbonyl reactivity toward perhydroxyl anion.
摘要翻译： 提供了一种过水解系统，其包括过氧酸前体和过氧源。 当溶解在水中时，这些组合物提供了高产率的具有结构“IMAGE”的新型过氧酸，其中R是氢或不超过5个碳原子的烷基。 前体可以包括作为离去基团的羟基氮衍生物，因为α-取代的苯氧基部分增强了对全羟基阴离子的羰基反应性。
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6.发明授权Antimicrobial hard surface cleaner comprising an ethoxylated quaternary ammonium surfactant 有权包含乙氧基化季铵表面活性剂的抗微生物硬表面清洁剂公开(公告)号：US06605584B2
公开(公告)日：2003-08-12
申请号：US09849660
申请日：2001-05-04
申请人： Ronald A. Fong , Stephen B. Kong , David Peterson
发明人： Ronald A. Fong , Stephen B. Kong , David Peterson
IPC分类号： C11D1835
摘要： The invention provides a, non- or minimized streaking/filming antimicrobial formulation, the cleaner containing: a. an akoxylated quaternary ammonium surfactant, present in a cleaning-effective amount; b. an alkoxylated short chain nonionic surfactant, also present in a cleaning-effective amount; c. alkanolamine as an alkalinity source, present in an amount effective to enhance soil removal in said cleaner; d. a quaternary ammonium compound in an amount present for antimicrobial efficacy; e. at least one water-soluble or dispersible organic solvent having a vapor pressure of at least 0.001 mm Hg at 25° C., said at least one organic solvent present in a solubilizing—or dispersion—effective amount; and f. the remainder, water.
摘要翻译： 本发明提供一种非或最小条纹/成膜抗微生物制剂，该清洁剂包含：a。 以清洁有效量存在的烷氧基化季铵表面活性剂; b。 也是存在于清洁有效量的烷氧基化短链非离子表面活性剂; c。 链烷醇胺作为碱度来源，以有效增强所述清洁剂中去除污垢的量存在; d。 以抗菌功效存在的季铵化合物; e。 至少一种在25℃下蒸气压至少为0.001mm Hg的水溶性或分散性有机溶剂，所述至少一种有机溶剂以增溶或分散有效量存在; 和。 剩下的，水。
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公开(公告)号：US5545748A
公开(公告)日：1996-08-13
申请号：US325050
申请日：1994-10-18
IPC分类号： C01B15/00 , C07C409/24 , C11D3/39 , C11D7/54 , D06L3/02 , D06L3/06 , C07C409/02 , C01B15/10
CPC分类号： C11D3/3907
摘要： Polyglycolate compounds are provided having the general structure: ##STR1## wherein n is an integer from 2 to about 10; R is C.sub.1-20 linear or branched alkyl, alkoxylated alkyl, cycloalkyl, aryl, alkylaryl, substituted aryl; R' and R" are independently H, C.sub.1-20 alkyl, aryl, C.sub.1-20 alkylaryl, substituted aryl, and NR.sub.3.sup..alpha.+, wherein R.sup..alpha. is C.sub.1-30 alkyl; and L is a leaving group displaceable in a peroxygen bleaching solution by perhydroxide anion. When this compound is combined with a source of peroxgen in aqueous solution, then a plurality of stain removing peracids are formed. Such peracids are formed substantially sequentially beginning with the carbonyl adjacent to the leaving group L. Thus, a first stain removing peracid having the structure ##STR2## will be formed in amounts approaching quantitative yield.
摘要翻译： 提供了具有以下通用结构的聚乙醇酸酯化合物：其中n为2至约10的整数; R为C 1-20直链或支链烷基，烷氧基化烷基，环烷基，芳基，烷基芳基，取代芳基; R'和R“独立地为H，C 1-20烷基，芳基，C 1-20烷基芳基，取代的芳基和NR 3α+，其中Rα为C 1-30烷基; L是在过氧漂白溶液中通过全氢氧化物阴离子置换的离去基团。 当该化合物与水溶液中的过氧化物源组合时，形成多个去污过酸。 这样的过酸基本上是从与离去基团L相邻的羰基开始形成的。因此，具有接近定量收率的量的第一个去除污垢的过酸的结构将被形成。
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公开(公告)号：US4613332A
公开(公告)日：1986-09-23
申请号：US629695
申请日：1984-07-11
申请人： Victor M. Casella , Ronald A. Fong
发明人： Victor M. Casella , Ronald A. Fong
CPC分类号： C11D3/395 , C11D3/3951
摘要： A dry bleaching composition, particularly useful for low temperature applications, is provided in which generation of hypochlorite by reaction between a peroxygen bleaching agent and a chloride salt is promoted by an aromatic diol or oxidized aromatic diol activator. Preferred activators are in ester form and provide hypochlorite generation at levels of less than about 20 ppm for at least about the first two minutes following dissolution of the compositions in aqueous solution, but rising to effective bleaching levels within a reasonable time thereafter. The initially low hypochlorite level assists in the functioning of laundry additives, such as fabric brighteners.
摘要翻译： 提供特别适用于低温应用的干燥漂白组合物，其中通过芳族二醇或氧化的芳族二醇活化剂促进过氧漂白剂和氯化物盐之间的反应产生次氯酸盐。 优选的活化剂为酯形式，并且在组合物在水溶液中溶解后至少约前后两分钟时间内产生低于约20ppm的次氯酸盐，然后在合适的时间内升高至有效的漂白水平。 最初的低次氯酸盐水平有助于洗衣添加剂的功能，例如织物增白剂。
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公开(公告)号：US4859800A
公开(公告)日：1989-08-22
申请号：US45197
申请日：1987-04-30
申请人： Alfred G. Zielske , Ronald A. Fong
发明人： Alfred G. Zielske , Ronald A. Fong
IPC分类号： C07D213/89 , C07C67/00 , C07C69/712 , C07C239/00 , C07C251/62 , C07C251/66 , C07C301/00 , C07C305/24 , C07C309/42 , C07C407/00 , C07C409/24 , C07D207/46 , C07D209/48 , C11D3/39 , C11D7/38 , C11D7/54
CPC分类号： C11D3/3907 , C07C309/00 , C07C409/24 , C07D207/46 , C07D209/48 , C11D3/3935
摘要： A perhydrolysis system is provided which includes peroxyacid precursors and a source of peroxygen. Upon dissolution in water these compositions provide high yields of a novel peroxyacid having the structure ##STR1## where R is hydrogen or an alkyl of not more than 5 carbon atoms. The precursor may include hydroxyl nitrogen derivatives as leaving groups, since the .alpha.-substituted phenoxy moiety enhances carbonyl reactivity toward perhydroxyl anion.
摘要翻译： 提供了一种过水解系统，其包括过氧酸前体和过氧源。 当溶解在水中时，这些组合物提供了高产率的具有结构“IMAGE”的新型过氧酸，其中R是氢或不超过5个碳原子的烷基。 前体可以包括作为离去基团的羟基氮衍生物，因为α-取代的苯氧基部分增强了对全羟基阴离子的羰基反应性。
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公开(公告)号：US4814110A
公开(公告)日：1989-03-21
申请号：US883626
申请日：1986-07-09
申请人： Ronald A. Fong , Richard R. Rowland
发明人： Ronald A. Fong , Richard R. Rowland
IPC分类号： C07C67/08 , C07C409/24 , C07C409/26 , C11D3/39
CPC分类号： C07C67/08 , C07C67/28 , C07C67/29 , C11D3/3907 , Y02P20/55
摘要： The present invention provides a method of esterifying dihydroxybenzene starting materials to synthesize unsymmetrical diesters in high yield. Many of the resultant unsymmetrical diesters are useful in dry bleaching compositions. The method can be practiced by selectively monoacylating a dihydroxybenzene starting material with an acid anhydride to form an intermediate monoester having the structure ##STR1## which is then acylated to form a diester reaction product having the structure ##STR2## wherein R.sub.1 is greater than R.sub.3 (and both R.sub.1 and R.sub.3 are alkyl groups) and X is a substituent group which does not participate in the esterification (or which can have a protecting group thereon).
摘要翻译： 本发明提供了一种酯化二羟基苯原料以高产率合成非对称二酯的方法。 许多所得的非对称二酯在干燥漂白组合物中是有用的。 该方法可以通过用酸酐选择性单酰化二羟基苯原料来形成具有结构“IMAGE”的中间体单酯，然后将其进行酰化，形成具有结构“IMAGE”的二酯反应产物，其中R1大于R3（ 并且R 1和R 3都是烷基），X是不参与酯化反应的取代基（或其中可以具有保护基）。
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