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31 条记录 (耗时 0.023 秒)

    Method for producing low-odor n-butane
    4.
    发明授权
    Method for producing low-odor n-butane 有权
    生产低气味正丁烷的方法

    公开(公告)号：US08846994B2

    公开(公告)日：2014-09-30

    申请号：US13381735

    申请日：2010-05-21

    申请人： Hans-Gerd Lueken ,  Alfred Kaizik ,  Markus Winterberg ,  Wilfried Bueschken ,  Dirk Fridag

    发明人： Hans-Gerd Lueken ,  Alfred Kaizik ,  Markus Winterberg ,  Wilfried Bueschken ,  Dirk Fridag

    IPC分类号： C07C5/00 ,  C07C9/10 ,  C07C7/163 ,  C07C7/10

    CPC分类号： C07C9/10 ,  C07C7/10 ,  C07C7/163

    摘要： The invention relates to a method for producing low-odor n-butane by catalytic hydrogenation of a feed mixture. The aim of the invention is to provide such a method, wherein the feed material, in addition to n-butane, n-butene and up to 1 mass % formic acid and/or up to 1 mass % pentanals and/or up to 0.5 mass % pentanols, also comprises carbon monoxide. The aim is achieved by treating the feed mixture in the temperature range of 15 to 120° C. with an aqueous solution of an alkali metal or alkaline earth metal hydroxide in the concentration range of 0.5 to 30 mass % and subsequently subjecting the feed mixture to the catalytic hydrogenation.

    摘要翻译： 本发明涉及通过进料混合物的催化氢化生产低气味正丁烷的方法。 本发明的目的是提供这样的方法，其中除了正丁烷，正丁烯和至多1质量％的甲酸和/或至多1质量％的戊醛和/或至多0.5的进料之外， 质量％戊醇还含有一氧化碳。 目的是通过在0.5〜30质量％的浓度范围内用碱金属或碱土金属氢氧化物的水溶液处理15〜120℃的温度范围内的进料混合物，然后将进料混合物 催化氢化。

    PROCESS FOR PREPARING ALPHA,BETA-UNSATURATED C10-ALDEHYDES
    5.
    发明申请
    PROCESS FOR PREPARING ALPHA,BETA-UNSATURATED C10-ALDEHYDES 有权
    制备ALPHA，不饱和C10-醛缩合物的方法

    公开(公告)号：US20120123169A1

    公开(公告)日：2012-05-17

    申请号：US13256116

    申请日：2010-02-23

    申请人： Alfred Kaizik ,  Dirk Fridag ,  Hans-Gerd Lueken ,  Wilfried Bueschken

    发明人： Alfred Kaizik ,  Dirk Fridag ,  Hans-Gerd Lueken ,  Wilfried Bueschken

    IPC分类号： C07C45/45

    CPC分类号： C07C45/74 ,  Y02P20/582 ,  C07C47/21

    摘要： The invention relates to a method for continuously producing α,β-unsaturated C10-aldehydes from aliphatic C5-aldehydes, comprising the following steps: aldol-condensing aliphatic C5-aldehydes into α,β-unsaturated C10-aldehydes in the presence of an aqueous base in a tube reactor; phase separating the output of the tube reactor into an aqueous catalyst phase and an organic product phase; separating the organic product phase into α,β-unsaturated C10-aldehydes, aliphatic C5-aldehydes, and auxiliary products; discharging a part of the aqueous catalyst phase to remove the reaction water and supplementing said part with liquor solution and subsequently returning said part to the tube reactor. The task of the invention is to improve a method of said kind in a way such that it requires lower energy input. This is achieved in that the aliphatic C5-aldehydes and/or the α,β-unsaturated C10-aldehydes are dispersed in the aqueous base as drops, wherein the average Sauter diameter of the drops is between 0.2 mm and 2 mm.

    摘要翻译： 本发明涉及从脂肪族C5醛连续生产α，β-不饱和C10醛的方法，包括以下步骤：将脂族C 5 - 醛缩合成α，β-不饱和C10醛，在 管式反应器中的水性碱; 将管式反应器的输出相分离成水性催化剂相和有机产物相; 将有机产物相分离成α，β-不饱和C10醛，脂肪族C5醛和辅助产物; 排出一部分水性催化剂相以除去反应水并用液体溶液补充所述部分，随后将所述部分返回到管式反应器。 本发明的任务是改进所述种类的方法，使其需要较低的能量输入。 这是通过脂肪族C5醛和/或α，β-不饱和C10醛以水滴的形式分散在水性基质中，其中液滴的平均Sauter直径在0.2mm和2mm之间。

    Process for preparing α,β-unsaturated C10-aldehydes
    6.
    发明授权
    Process for preparing α,β-unsaturated C10-aldehydes 有权
    制备α，β-不饱和C10醛的方法

    公开(公告)号：US08581008B2

    公开(公告)日：2013-11-12

    申请号：US13256116

    申请日：2010-02-23

    申请人： Alfred Kaizik ,  Dirk Fridag ,  Hans-Gerd Lueken ,  Wilfried Bueschken

    发明人： Alfred Kaizik ,  Dirk Fridag ,  Hans-Gerd Lueken ,  Wilfried Bueschken

    IPC分类号： C07C45/45

    CPC分类号： C07C45/74 ,  Y02P20/582 ,  C07C47/21

    摘要： The invention relates to a method for continuously producing α,β-unsaturated C10-aldehydes from aliphatic C5-aldehydes, comprising the following steps: aldol-condensing aliphatic C5-aldehydes into α,β-unsaturated C10-aldehydes in the presence of an aqueous base in a tube reactor; phase separating the output of the tube reactor into an aqueous catalyst phase and an organic product phase; separating the organic product phase into α,β-unsaturated C10-aldehydes, aliphatic C5-aldehydes, and auxiliary products; discharging a part of the aqueous catalyst phase to remove the reaction water and supplementing said part with liquor solution and subsequently returning said part to the tube reactor. The task of the invention is to improve a method of said kind in a way such that it requires lower energy input. This is achieved in that the aliphatic C5-aldehydes and/or the α,β-unsaturated C10-aldehydes are dispersed in the aqueous base as drops, wherein the average Sauter diameter of the drops is between 0.2 mm and 2 mm.

    摘要翻译： 本发明涉及一种从脂肪族C5醛连续生产α，β-不饱和C10醛的方法，包括以下步骤：将脂族C 5 - 醛缩合成α，β-不饱和C10醛在水溶液 基于管式反应器; 将管式反应器的输出相分离成水性催化剂相和有机产物相; 将有机产物相分离成α，β-不饱和C10醛，脂族C5醛和辅助产物; 排出一部分水性催化剂相以除去反应水并用液体溶液补充所述部分，随后将所述部分返回到管式反应器。 本发明的任务是改进所述种类的方法，使其需要较低的能量输入。 这是因为脂族C 5 - 醛和/或α，β-不饱和C 10 - 醛以水滴的形式分散在水性碱中，其中液滴的平均Sauter直径在0.2mm与2mm之间。

    PROCESS FOR PREPARING DECANECARBOXYLIC ACIDS
    8.
    发明申请
    PROCESS FOR PREPARING DECANECARBOXYLIC ACIDS 有权
    制备癸酰氧基酸的方法

    公开(公告)号：US20120172624A1

    公开(公告)日：2012-07-05

    申请号：US13386523

    申请日：2010-05-25

    申请人： Michael Grass ,  Alfred Kaizik ,  Hans-Gerd Lueken ,  Wilfried Bueschken

    发明人： Michael Grass ,  Alfred Kaizik ,  Hans-Gerd Lueken ,  Wilfried Bueschken

    IPC分类号： C07C51/373

    CPC分类号： C07C45/74 ,  C07C45/50 ,  C07C45/62 ,  C07C51/235 ,  C07C47/02 ,  C07C47/21 ,  C07C53/128

    摘要： The invention relates to a process for preparing a mixture of isomeric decane-carboxylic acids, which comprises the following steps:a) hydroformylation of a hydrocarbon mixture containing linear C4-olefins using a rhodium-containing catalyst system;b) aldol condensation of a mixture of aliphatic C5-aldehydes obtained from step a);c) selective hydrogenation of the mixture of unsaturated C10-aldehydes from step b) to aliphatic C10-aldehydes;d) uncatalysed oxidation of the mixture of aliphatic C10-aldehydes from step c) to give a mixture having a proportion of at least 70% by mass of 2-propylheptanoic acid, based on the total content of isomeric decanecarboxylic acids.

    摘要翻译： 本发明涉及一种制备异构癸烷 - 羧酸的混合物的方法，其包括以下步骤：a）使用含铑催化剂体系加氢甲酰化含有线性C 4 - 烯烃的烃混合物; b）从步骤a）获得的脂族C 5 - 醛的混合物的醛醇缩合; c）选自氢化来自步骤b）的不饱和C10-醛的混合物至脂族C 10 - 醛; d）来自步骤c）的脂族C 10 - 醛混合物的未催化氧化，得到基于异构癸烷羧酸的总含量的至少70质量％的2-丙基庚酸的混合物。

    ONE-STAGE CONTINUOUS PROCESS FOR HYDROFORMYLATING HIGHER OLEFINS OR OLEFIN MIXTURES
    9.
    发明申请
    ONE-STAGE CONTINUOUS PROCESS FOR HYDROFORMYLATING HIGHER OLEFINS OR OLEFIN MIXTURES 有权
    氢化烯烃或烯烃混合物的一步连续工艺

    公开(公告)号：US20100249464A1

    公开(公告)日：2010-09-30

    申请号：US12738111

    申请日：2008-10-28

    申请人： Hans-Gerd Lueken ,  Stefan Drees ,  Alfred Kaizik ,  Wilfried Bueschken

    发明人： Hans-Gerd Lueken ,  Stefan Drees ,  Alfred Kaizik ,  Wilfried Bueschken

    IPC分类号： C07C45/00 ,  C07C29/00

    CPC分类号： C07C29/16 ,  C07C45/50 ,  C07C47/02 ,  C07C31/125

    摘要： The invention relates to a one-stage continuous process for hydroformylating olefins having at least 5 carbon atoms to the corresponding aldehydes and/or alcohols having at least 6 carbon atoms in the presence of unmodified cobalt catalysts in a process in which, in the presence of an aqueous phase and of an organic phase, catalyst formation, catalyst extraction and hydroformylation proceed in the same reactor, which is characterized in that more aqueous cobalt salt solution is fed into the reactor as an aqueous phase with the liquid reaction mixture and is discharged from the reactor with the gas phase, and in that the level of the aqueous bottom phase is kept constant by continuously conducting a portion of the aqueous bottom phase out of the reactor.

    摘要翻译： 本发明涉及在未改性的钴催化剂的存在下，在具有至少5个碳原子的烯烃中对相应的醛和/或具有至少6个碳原子的醇进行加氢甲酰化的一步连续方法，其中在存在 水相和有机相，催化剂形成，催化剂萃取和加氢甲酰化在相同的反应器中进行，其特征在于更多的钴盐水溶液作为水相与液体反应混合物进料到反应器中并从 具有气相的反应器，并且通过将一部分水相底部相继续导出反应器，水相底部水平保持恒定。

    Process for preparing decanecarboxylic acids
    10.
    发明授权
    Process for preparing decanecarboxylic acids 有权
    癸烷羧酸的制备方法

    公开(公告)号：US08907129B2

    公开(公告)日：2014-12-09

    申请号：US13386523

    申请日：2010-05-25

    申请人： Michael Grass ,  Alfred Kaizik ,  Hans-Gerd Lueken ,  Wilfried Bueschken

    发明人： Michael Grass ,  Alfred Kaizik ,  Hans-Gerd Lueken ,  Wilfried Bueschken

    IPC分类号： C07C51/235 ,  C07C45/74 ,  C07C45/62 ,  C07C45/50

    CPC分类号： C07C45/74 ,  C07C45/50 ,  C07C45/62 ,  C07C51/235 ,  C07C47/02 ,  C07C47/21 ,  C07C53/128

    摘要： The invention relates to a process for preparing a mixture of isomeric decane-carboxylic acids, which comprises the following steps: a) hydroformylation of a hydrocarbon mixture containing linear C4-olefins using a rhodium-containing catalyst system; b) aldol condensation of a mixture of aliphatic C5-aldehydes obtained from step a); c) selective hydrogenation of the mixture of unsaturated C10-aldehydes from step b) to aliphatic C10-aldehydes; d) uncatalysed oxidation of the mixture of aliphatic C10-aldehydes from step c) to give a mixture having a proportion of at least 70% by mass of 2-propylheptanoic acid, based on the total content of isomeric decanecarboxylic acids.

    摘要翻译： 本发明涉及一种制备异构癸烷 - 羧酸的混合物的方法，其包括以下步骤：a）使用含铑催化剂体系加氢甲酰化含有线性C 4 - 烯烃的烃混合物; b）从步骤a）获得的脂族C 5 - 醛的混合物的醛醇缩合; c）选自氢化来自步骤b）的不饱和C10-醛的混合物至脂族C 10 - 醛; d）来自步骤c）的脂族C 10 - 醛混合物的未催化氧化，得到基于异构癸烷羧酸的总含量的至少70质量％的2-丙基庚酸的混合物。