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公开(公告)号：US20090247724A1
公开(公告)日：2009-10-01
申请号：US12414856
申请日：2009-03-31
CPC分类号： C08G65/44 , H05K1/0326
摘要： A poly(arylene ether) copolymer is the product of oxidative copolymerization of monomers including a monohydric phenol and a dihydric phenol. It has an intrinsic viscosity of about 0.04 to about 0.15 deciliter per gram and, on average, about 1.8 to about 2 hydroxyl groups per molecule. The poly(arylene ether) copolymer is enriched in low molecular weight copolymer chains and copolymer chains that include a terminal unit derived from the dihydric phenol.
摘要翻译： 聚（亚芳基醚）共聚物是包括一元酚和二元酚的单体的氧化共聚的产物。 其特性粘度为约0.04至约0.15分升每克，平均每分子约1.8至约2个羟基。 聚（亚芳基醚）共聚物富含低分子量共聚物链和共聚物链，其包括源自二元酚的末端单元。
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公开(公告)号：US07541421B2
公开(公告)日：2009-06-02
申请号：US11298182
申请日：2005-12-08
CPC分类号： C08G65/44 , H05K1/0326
摘要： A poly(arylene ether) copolymer is the product of oxidative copolymerization of monomers including a monohydric phenol and a dihydric phenol. It has an intrinsic viscosity of about 0.04 to about 0.15 deciliter per gram and, on average, about 1.8 to about 2 hydroxyl groups per molecule. The poly(arylene ether) copolymer is enriched in low molecular weight copolymer chains and copolymer chains that include a terminal unit derived from the dihydric phenol.
摘要翻译： 聚（亚芳基醚）共聚物是包括一元酚和二元酚的单体的氧化共聚的产物。 其特性粘度为约0.04至约0.15分升每克，平均每分子约1.8至约2个羟基。 聚（亚芳基醚）共聚物富含低分子量共聚物链和共聚物链，其包括源自二元酚的末端单元。
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公开(公告)号：US07671167B2
公开(公告)日：2010-03-02
申请号：US12414856
申请日：2009-03-31
IPC分类号： C08G65/38
CPC分类号： C08G65/44 , H05K1/0326
摘要： A poly(arylene ether) copolymer is the product of oxidative copolymerization of monomers including a monohydric phenol and a dihydric phenol. It has an intrinsic viscosity of about 0.04 to about 0.15 deciliter per gram and, on average, about 1.8 to about 2 hydroxyl groups per molecule. The poly(arylene ether) copolymer is enriched in low molecular weight copolymer chains and copolymer chains that include a terminal unit derived from the dihydric phenol.
摘要翻译： 聚（亚芳基醚）共聚物是包括一元酚和二元酚的单体的氧化共聚的产物。 其特性粘度为约0.04至约0.15分升每克，平均每分子约1.8至约2个羟基。 聚（亚芳基醚）共聚物富含低分子量共聚物链和共聚物链，其包括源自二元酚的末端单元。
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公开(公告)号：US07595367B2
公开(公告)日：2009-09-29
申请号：US11845823
申请日：2007-08-28
申请人： Alvaro Carrillo , Hua Guo , Alexey Kruglov , Edward Norman Peters
发明人： Alvaro Carrillo , Hua Guo , Alexey Kruglov , Edward Norman Peters
IPC分类号： C08F283/08
CPC分类号： C08G65/44 , C08G65/485 , C08L2205/05
摘要： Capped poly(arylene ether)s are prepared by a method that includes reacting a poly(arylene ether) with a capping agent to form a capping reaction mixture, washing the capping reaction mixture with a concentrated basic aqueous solution, and isolating the capped poly(arylene ether) by a total isolation method. The washing method is effective for removal of capping-related impurities, and surprisingly does not result in decomposition of the capped poly(arylene ether).
摘要翻译： 通过包括使聚（亚芳基醚）与封端剂反应形成封端反应混合物，用浓缩的碱性水溶液洗涤封端反应混合物并分离封端的聚（亚芳基醚）的聚（亚芳基醚） 亚芳基醚）。 洗涤方法对于除去封盖相关杂质是有效的，并且令人惊讶地不会导致封端的聚（亚芳基醚）的分解。
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公开(公告)号：US20090062478A1
公开(公告)日：2009-03-05
申请号：US11845823
申请日：2007-08-28
申请人： Alvaro Carrillo , Hua Guo , Alexey Kruglov , Edward Norman Peters
发明人： Alvaro Carrillo , Hua Guo , Alexey Kruglov , Edward Norman Peters
IPC分类号： C08G65/48
CPC分类号： C08G65/44 , C08G65/485 , C08L2205/05
摘要： Capped poly(arylene ether)s are prepared by a method that includes reacting a poly(arylene ether) with a capping agent to form a capping reaction mixture, washing the capping reaction mixture with a concentrated basic aqueous solution, and isolating the capped poly(arylene ether) by a total isolation method. The washing method is effective for removal of capping-related impurities, and surprisingly does not result in decomposition of the capped poly(arylene ether).
摘要翻译： 通过包括使聚（亚芳基醚）与封端剂反应形成封端反应混合物，用浓缩的碱性水溶液洗涤封端反应混合物并分离封端的聚（亚芳基醚）的聚（亚芳基醚） 亚芳基醚）。 洗涤方法对于去除封端相关杂质是有效的，并且令人惊奇地不会导致封端的聚（亚芳基醚）的分解。
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公开(公告)号：US20070135609A1
公开(公告)日：2007-06-14
申请号：US11298182
申请日：2005-12-08
申请人： Alvaro Carrillo , Erik Delsman , Hua Guo , Alexey Kruglov , Edward Peters
发明人： Alvaro Carrillo , Erik Delsman , Hua Guo , Alexey Kruglov , Edward Peters
IPC分类号： C08G61/02
CPC分类号： C08G65/44 , H05K1/0326
摘要： A poly(arylene ether) copolymer is the product of oxidative copolymerization of monomers including a monohydric phenol and a dihydric phenol. It has an intrinsic viscosity of about 0.04 to about 0.15 deciliter per gram and, on average, about 1.8 to about 2 hydroxyl groups per molecule. The poly(arylene ether) copolymer is enriched in low molecular weight copolymer chains and copolymer chains that include a terminal unit derived from the dihydric phenol.
摘要翻译： 聚（亚芳基醚）共聚物是包括一元酚和二元酚的单体的氧化共聚的产物。 其特性粘度为约0.04至约0.15分升每克，平均每分子约1.8至约2个羟基。 聚（亚芳基醚）共聚物富含低分子量共聚物链和共聚物链，其包括源自二元酚的末端单元。
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公开(公告)号：US20070106051A1
公开(公告)日：2007-05-10
申请号：US11272119
申请日：2005-11-10
申请人： Alvaro Carrillo , Erik Delsman , Hua Guo , Alexey Kruglov , Edward Peters
发明人： Alvaro Carrillo , Erik Delsman , Hua Guo , Alexey Kruglov , Edward Peters
IPC分类号： C08G61/02
CPC分类号： C08G65/44 , C08G65/46 , H05K1/0326
摘要： A polyfunctional poly(arylene ether) resin may be prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a polyhydric phenol in an aromatic hydrocarbon solvent in the presence of a catalyst comprising a metal ion and a nitrogen-containing ligand to form a solution comprising a polyfunctional poly(arylene ether) having an intrinsic viscosity of about 0.04 to about 0.3 deciliter per gram at 25° C. in chloroform; and contacting the polyfunctional poly(arylene ether) solution with an aqueous solution of a chelating agent to extract the metal ion from the solution; wherein the chelating agent and metal ion are present in a molar ratio of about 1.0 to about 1.5. The method reduces the formation of a dispersion during the chelation step.
摘要翻译： 多官能聚（亚芳基醚）树脂可以通过包括在包含金属离子和含氮配体的催化剂存在下在芳烃溶剂中将一元酚和多元酚氧化共聚以形成溶液的方法来制备 包括在25℃下在氯仿中特性粘度为约0.04至约0.3分升/克的多官能聚（亚芳基醚） 并使多官能聚（亚芳基醚）溶液与螯合剂的水溶液接触，从溶液中提取金属离子; 其中所述螯合剂和金属离子以约1.0至约1.5的摩尔比存在。 该方法减少了螯合步骤期间分散体的形成。
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8.发明授权公开(公告)号：US07205377B2
公开(公告)日：2007-04-17
申请号：US10953723
申请日：2004-09-29
摘要： A method for preparing a poly(arylene ether) with a reduced level of powder fines is described. In one embodiment, the method comprises oxidatively coupling a monohydric phenol in the presence of a solvent and a complex metal catalyst, to produce a poly(arylene ether) resin; and then removing a portion of the solvent to produce a concentrated solution having a cloud point Tcloud. The concentrated solution is then combined with an anti-solvent to precipitate the poly(arylene ether) in the form of a precipitation mixture. The concentrated solution usually has a temperature of at least about (Tcloud−10° C.) immediately before it is combined with the anti-solvent. The precipitation mixture has a temperature of at least about (Tcloud−40° C.) after its formation. Related poly(arylene ether) copolymers are also described.
摘要翻译： 描述了一种制备具有降低粉末粉粒度的聚（亚芳基醚）的方法。 在一个实施方案中，该方法包括在溶剂和复合金属催化剂的存在下将一元酚氧化偶联以产生聚（亚芳基醚）树脂; 然后除去溶剂的一部分以产生具有浊点T云的浓缩溶液。 然后将浓缩溶液与抗溶剂组合以沉淀出沉淀混合物形式的聚（亚芳基醚）。 在与抗溶剂组合之前，浓缩溶液通常具有至少约（T N 10 -2℃）的温度。 沉淀混合物在其形成之后的温度至少约为（T -40℃）。 还描述了相关的聚（亚芳基醚）共聚物。
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公开(公告)号：US06680270B2
公开(公告)日：2004-01-20
申请号：US09681527
申请日：2001-04-24
申请人： Rudy Francois Alain Joseph Peemans , Alexey Kruglov , Sheldon Jay Shafer , Chuks O. Mbeledogu , Darlene Hope Nance , Karl Aaron Baro , Emil Markov Georgiev , Eduard Hendricus Schlarmann , Gaylord Michael Kissinger
发明人： Rudy Francois Alain Joseph Peemans , Alexey Kruglov , Sheldon Jay Shafer , Chuks O. Mbeledogu , Darlene Hope Nance , Karl Aaron Baro , Emil Markov Georgiev , Eduard Hendricus Schlarmann , Gaylord Michael Kissinger
IPC分类号： B01J3852
CPC分类号： B01J31/10 , B01J31/0225 , B01J31/4007 , B01J2231/342 , C07C37/20 , Y02P20/584 , C07C39/16
摘要： A method for regenerating deactivated sulfonated cation exchange catalysts comprises washing the deactivated catalyst with phenol-water mixtures comprising about 5-20 wt. % of water in phenol at a temperature of about 70-95° C.
摘要翻译： 再生失活的磺化阳离子交换催化剂的方法包括用包含约5-20wt。 在约70-95℃的温度下苯酚中的水的％
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10.发明申请公开(公告)号：US20060069229A1
公开(公告)日：2006-03-30
申请号：US10953723
申请日：2004-09-29
摘要： A method for preparing a poly(arylene ether) with a reduced level of powder fines is described. In one embodiment, the method comprises oxidatively coupling a monohydric phenol in the presence of a solvent and a complex metal catalyst, to produce a poly(arylene ether) resin; and then removing a portion of the solvent to produce a concentrated solution having a cloud point Tcloud. The concentrated solution is then combined with an anti-solvent to precipitate the poly(arylene ether) in the form of a precipitation mixture. The concentrated solution usually has a temperature of at least about (Tcloud−10° C.) immediately before it is combined with the anti-solvent. The precipitation mixture has a temperature of at least about (Tcloud−40° C.) after its formation. Related poly(arylene ether) copolymers are also described.
摘要翻译： 描述了一种制备具有降低粉末粉粒度的聚（亚芳基醚）的方法。 在一个实施方案中，该方法包括在溶剂和复合金属催化剂的存在下将一元酚氧化偶联以产生聚（亚芳基醚）树脂; 然后除去溶剂的一部分以产生具有浊点T云的浓缩溶液。 然后将浓缩溶液与抗溶剂组合以沉淀出沉淀混合物形式的聚（亚芳基醚）。 在与抗溶剂组合之前，浓缩溶液通常具有至少大约（T 1云）-10℃的温度。 沉淀混合物在其形成之后的温度至少约为（T -40℃）。 还描述了相关的聚（亚芳基醚）共聚物。
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