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公开(公告)号：US06680270B2
公开(公告)日：2004-01-20
申请号：US09681527
申请日：2001-04-24
申请人： Rudy Francois Alain Joseph Peemans , Alexey Kruglov , Sheldon Jay Shafer , Chuks O. Mbeledogu , Darlene Hope Nance , Karl Aaron Baro , Emil Markov Georgiev , Eduard Hendricus Schlarmann , Gaylord Michael Kissinger
发明人： Rudy Francois Alain Joseph Peemans , Alexey Kruglov , Sheldon Jay Shafer , Chuks O. Mbeledogu , Darlene Hope Nance , Karl Aaron Baro , Emil Markov Georgiev , Eduard Hendricus Schlarmann , Gaylord Michael Kissinger
IPC分类号： B01J3852
CPC分类号： B01J31/10 , B01J31/0225 , B01J31/4007 , B01J2231/342 , C07C37/20 , Y02P20/584 , C07C39/16
摘要： A method for regenerating deactivated sulfonated cation exchange catalysts comprises washing the deactivated catalyst with phenol-water mixtures comprising about 5-20 wt. % of water in phenol at a temperature of about 70-95° C.
摘要翻译： 再生失活的磺化阳离子交换催化剂的方法包括用包含约5-20wt。 在约70-95℃的温度下苯酚中的水的％
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2.发明申请Polyethermide resins useful for high temperature applications, and related processes 审中-公开用于高温应用的聚醚醚树脂及相关工艺公开(公告)号：US20120082833A1
公开(公告)日：2012-04-05
申请号：US12924666
申请日：2010-09-30
申请人： Sheldon Jay Shafer
发明人： Sheldon Jay Shafer
CPC分类号： C08G73/1042 , C08G73/1046 , C08G73/105
摘要： A polyetherimide resin is described herein. The resin includes a structure of repeating units of the formula (I) wherein each aromatic ring in the structure can be substituted with at least one halogen atom, nitro group, cyano group, alkyl group, cycloalkyl group, or aryl group. Another embodiment relates to a method for preparing a polyetherimide polymer. The method includes the step of reacting metaphenylenediamine bis(4-nitrophthalimide) with a bisphenolic mixture of a salt of bisphenol A and a salt of an arylcyano-modified bisphenol.
摘要翻译： 本文描述了聚醚酰亚胺树脂。 树脂包括式（I）的重复单元的结构，其中结构中的每个芳环可被至少一个卤素原子，硝基，氰基，烷基，环烷基或芳基取代。 另一个实施方案涉及一种制备聚醚酰亚胺聚合物的方法。 该方法包括使间苯二胺双（4-硝基邻苯二甲酰亚胺）与双酚A的盐和芳基氰基改性双酚的盐的双酚混合物反应的步骤。
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3.发明申请Monomers for preparing polycarbonate resins, methods of preparing the monomers, polycarbonate resins prepared with the monomers, and capacitors comprising the polycarbonate resins 失效用于制备聚碳酸酯树脂的单体，制备单体的方法，用单体制备的聚碳酸酯树脂，以及包含聚碳酸酯树脂的电容器公开(公告)号：US20110242729A1
公开(公告)日：2011-10-06
申请号：US12751649
申请日：2010-03-31
申请人： Norberto Silvi , Gary Charles Davis , Patrick Joseph McCloskey , Sheldon Jay Shafer , Julia Lam Lee , Yang Cao , Patricia Chapman Irwin
发明人： Norberto Silvi , Gary Charles Davis , Patrick Joseph McCloskey , Sheldon Jay Shafer , Julia Lam Lee , Yang Cao , Patricia Chapman Irwin
IPC分类号： H01G4/08 , C08G64/04 , C07C255/50
CPC分类号： C08G64/12 , C07C255/53 , H01G4/18 , Y10T29/41 , Y10T29/417
摘要： A monomer and polycarbonate resin are provided, as are methods of making the monomer. The resin may be used to provide a thin film that has a higher dielectric constant and higher glass transition temperature, and similar breakdown strength and similar dissipation factor to films prepared from polycarbonate resins not so modified. The thin films, in turn, may advantageously be used to form, wholly or in part, articles such as capacitors, sensors, batteries, flexible printed circuit boards, keyboard membranes, motor/transformer insulations, cable wrappings, industrial tapes, interior coverage materials, and the like. In particular, a capacitor comprising the polycarbonate resin is also provided.
摘要翻译： 提供单体和聚碳酸酯树脂，以及制备单体的方法。 该树脂可用于提供具有较高介电常数和较高玻璃化转变温度的薄膜，以及与未进行改性的聚碳酸酯树脂制备的薄膜相似的击穿强度和相似的耗散因数。 薄膜又可有利地用于整体或部分地形成诸如电容器，传感器，电池，柔性印刷电路板，键盘膜，电动机/变压器绝缘体，电缆包装，工业胶带，内部覆盖材料 ，等等。 特别地，还提供了包含聚碳酸酯树脂的电容器。
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公开(公告)号：US5981788A
公开(公告)日：1999-11-09
申请号：US963109
申请日：1997-11-03
IPC分类号： B09B3/00 , B01J23/94 , B01J27/32 , B01J31/40 , B01J38/00 , B01J38/50 , C07C68/08 , C07C69/68 , C07C69/96
CPC分类号： B01J31/1805 , B01J31/0239 , B01J31/04 , B01J31/2208 , B01J31/2239 , B01J31/4023 , B01J31/4038 , C22B11/048 , B01J2531/82 , B01J2531/822 , B01J2531/845 , B01J27/10 , Y02P10/214
摘要： Catalytic materials including divalent palladium compounds, divalent cobalt compounds and bromide sources such as tetraalkylammonium and hexaalkylguanidinium bromides are removed from organic carbonylation reaction mixtures comprising said materials in combination with diaryl carbonate and hydroxyaromatic compound. The removal steps include extraction with an aqueous complexing solution for palladium, extraction with an aqueous non-basic and preferably ionic extractant for cobalt, and extraction with water to remove bromide source. These steps may be combined into an integrated process. Further steps of recycle of the palladium by reduction to elemental palladium and conversion to a catalytically active species, and conversion of cobalt to a catalytically active species, may be included in the integrated process.
摘要翻译： 包括二价钯化合物，二价钴化合物和溴化物源如四烷基铵和六烷基胍溴化物的催化材料从包含所述材料的碳酸二芳基酯和羟基芳族化合物的有机羰基化反应混合物中除去。 去除步骤包括用钯的水性络合溶液萃取，用非水碱性和优选离子萃取剂用于钴的萃取，并用水萃取以除去溴化物源。 这些步骤可以组合成一个集成的过程。 在一体化方法中可以包括通过还原成元素钯并转化为催化活性物质的钯和将钴转化成催化活性物质的再循环的步骤。
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5.发明授权
公开(公告)号：US5908952A
公开(公告)日：1999-06-01
申请号：US823784
申请日：1997-03-24
CPC分类号： C07C68/005
摘要： Hydroxyaromatic compounds such as phenol are converted to diaryl carbonates by reaction with oxygen and carbon monoxide in the presence of a catalyst package which comprises a Group VIIIB metal, preferably palladium, salt of at least one aliphatic .beta.-diketone such as 2,4-pentanedione. The catalyst package also preferably comprises an inorganic cocatalyst, an organic cocatalyst and a bromide or chloride, preferably bromide, source such as a hexaalkylguanidinium bromide. The use of the .beta.-diketone salt confers such advantages as long shelf life under normal storage conditions, high activity upon recycle and capability of carbonylation at relatively low temperatures.
摘要翻译： 羟基芳族化合物如苯酚通过与氧和一氧化碳反应在催化剂包的存在下转化为碳酸二芳基酯，催化剂包含ⅦB族金属，优选至少一种脂族β-二酮的钯盐，例如2,4-戊二酮 。 催化剂包装还优选包含无机助催化剂，有机助催化剂和溴化物或氯化物，优选溴化物源，例如六烷基溴化胍。 使用β-二酮盐具有在正常储存条件下长保存期限，循环时高活性和在较低温度下羰基化能力的优点。
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6.发明授权Method for preparing diaryl carbonates employing hexaalkylguanidinium halides 失效使用六烷基囟鎓卤化物制备碳酸二芳基酯的方法
公开(公告)号：US5898079A
公开(公告)日：1999-04-27
申请号：US929000
申请日：1997-09-12
IPC分类号： C07C68/00
CPC分类号： C07C68/005
摘要： Hydroxyaromatic compounds such as phenol are converted to diaryl carbonates by reaction with oxygen and carbon monoxide in the presence of a catalyst package which typically comprises a group VIIIB metal or compound thereof, an inorganic cocatalyst, an organic cocatalyst and a hexaalkylguanidinium bromide or chloride, preferably bromide. The use of the hexaalkylguanidinium salt causes an increase in the yield of diaryl carbonate without a decrease in selectivity.
摘要翻译： 在通常包含第VIIIB族金属或其化合物，无机助催化剂，有机助催化剂和六烷基溴化胍或氯化物的催化剂包的存在下，通过与氧和一氧化碳反应，将羟基芳族化合物如苯酚转化为碳酸二芳基酯 溴化物。 六烷基胍盐的使用导致碳酸二芳基酯的收率增加，而不会降低选择性。
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公开(公告)号：US5760272A
公开(公告)日：1998-06-02
申请号：US823785
申请日：1997-03-24
CPC分类号： C07C68/005
摘要： Hydroxyaromatic compounds such as phenol are converted to diaryl carbonates by reaction with oxygen and carbon monoxide in the presence of a catalyst package and an added diluent free from active hydrogen. The preferred catalyst packages comprise a Group VIIIB metal or salt thereof, an inorganic cocatalyst, and organic cocatalysts and a bromide or chloride source. The amount of added diluent is an effective amount to improve selectivity to diaryl carbonate. Preferred diluents are diphenyl carbonate and N-methylpyrrolidone.
摘要翻译： 在催化剂封装和不含活性氢的添加稀释剂的存在下，通过与氧气和一氧化碳反应，将羟基芳族化合物如苯酚转化为碳酸二芳基酯。 优选的催化剂组合物包含VIIIB族金属或其盐，无机助催化剂和有机助催化剂以及溴化物或氯化物源。 添加的稀释剂的量是改善对碳酸二芳基酯的选择性的有效量。 优选的稀释剂是碳酸二苯酯和N-甲基吡咯烷酮。
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公开(公告)号：US5756801A
公开(公告)日：1998-05-26
申请号：US797068
申请日：1997-02-10
CPC分类号： C07C68/08
摘要： Adducts of hydroxyaromatic compounds such as phenol and diaryl carbonates such as diphenyl carbonate are washed with a washing composition comprising a major proportion, typically about 90%, of the hydroxyaromatic compound and a minor proportion, typically about 10%, of the diaryl carbonate.
摘要翻译： 羟基芳族化合物如苯酚和碳酸二芳基酯如碳酸二苯酯的加合物用包含主要比例（通常约90％）的羟基芳族化合物和较小比例，通常约10％的碳酸二芳基酯的洗涤组合物洗涤。 ！
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公开(公告)号：US5723689A
公开(公告)日：1998-03-03
申请号：US587052
申请日：1996-01-16
IPC分类号： B01J31/02 , B01J31/10 , C07B61/00 , C07C37/20 , C07C37/68 , C07C37/74 , C07C37/84 , C07C39/16 , C07C39/12
CPC分类号： C07C37/74 , C07C37/685 , C07C37/84
摘要： A method for recovering substantially pure p,p-bisarylols from a mixture comprising the same by subjecting the mixture to vacuum distillation and melt crystallization in the absence of an adduct crystallization and the generation of a reaction recycle stream.
摘要翻译： 一种通过在不存在加合物结晶并产生反应循环物流的情况下使混合物进行真空蒸馏和熔融结晶从而从包含其的混合物的混合物中回收基本上纯的p，p-双杂环的方法。
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10.发明授权Monomers for preparing polycarbonate resins, methods of preparing the monomers, polycarbonate resins prepared with the monomers, and capacitors comprising the polycarbonate resins 失效用于制备聚碳酸酯树脂的单体，制备单体的方法，用单体制备的聚碳酸酯树脂，以及包含聚碳酸酯树脂的电容器公开(公告)号：US08218291B2
公开(公告)日：2012-07-10
申请号：US12751649
申请日：2010-03-31
申请人： Norberto Silvi , Gary Charles Davis , Patrick Joseph McCloskey , Sheldon Jay Shafer , Julia Lam Lee , Yang Cao , Patricia Chapman Irwin
发明人： Norberto Silvi , Gary Charles Davis , Patrick Joseph McCloskey , Sheldon Jay Shafer , Julia Lam Lee , Yang Cao , Patricia Chapman Irwin
IPC分类号： H01G9/00
CPC分类号： C08G64/12 , C07C255/53 , H01G4/18 , Y10T29/41 , Y10T29/417
摘要： A monomer and polycarbonate resin are provided, as are methods of making the monomer. The resin may be used to provide a thin film that has a higher dielectric constant and higher glass transition temperature, and similar breakdown strength and similar dissipation factor to films prepared from polycarbonate resins not so modified. The thin films, in turn, may advantageously be used to form, wholly or in part, articles such as capacitors, sensors, batteries, flexible printed circuit boards, keyboard membranes, motor/transformer insulations, cable wrappings, industrial tapes, interior coverage materials, and the like. In particular, a capacitor comprising the polycarbonate resin is also provided.
摘要翻译： 提供单体和聚碳酸酯树脂，以及制备单体的方法。 该树脂可用于提供具有较高介电常数和较高玻璃化转变温度的薄膜，以及与未进行改性的聚碳酸酯树脂制备的薄膜相似的击穿强度和相似的耗散因数。 薄膜又可有利地用于整体或部分地形成诸如电容器，传感器，电池，柔性印刷电路板，键盘膜，电动机/变压器绝缘体，电缆包装，工业胶带，内部覆盖材料 ，等等。 特别地，还提供了包含聚碳酸酯树脂的电容器。
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