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公开(公告)号：US08119846B2
公开(公告)日：2012-02-21
申请号：US12299887
申请日：2007-06-01
IPC分类号： C07C17/38
CPC分类号： C07C17/38 , C07C17/08 , C07C17/383 , C07C19/075
摘要： Described is a process for separating an organic phase comprising mainly propyl bromide from a crude reaction mixture formed by free-radical catalyzed hydrobromination of propylene with hydrogen bromide. The process comprises (A) feeding cold water into an upper or mid-portion of a packed column; (B) concurrently feeding the crude reaction mixture into an upper portion and/or mid-portion of the column so that the water contacts the crude reaction mixture; to form a mixture of (i) an acidic aqueous phase comprising aqueous hydrogen bromide and (ii) an organic phase comprising propyl bromide; (C) withdrawing the resultant phases from said column, at a rate comparable to the feeds being made into the column; and (D) separating the phases to form an upper acidic aqueous phase comprising aqueous hydrogen bromide superposed on a lower liquid organic phase comprising propyl bromide, and separating these upper and lower phases from each other.
摘要翻译： 描述了从由丙烯与溴化氢的自由基催化氢溴酸形成的粗反应混合物中分离主要包含丙基溴的有机相的方法。 该方法包括（A）将冷水送入填充塔的上部或中部; （B）同时将粗反应混合物进料到塔的上部和/或中间部分，使得水接触粗反应混合物; 以形成（i）包含溴化氢水溶液的酸性水相和（ii）包含丙基溴的有机相的混合物; （C）以与进料塔进料相当的速率从所述塔中取出所得相; 和（D）分离相以形成上层酸性水相，其包含叠加在包含丙基溴的下部液体有机相上的溴化氢水溶液，并将这些上部和下部相分离。
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公开(公告)号：US20090240091A1
公开(公告)日：2009-09-24
申请号：US12299887
申请日：2007-06-01
IPC分类号： C07C17/38
CPC分类号： C07C17/38 , C07C17/08 , C07C17/383 , C07C19/075
摘要： Described is a process for separating an organic phase comprising mainly propyl bromide from a crude reaction mixture formed by free-radical catalyzed hydrobromination of propylene with hydrogen bromide. The process comprises (A) feeding cold water into an upper or mid-portion of a packed column; (B) concurrently feeding the crude reaction mixture into an upper portion and/or mid-portion of the column so that the water contacts the crude reaction mixture; to form a mixture of (i) an acidic aqueous phase comprising aqueous hydrogen bromide and (ii) an organic phase comprising propyl bromide; (C) withdrawing the resultant phases from said column, at a rate comparable to the feeds being made into the column; and (D) separating the phases to form an upper acidic aqueous phase comprising aqueous hydrogen bromide superposed on a lower liquid organic phase comprising propyl bromide, and separating these upper and lower phases from each other.
摘要翻译： 描述了从由丙烯与溴化氢的自由基催化氢溴酸形成的粗反应混合物中分离主要包含丙基溴的有机相的方法。 该方法包括（A）将冷水送入填充塔的上部或中部; （B）同时将粗反应混合物进料到塔的上部和/或中间部分，使得水接触粗反应混合物; 以形成（i）包含溴化氢水溶液的酸性水相和（ii）包含丙基溴的有机相的混合物; （C）以与进料塔进料相当的速率从所述塔中取出所得相; 和（D）分离相以形成上层酸性水相，其包含叠加在包含丙基溴的下部液体有机相上的溴化氢水溶液，并将这些上部和下部相分离。
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公开(公告)号：US20090054709A1
公开(公告)日：2009-02-26
申请号：US12296629
申请日：2007-04-11
IPC分类号： C07C17/08
CPC分类号： C07C17/08 , C07C19/075
摘要： A process for the production of an aliphatic bromide in which the bromine atom is attached to a terminal carbon atom, which process comprises continuously feeding olefin having a terminal double bond, gaseous hydrogen bromide, and a molecular oxygen-containing gas into a liquid phase reaction medium comprised of aliphatic bromide to cause anti-Markovnikov addition of HBr to terminal olefin, the feeds being proportioned and maintained to provide a molar excess of hydrogen bromide relative to terminal olefin in the range of about 1 to about 5 percent, and a molar ratio of molecular oxygen to terminal olefin of less than 0.005. The process is especially suited for production of n-propyl bromide.
摘要翻译： 一种生产其中溴原子连接到末端碳原子上的脂族溴化物的方法，该方法包括将具有末端双键的烯烃，气态溴化氢和含分子氧的气体连续进料到液相反应 介质由脂肪族溴化物引起，使马可夫尼科夫将HBr加入到末端烯烃中，进料成比例并保持为相对于末端烯烃的摩尔过量的溴化氢为约1至约5％，摩尔比 的分子氧与末端烯烃的摩尔比小于0.005。 该方法特别适用于生产正丙基溴。
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公开(公告)号：US08921624B2
公开(公告)日：2014-12-30
申请号：US12296629
申请日：2007-04-11
CPC分类号： C07C17/08 , C07C19/075
摘要： A process for the production of an aliphatic bromide in which the bromine atom is attached to a terminal carbon atom, which process comprises continuously feeding olefin having a terminal double bond, gaseous hydrogen bromide, and a molecular oxygen-containing gas into a liquid phase reaction medium comprised of aliphatic bromide to cause anti-Markovnikov addition of HBr to terminal olefin, the feeds being proportioned and maintained to provide a molar excess of hydrogen bromide relative to terminal olefin in the range of about 1 to about 5 percent, and a molar ratio of molecular oxygen to terminal olefin of less than 0.005. The process is especially suited for production of n-propyl bromide.
摘要翻译： 一种生产其中溴原子连接到末端碳原子上的脂族溴化物的方法，该方法包括将具有末端双键的烯烃，气态溴化氢和含分子氧的气体连续进料到液相反应 介质由脂肪族溴化物引起，使马可夫尼科夫将HBr加入到末端烯烃中，进料成比例并保持为相对于末端烯烃的摩尔过量的溴化氢为约1至约5％，摩尔比 的分子氧与末端烯烃的摩尔比小于0.005。 该方法特别适用于生产正丙基溴。
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公开(公告)号：US20080058554A1
公开(公告)日：2008-03-06
申请号：US11846420
申请日：2007-08-28
申请人： Keith G. Anderson , James E. Torres
发明人： Keith G. Anderson , James E. Torres
IPC分类号： C07C49/00
CPC分类号： C23G5/028 , C07C17/08 , C11D7/28 , C11D11/0047 , C07C19/075
摘要： This invention provides wet and dry n-propyl bromide compositions comprising minimal amounts of acetone, bromoacetone, 1-propanol, and isopropyl bromide. These n-propyl bromide compositions are formed by free-radical catalyzed hydrobromination of propylene with hydrogen bromide.
摘要翻译： 本发明提供含有最少量的丙酮，溴丙酮，1-丙醇和异丙基溴的湿和干的正丙基溴组合物。 这些正丙基溴组合物是通过丙烯与溴化氢的自由基催化氢溴化形成的。
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6.发明授权公开(公告)号：US06352725B1
公开(公告)日：2002-03-05
申请号：US09451344
申请日：1999-11-30
IPC分类号： A01N3900
CPC分类号： C02F1/766 , A01N59/00 , C02F2303/04 , A01N2300/00
摘要： The process involves (a) continuously forming bromine chloride from separate feed streams of bromine and chlorine by maintaining said streams under automatic feed rate control whereby the streams are continuously proportioned to come together in equimolar amounts to form bromine chloride; (b) continuously forming an aqueous product having an active bromine content of at least 100,000 ppm (wt/wt), a pH of at least 7, and an atom ratio of nitrogen to active bromine greater than 0.93:1 by continuously feeding into mixing apparatus separate feed streams of (1) bromine chloride formed in (a), and (2) an aqueous solution of alkali metal salt of sulfamic acid, under automatic feed rate control whereby the feed streams are continuously proportioned to come together in amounts that produce an aqueous product having an active bromine content of at least 100,000 ppm (wt/wt), a pH of at least 7, and an atom ratio of nitrogen to active bromine from (1) and (2) greater than 0.93:1; and, (c) withdrawing said aqueous product from said mixing apparatus at a rate sufficient to enable the continuous feeding in (a) and (b) to be maintained.
摘要翻译： 该方法包括（a）通过在自动进料速率控制下将所述物流保持在连续成比例的范围内，以等摩尔量混合形成溴氯化物，从溴和氯的不同进料流中连续形成溴氯化物; （b）连续地形成具有至少100,000ppm（wt / wt）的活性溴含量，至少7的pH以及氮与活性溴的原子比大于0.93:1的含水产物， 在（a）中形成的（1）溴化氯和（2）氨基磺酸的碱金属盐的水溶液的分离进料流，其中进料流被连续地成比例地以一定的量生成 活性溴含量至少为100,000ppm（wt / wt），pH至少为7，氮与活性溴的原子比（1）和（2）大于0.93:1的含水产物; 和（c）以足以使（a）和（b）中的连续进料保持的速率从所述混合装置中取出所述含水产物。
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公开(公告)号：US5025050A
公开(公告)日：1991-06-18
申请号：US494398
申请日：1990-03-16
申请人： James E. Torres
发明人： James E. Torres
IPC分类号： C08K5/3417 , C08K5/3435 , C08K5/3475 , C08K5/521
CPC分类号： C08K5/3417 , C08K5/3435 , C08K5/3475 , C08K5/521
摘要： This invention relates to an ultraviolet-radiation stabilizer flame retarding system containing an N,N'-ethylene-bis(tetrabromophthalimide) or an N,N'-bis(tetrabromophthalimide) predominate product, a hindered-amine light stabilizer, a 2-(2'-hydroxyphenyl)benzotriazole, a titanate, and, optionally, Mg(OH).sub.2 and/or ZnO.
摘要翻译： 本发明涉及含有N，N'-亚乙基 - 双（四溴邻苯二甲酰亚胺）或N，N'-双（四溴邻苯二甲酰亚胺）主要产品，受阻胺光稳定剂，2-（ 2'-羟基苯基）苯并三唑，钛酸盐和任选的Mg（OH）2和/或ZnO。
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8.发明授权公开(公告)号：US06348219B1
公开(公告)日：2002-02-19
申请号：US09663788
申请日：2000-09-18
IPC分类号： A01N5902
CPC分类号： C02F1/766 , A01N59/00 , C02F2303/04 , A01N2300/00
摘要： The process involves (a) continuously forming bromine chloride from separate feed streams of bromine and chlorine by maintaining said streams under automatic feed rate control whereby the streams are continuously proportioned to come together to form bromine chloride; (b) continuously forming an aqueous product having an active bromine content of at least 100,000 ppm (wt/wt), a pH of at least 7, and an atom ratio of nitrogen to active bromine greater than 0.93:1 by continuously or intermittently feeding into mixing apparatus separate feed streams of (1) bromine chloride formed in (a), and (2) an aqueous solution of alkali metal salt of sulfamic acid, under automatic feed rate control.
摘要翻译： 该方法包括（a）通过在自动进料速率控制下将所述物流保持在连续成比例以一起形成氯化溴，从溴和氯的不同进料流中连续形成溴氯化物; （b）通过连续或间歇进料连续形成具有至少100,000ppm（wt / wt）的活性溴含量，至少7的pH以及氮与活性溴的原子比大于0.93:1的含水产物 在（a）中形成的（1）溴氯化物的进料流和（2）氨基磺酸的碱金属盐的水溶液中分离进料流，在自动进料速率控制下。
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公开(公告)号：US5281648A
公开(公告)日：1994-01-25
申请号：US923511
申请日：1992-08-03
申请人： David K. Doucet , Janet F. Jones , Susan D. Landry , F. Alexander Pettigrew , Jon S. Reed , James E. Torres
发明人： David K. Doucet , Janet F. Jones , Susan D. Landry , F. Alexander Pettigrew , Jon S. Reed , James E. Torres
CPC分类号： C08J3/226 , C08K5/03 , C08K5/06 , C08K5/18 , C08J2353/02
摘要： The impact strength of articles made from a flame-retarded formulated ABS resin containing an impact modifier is increased by forming a concentrate or masterbatch containing the flame retardant and impact modifier, blending the concentrate with ABS resin and extruding the resultant blend.
摘要翻译： 通过形成含有阻燃剂和抗冲改性剂的浓缩物或母料，将浓缩物与ABS树脂混合并挤出所得的共混物，增加了由含有抗冲改性剂的阻燃配方的ABS树脂制成的制品的冲击强度。
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公开(公告)号：US5218017A
公开(公告)日：1993-06-08
申请号：US744873
申请日：1991-08-14
申请人： David K. Doucet , Janet F. Jones , Susan D. Landry , F. Alexander Pettigrew , Jon S. Reed , James E. Torres
发明人： David K. Doucet , Janet F. Jones , Susan D. Landry , F. Alexander Pettigrew , Jon S. Reed , James E. Torres
CPC分类号： C08J3/226 , C08K5/03 , C08K5/06 , C08K5/18 , C08J2353/02
摘要： The impact strength of a flame retarded formulated ABS resin containing an impact modifier is increased by masterbatching the flame retardant and impact modifier.
摘要翻译： 含有抗冲改性剂的阻燃配方ABS树脂的冲击强度通过母料的阻燃剂和抗冲改性剂的增加而增加。
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