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公开(公告)号：US20110004027A1
公开(公告)日：2011-01-06
申请号：US12595430
申请日：2008-04-11
摘要： A process and apparatus for producing chlorohydrin comprising reacting a multihydroxylated-aliphatic hydrocarbon-containing stream with a stream of a first effluent exiting from a hydrochlorination reactor in at least one vessel wherein the vessel exhibits a plug flow residence time characteristic, under conditions such that at least a portion of any unreacted HCl component present in the first effluent is reacted with the multihydroxylated-aliphatic hydrocarbon present in the multihydroxylated aliphatic hydrogen-containing stream to from an amount of monochlorohydrin in a stream of a second effluent exiting from the plug flow vessel; recovering said second effluent; and then optionally using the second effluent from the plug flow reactor in a subsequent processing operation.
摘要翻译： 一种用于生产氯代醇的方法和装置，包括使多羟基化 - 脂族含烃流与在至少一个容器中从氢氯化反应器排出的第一流出物流反应，其中容器呈现塞流动停留时间特性， 存在于第一流出物中的任何未反应的HCl组分的至少一部分与存在于多羟基化脂族含氢物流中的多羟基化脂族烃与从活塞流容器排出的第二流出物流中的一氯代醇反应; 回收所述第二流出物; 然后在随后的处理操作中任选地使用来自活塞流反应器的第二流出物。
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公开(公告)号：US08541632B2
公开(公告)日：2013-09-24
申请号：US12595430
申请日：2008-04-11
IPC分类号： C07C311/36
摘要： A process and apparatus for producing chlorohydrin comprising reacting a multihydroxylated-aliphatic hydrocarbon-containing stream with a stream of a first effluent exiting from a hydrochlorination reactor in at least one vessel wherein the vessel exhibits a plug flow residence time characteristic, under conditions such that at least a portion of any unreacted HCl component present in the first effluent is reacted with the multihydroxylated-aliphatic hydrocarbon present in the multihydroxylated aliphatic hydrogen-containing stream to from an amount of monochlorohydrin in a stream of a second effluent exiting from the plug flow vessel; recovering said second effluent; and then optionally using the second effluent from the plug flow reactor in a subsequent processing operation.
摘要翻译： 一种用于生产氯代醇的方法和装置，包括使多羟基化 - 脂族含烃流与在至少一个容器中从氢氯化反应器排出的第一流出物流反应，其中容器呈现塞流动停留时间特性， 存在于第一流出物中的任何未反应的HCl组分的至少一部分与存在于多羟基化脂族含氢物流中的多羟基化脂族烃与从活塞流容器排出的第二流出物流中的一氯代醇反应; 回收所述第二流出物; 然后在随后的处理操作中任选地使用来自活塞流反应器的第二流出物。
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3.发明申请PROCESS AND APPARATUS FOR RECOVERY OF DICHLOROHYDRINS VIA CODISTILLATION 失效通过CODISTILLATION恢复二氯乙酸的方法和装置公开(公告)号：US20100137653A1
公开(公告)日：2010-06-03
申请号：US12595500
申请日：2008-04-11
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated-aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising water, chlorinating agents, catalysts and/or esters of catalysts is disclosed. The mixture is stripped to recover dichlorohydrin(s) while distilling or fractionating the mixture to separate a lower boiling fraction comprising dichlorohydrin(s) from the mixture in one step. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, and reduced capital investment in recovery equipment.
摘要翻译： 一种用于从包含二氯代醇，一种或多种选自二氯丙醇，一氯代醇和/或其酯的酯，以及多羟基化脂族烃化合物和/或其酯的化合物和一种或多种包含水的物质的混合物中回收二氯代醇的方法和装置 ，公开了氯化剂，催化剂和/或催化剂的酯。 将混合物汽提以回收二氯丙醇，同时蒸馏或分馏该混合物以在一个步骤中从混合物中分离包含二氯代丙醇的低沸点馏分。 优点包括对于给定的蒸馏塔更有效地回收二氯代醇，由于避免了有利于形成重质副产物的条件而减少浪费，并减少了回收设备的资本投入。
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公开(公告)号：US08629305B2
公开(公告)日：2014-01-14
申请号：US12595493
申请日：2008-04-11
IPC分类号： C07C29/82
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, water, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated-aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising chlorinating agents, catalysts and/or esters of catalysts is disclosed. A liquid aqueous phase is recycled to the distillation column while distilling or fractionating the mixture to separate dichlorohydrin(s) and water from the mixture. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, and reduced capital investment in recovery equipment.
摘要翻译： 一种用于从包含二氯代醇，水，一种或多种选自二氯代醇，一氯代醇和/或其酯的酯和多羟基化脂族烃化合物和/或其酯的化合物的混合物中回收二氯代醇的方法和装置，以及任选的一种或多种物质 公开了氯化剂，催化剂和/或催化剂的酯。 将液体水相再循环到蒸馏塔中，同时蒸馏或分馏该混合物以从该混合物中分离二氯丙醇和水。 优点包括对于给定的蒸馏塔更有效地回收二氯代醇，由于避免了有利于形成重质副产物的条件而减少浪费，并减少了回收设备的资本投入。
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公开(公告)号：US08420870B2
公开(公告)日：2013-04-16
申请号：US12595500
申请日：2008-04-11
IPC分类号： C07C31/36
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated-aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising water, chlorinating agents, catalysts and/or esters of catalysts is disclosed. The mixture is stripped to recover dichlorohydrin(s) while distilling or fractionating the mixture to separate a lower boiling fraction comprising dichlorohydrin(s) from the mixture in one step. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, and reduced capital investment in recovery equipment.
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公开(公告)号：US20100105965A1
公开(公告)日：2010-04-29
申请号：US12595493
申请日：2008-04-11
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, water, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated-aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising chlorinating agents, catalysts and/or esters of catalysts is disclosed. A liquid aqueous phase is recycled to the distillation column while distilling or fractionating the mixture to separate dichlorohydrin(s) and water from the mixture. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, and reduced capital investment in recovery equipment.
摘要翻译： 一种用于从包含二氯代醇，水，一种或多种选自二氯代醇，一氯代醇和/或其酯的酯和多羟基化脂族烃化合物和/或其酯的化合物的混合物中回收二氯代醇的方法和装置，以及任选的一种或多种物质 公开了氯化剂，催化剂和/或催化剂的酯。 将液体水相再循环到蒸馏塔中，同时蒸馏或分馏该混合物以从该混合物中分离二氯丙醇和水。 优点包括对于给定的蒸馏塔更有效地回收二氯代醇，由于避免了有利于形成重质副产物的条件而减少浪费，并减少了回收设备的资本投入。
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7.发明授权Process and apparatus for reducing heavy byproduct formation during distillation 有权用于减少蒸馏期间重副产物形成的方法和装置公开(公告)号：US08334415B2
公开(公告)日：2012-12-18
申请号：US12595468
申请日：2008-04-11
IPC分类号： C07C31/34 , C07D301/02
CPC分类号： C07C29/82 , B01D3/14 , B01D3/146 , B01D3/38 , C07C69/80 , C07C31/36 , C07C31/42 , C07C31/225
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, water, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated-aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising chlorinating agents, catalysts and/or esters of catalysts while minimizing formation of heavies is disclosed.
摘要翻译： 一种用于从包含二氯代醇，水，一种或多种选自二氯代醇，一氯代醇和/或其酯的酯和多羟基化脂族烃化合物和/或其酯的化合物的混合物中回收二氯代醇的方法和装置，以及任选的一种或多种物质 公开了包含氯化剂，催化剂和/或催化剂酯，同时最小化重质物的形成。
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公开(公告)号：US6048513A
公开(公告)日：2000-04-11
申请号：US728811
申请日：1997-01-10
申请人： George J. Quarderer , David L. Trent , Erik J. Stewart , Danil Tirtowidjojo , Anil J. Mehta , Cheryl A. Tirtowidjojo
发明人： George J. Quarderer , David L. Trent , Erik J. Stewart , Danil Tirtowidjojo , Anil J. Mehta , Cheryl A. Tirtowidjojo
CPC分类号： C01B11/04 , B01J19/0066 , B01J19/0073 , B01J19/1806 , B01J2219/00103 , Y02P20/149
摘要： This invention is a method for forming hypohalous acid in a mass transfer device. The method comprises: (1) feeding into the device a stream of caustic solution comprising at least one alkali or alkaline earth metal of a hydroxide, oxide, hypohalite, bicarbonate, or carbonate; (2) feeding a stream comprising halogen gas into the device; (3) reacting at least some of the halogen gas with the caustic solution to form a solution containing hypohalous acid; (4) desorbing the hypohalous acid from the solution and into the stream of halogen gas; and (5) removing the stream of halogen gas from the device. In this method, the mass transfer device comprises a porous rotor which is permeable to the streams, and is rotated about an axis such that the streams flow through the rotor and the stream of caustic solution flows radially outward from the axis.
摘要翻译： 本发明是在传质装置中形成次卤酸的方法。 该方法包括：（1）向装置中加入包含至少一种氢氧化物，氧化物，次卤酸盐，碳酸氢盐或碳酸盐的碱金属或碱土金属的苛性碱溶液; （2）将包含卤素气体的流供给到所述装置中; （3）使至少一些卤素气体与苛性碱溶液反应，形成含有次卤酸的溶液; （4）从溶液中将次卤酸解吸到卤素气流中; 和（5）从装置中除去卤素气流。 在该方法中，传质装置包括可流动的多孔转子，并且绕轴旋转，使得流流过转子，并且苛性碱流从轴线径向向外流动。
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9.发明申请PROCESS AND APPARATUS FOR VAPOR PHASE PURIFICATION DURING HYDROCHLORINATION OF MULTI-HYDROXYLATED ALIPHATIC HYDROCARBON COMPOUNDS 审中-公开多羟基化学烃类化合物氢化过程中蒸汽相纯化的工艺和装置公开(公告)号：US20110152580A1
公开(公告)日：2011-06-23
申请号：US12595488
申请日：2008-04-11
申请人： Bruce D. Hook , Anna Forlin , Andrei S. Merenov , Danil Tirtowidjolo , Anil J. Mehta , Jan W. Verwijs , Aaltje Verwijs-van den Brink , Lena Verwijs , Hendrika Gerrita Verwijs , Wilma Hensen
发明人： Bruce D. Hook , Anna Forlin , Andrei S. Merenov , Danil Tirtowidjolo , Anil J. Mehta , Jan W. Verwijs , Aaltje Verwijs-van den Brink , Lena Verwijs , Hendrika Gerrita Verwijs , Wilma Hensen
摘要： A process for converting multihydroxylated-aliphatic hydrocarbon compound(s) and/or ester(s) thereof to chlorohydrins and/or esters thereof is disclosed in which one or more of multihydroxylated-aliphatic hydrocarbon compound(s) and/or ester(s) thereof and/or monochlorohydrin(s) and/or ester(s) thereof with at least one chlorinating feed stream comprising at least one chlorinating agent and at least one impurity having a boiling point below the boiling point of the chlorohydrin product having the lowest boiling under hydrochlorination conditions, optionally in the presence of water, one or more catalyst(s), and/or one or more heavy byproduct(s) in a reaction vessel under hydrochlorination conditions, wherein the liquid-phase reaction mixture is maintained at a temperature below the boiling point of the chlorohydrin product having the lowest boiling point under hydrochlorination conditions and greater than the boiling point(s) of the at least one impurity and a vapor phase vent stream comprising the at least one impurity is removed from the liquid phase reaction mixture. An apparatus suitable for carrying out the disclosed process is illustrated in FIG. 1 of the drawings. The process and apparatus improve conversion rates and/or provide for recovery of chlorinating agent for lower operating costs.
摘要翻译： 公开了一种将多羟基化脂族烃化合物和/或其酯转化为氯醇和/或其酯的方法，其中一种或多种多羟基化脂族烃化合物和/或酯（一种或多种） 和/或一氯代醇和/或其酯与至少一种氯化进料流一起包含至少一种氯化剂和至少一种沸点低于具有最低沸点的氯代醇产物的沸点的杂质 在氢氯化条件下，任选地在氢氯化条件下在反应容器中存在水，一种或多种催化剂和/或一种或多种重质副产物，其中将液相反应混合物保持在温度 低于氢氯化条件下具有最低沸点的氯代醇产物的沸点并且大于至少一种杂质的沸点和气相排出流c 从液相反应混合物中除去至少一种杂质。 图1中示出了适用于执行所公开的处理的装置。 1图。 该方法和设备提高转化率和/或提供氯化剂的回收以降低运行成本。
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公开(公告)号：US20130204044A1
公开(公告)日：2013-08-08
申请号：US13876388
申请日：2011-09-13
IPC分类号： C07C209/84
CPC分类号： C07C209/84 , C07C211/14
摘要： The present invention provides methods that are used to decolorize compositions containing one or more amines in the presence of one or more weak acids. Significantly, the weak acids, particularly organic acids such as glacial acetic acid, when used in combination with a heat treatment produce dramatically less by-products than do the stronger mineral acids, making heat treatments and subsequent separation techniques more effective while producing less waste. In some modes of practice, the weak acids do not need to be neutralized, eliminating neutralizing steps and waste streams associated with neutralization. Low color products can be obtained easily at very high yield as a consequence.
摘要翻译： 本发明提供了用于在一种或多种弱酸存在下使包含一种或多种胺的组合物脱色的方法。 重要的是，弱酸，特别是有机酸，如冰醋酸，当与热处理相结合使用时，产生的副产物比较强的无机酸显着减少，使热处理和随后的分离技术更有效，同时产生更少的废物。 在某些实践模式中，弱酸不需要中和，消除了与中和相关的中和步骤和废物流。 因此，可以以非常高的产率容易地获得低颜色产品。
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