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公开(公告)号：US20110004027A1
公开(公告)日：2011-01-06
申请号：US12595430
申请日：2008-04-11
摘要： A process and apparatus for producing chlorohydrin comprising reacting a multihydroxylated-aliphatic hydrocarbon-containing stream with a stream of a first effluent exiting from a hydrochlorination reactor in at least one vessel wherein the vessel exhibits a plug flow residence time characteristic, under conditions such that at least a portion of any unreacted HCl component present in the first effluent is reacted with the multihydroxylated-aliphatic hydrocarbon present in the multihydroxylated aliphatic hydrogen-containing stream to from an amount of monochlorohydrin in a stream of a second effluent exiting from the plug flow vessel; recovering said second effluent; and then optionally using the second effluent from the plug flow reactor in a subsequent processing operation.
摘要翻译： 一种用于生产氯代醇的方法和装置，包括使多羟基化 - 脂族含烃流与在至少一个容器中从氢氯化反应器排出的第一流出物流反应，其中容器呈现塞流动停留时间特性， 存在于第一流出物中的任何未反应的HCl组分的至少一部分与存在于多羟基化脂族含氢物流中的多羟基化脂族烃与从活塞流容器排出的第二流出物流中的一氯代醇反应; 回收所述第二流出物; 然后在随后的处理操作中任选地使用来自活塞流反应器的第二流出物。
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公开(公告)号：US08541632B2
公开(公告)日：2013-09-24
申请号：US12595430
申请日：2008-04-11
IPC分类号： C07C311/36
摘要： A process and apparatus for producing chlorohydrin comprising reacting a multihydroxylated-aliphatic hydrocarbon-containing stream with a stream of a first effluent exiting from a hydrochlorination reactor in at least one vessel wherein the vessel exhibits a plug flow residence time characteristic, under conditions such that at least a portion of any unreacted HCl component present in the first effluent is reacted with the multihydroxylated-aliphatic hydrocarbon present in the multihydroxylated aliphatic hydrogen-containing stream to from an amount of monochlorohydrin in a stream of a second effluent exiting from the plug flow vessel; recovering said second effluent; and then optionally using the second effluent from the plug flow reactor in a subsequent processing operation.
摘要翻译： 一种用于生产氯代醇的方法和装置，包括使多羟基化 - 脂族含烃流与在至少一个容器中从氢氯化反应器排出的第一流出物流反应，其中容器呈现塞流动停留时间特性， 存在于第一流出物中的任何未反应的HCl组分的至少一部分与存在于多羟基化脂族含氢物流中的多羟基化脂族烃与从活塞流容器排出的第二流出物流中的一氯代醇反应; 回收所述第二流出物; 然后在随后的处理操作中任选地使用来自活塞流反应器的第二流出物。
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3.发明授权公开(公告)号：US08088957B2
公开(公告)日：2012-01-03
申请号：US11628269
申请日：2005-07-18
申请人： William J. Kruper, Jr. , David J. Schreck , Kenneth L. Kearns , Richard D. Varjian , Mark E. Jones , Robert M. Campbell , Bruce D. Hook , John R. Briggs , Jeffrey G. Hippler
发明人： William J. Kruper, Jr. , David J. Schreck , Kenneth L. Kearns , Richard D. Varjian , Mark E. Jones , Robert M. Campbell , Bruce D. Hook , John R. Briggs , Jeffrey G. Hippler
IPC分类号： C07C31/34
CPC分类号： C07D301/24 , C07C29/62 , C07C29/82 , C07C31/36 , C07C31/42
摘要： The present invention relates to a process for converting a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin, by contacting the multihydroxylated-aliphatic hydrocarbon or ester thereof starting material with a source of a superatmospheric partial pressure of hydrogen chloride for a sufficient time and at a sufficient temperature, and wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts. In addition, certain catalysts of the present invention may be used in the present process at superatmospheric, atmospheric and subatmospheric pressure conditions with improved results.
摘要翻译： 本发明涉及将多羟基化脂肪族烃或其酯转化为氯代醇的方法，该方法是将多羟基化脂族烃或其起始原料与氯化氢的超大气压分压源接触足够的时间和 足够的温度，并且其中这种收缩步骤在不显着除去水的情况下进行，以产生所需的氯代醇产物; 其中所需的产物或产物可以高产率制备而不显着形成不需要的过氯化副产物。 此外，本发明的某些催化剂可以在超大气压，大气压和低于大气压的条件下用于本方法，并具有改进的结果。
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4.发明授权公开(公告)号：US07910781B2
公开(公告)日：2011-03-22
申请号：US11710010
申请日：2007-02-22
申请人： Bruce D. Hook , John Briggs , Robert M. Campbell , William J. Kruper, Jr. , David J. Schreck , Richard D. Varjian , Jeffrey G. Hippler
发明人： Bruce D. Hook , John Briggs , Robert M. Campbell , William J. Kruper, Jr. , David J. Schreck , Richard D. Varjian , Jeffrey G. Hippler
IPC分类号： C07C31/34
CPC分类号： C07D301/27 , C07C29/62 , C07C67/287 , C07C69/003 , C07C69/63 , C07C31/36 , C07C31/42
摘要： A process for converting a crude glycerol, crude mixtures of naturally derived multihydroxylated-aliphatic hydrocarbons or esters thereof to a chlorohydrin, by contacting the crude glycerol, crude mixtures of naturally derived multihydroxylated-aliphatic hydrocarbons or esters thereof starting material with a source of a superatmospheric partial pressure of hydrogen chloride for a sufficient time and at a sufficient temperature, and wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts; wherein said crude glycerol, said ester of crude glycerol, or mixture thereof is derived from a renewable raw material. Chlorohydrins made by the process of the present invention are useful in preparing epoxides such as epichlorohydrins.
摘要翻译： 通过将粗甘油，天然衍生的多羟基化脂肪族烃或其酯的起始原料的粗混合物与超大气压源的原料甘油，天然衍生的多羟基化脂肪族烃或其酯的粗混合物与氯代醇反应， 氯化氢的分压足够的时间和足够的温度，并且其中这种收缩步骤在不基本除去水的情况下进行，以产生所需的氯代醇产物; 其中所需产物或产物可以以高产率制备而不显着形成不需要的过氯化副产物; 其中所述粗甘油，所述粗甘油酯或其混合物衍生自可再生原料。 通过本发明方法制备的氯代醇可用于制备环氧化物如表氯醇。
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5.发明授权公开(公告)号：US08236975B2
公开(公告)日：2012-08-07
申请号：US13023783
申请日：2011-02-09
申请人： Bruce D. Hook , John Briggs , Robert M. Campbell , William J. Kruper , David J. Schreck , Richard D. Varjian , Jeffrey G. Hippler
发明人： Bruce D. Hook , John Briggs , Robert M. Campbell , William J. Kruper , David J. Schreck , Richard D. Varjian , Jeffrey G. Hippler
IPC分类号： C07D301/24
CPC分类号： C07D301/27 , C07C29/62 , C07C67/287 , C07C69/003 , C07C69/63 , C07C31/36 , C07C31/42
摘要： A process for converting a crude glycerol, crude mixtures of naturally derived multihydroxylated-aliphatic hydrocarbons or esters thereof to a chlorohydrin, by contacting the crude glycerol, crude mixtures of naturally derived multihydroxylated-aliphatic hydrocarbons or esters thereof starting material with a source of a superatmospheric partial pressure of hydrogen chloride for a sufficient time and at a sufficient temperature, and wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts; wherein said crude glycerol, said ester of crude glycerol, or mixture thereof is derived from a renewable raw material. Chlorohydrins made by the process of the present invention are useful in preparing epoxides such as epichlorohydrins.
摘要翻译： 通过将粗甘油，天然衍生的多羟基化脂肪族烃或其酯的起始原料的粗混合物与超大气压源的原料甘油，天然衍生的多羟基化脂肪族烃或其酯的粗混合物与氯代醇反应， 氯化氢的分压足够的时间和足够的温度，并且其中这种收缩步骤在不基本除去水的情况下进行，以产生所需的氯代醇产物; 其中所需产物或产物可以以高产率制备而不显着形成不需要的过氯化副产物; 其中所述粗甘油，所述粗甘油酯或其混合物衍生自可再生原料。 通过本发明方法制备的氯代醇可用于制备环氧化物如表氯醇。
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6.发明申请公开(公告)号：US20110178315A1
公开(公告)日：2011-07-21
申请号：US13023783
申请日：2011-02-09
申请人： Bruce D. Hook , John Briggs , Robert M. Campbell , William J. Kruper, JR. , David J. Schreck , Richard D. Varjian , Jeffrey G. Hippler
发明人： Bruce D. Hook , John Briggs , Robert M. Campbell , William J. Kruper, JR. , David J. Schreck , Richard D. Varjian , Jeffrey G. Hippler
IPC分类号： C07D301/02 , C07C31/36
CPC分类号： C07D301/27 , C07C29/62 , C07C67/287 , C07C69/003 , C07C69/63 , C07C31/36 , C07C31/42
摘要： A process for converting a crude glycerol, crude mixtures of naturally derived multihydroxylated-aliphatic hydrocarbons or esters thereof to a chlorohydrin, by contacting the crude glycerol, crude mixtures of naturally derived multihydroxylated-aliphatic hydrocarbons or esters thereof starting material with a source of a superatmospheric partial pressure of hydrogen chloride for a sufficient time and at a sufficient temperature, and wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts; wherein said crude glycerol, said ester of crude glycerol, or mixture thereof is derived from a renewable raw material. Chlorohydrins made by the process of the present invention are useful in preparing epoxides such as epichlorohydrins.
摘要翻译： 通过将粗甘油，天然衍生的多羟基化脂肪族烃或其酯的起始原料的粗混合物与超大气压源的原料甘油，天然衍生的多羟基化脂肪族烃或其酯的粗混合物与氯代醇反应， 氯化氢的分压足够的时间和足够的温度，并且其中这种收缩步骤在不基本除去水的情况下进行，以产生所需的氯代醇产物; 其中所需产物或产物可以以高产率制备而不显着形成不需要的过氯化副产物; 其中所述粗甘油，所述粗甘油酯或其混合物衍生自可再生原料。 通过本发明方法制备的氯代醇可用于制备环氧化物如表氯醇。
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7.发明申请PROCESS FOR MAKING ETHERS FROM ALKOXIDE ANIONS OR PRECURSORS OF ALKOXIDE ANIONS 有权来自烷氧化物阴离子或碱性阴离子前体的制备方法公开(公告)号：US20100280277A1
公开(公告)日：2010-11-04
申请号：US12680022
申请日：2008-09-22
IPC分类号： C07C43/11
摘要： Improved methods for making ethers. In particular, an alkoxide can be more effectively converted into an ether by reaction with a hydrocarbyl halide in the presence of a substantial excess of a hygroscopic base such as NaOH. When present in such an unconventional excess, the base serves multiple functions. As a consequence, the alkoxide is extensively converted to the desired ether rapidly at excellent yields. The reaction environment also aids later product isolation. The use of the NaOH rather than Na metal allows the ether product to be separated from water soluble impurities such as salt products, left over base, left over hydrocarbyl halide, formates, etc. by liquid-liquid extraction among aqueous and organic phases.
摘要翻译： 改进制备醚的方法。 特别地，在大量过量的吸湿性碱如NaOH的存在下，通过与烃基卤化物反应，可以更有效地将醇盐转化为醚。 当这种非常规的超量存在时，该基座具有多种功能。 因此，醇盐以极好的收率快速地转化为所需的醚。 反应环境还有助于后期产品分离。 使用NaOH而不是Na金属允许醚产物与水溶性杂质如盐产物分离，残留在碱，残留在烃基卤化物，甲酸盐等上，通过液相萃取在水相和有机相中。
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8.发明授权Hydroformylation process and product separation with improved recovery of rhodium 有权加氢甲酰化工艺和产物分离，提高铑的回收率公开(公告)号：US07663002B2
公开(公告)日：2010-02-16
申请号：US12299853
申请日：2007-04-17
申请人： Wei-Jun Peng , Kurt D. Olson , Donald L. Morrison , Brian M. Roesch , Donald L. Bunning , Jeffrey G. Hippler , Vincent J. Stricker
发明人： Wei-Jun Peng , Kurt D. Olson , Donald L. Morrison , Brian M. Roesch , Donald L. Bunning , Jeffrey G. Hippler , Vincent J. Stricker
IPC分类号： C07C45/50
CPC分类号： C07C45/80 , C07C45/50 , C07C67/347 , Y02P20/584 , C07C69/738 , C07C69/716 , C07C47/02
摘要： A non-aqueous hydroformylation process with liquid catalyst recycle involving a hydroformylation step and one or more stages of phase separation to recover a high molecular weight aldehyde product with efficient recovery of rhodium catalyst. The process includes a hydroformylation step to prepare a non-aqueous hydroformylation reaction product composition comprising one or more aldehyde products, one or more conjugated polyolefins, a rhodium-organophosphorus ligand complex, free organophosphorus ligand, and an organic solubilizing agent for said complex and said free ligand, and thereafter one or more stages of phase separation using added water under a carbon monoxide gas, hydrogen gas, or a mixture thereof. The process requires a specific range of total pressure for the hydroformylation, a specific range of total pressure for at least one of the separation stages, and a minimum sum of the total pressure of the hydroformylation step and the total pressure of the separation stage containing said gas.
摘要翻译： 具有液体催化剂循环的非水羰基化方法，其涉及加氢甲酰化步骤和一个或多个相分离阶段以回收高分子量醛产物并有效回收铑催化剂。 该方法包括加氢甲酰化步骤，以制备包含一种或多种醛产物，一种或多种共轭聚烯烃，铑 - 有机磷配体络合物，游离有机磷配体和用于所述络合物的有机增溶剂的非水羰基化反应产物组合物和所述 游离配体，然后在一氧化碳气体，氢气或其混合物中使用加入的水进行一个或多个相分离阶段。 该方法需要加氢甲酰化的总压力的特定范围，至少一个分离阶段的总压力的特定范围，以及加氢甲酰化步骤的总压力和含有所述分离阶段的分离阶段的总压力的最小总和 加油站。
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9.发明申请HYDROFORMYLATION PROCESS AND PRODUCT SEPARATION WITH IMPROVED RECOVERY OF RHODIUM 有权氢氧化工艺和产品分离与改进的RHODIUM恢复公开(公告)号：US20090118548A1
公开(公告)日：2009-05-07
申请号：US12299853
申请日：2007-04-17
申请人： Wei-Jun Peng , Kurt D. Olson , Donald L. Morrison , Brian M. Roesch , Donald L. Bunning , Jeffrey G. Hippler , Vincent J. Stricker
发明人： Wei-Jun Peng , Kurt D. Olson , Donald L. Morrison , Brian M. Roesch , Donald L. Bunning , Jeffrey G. Hippler , Vincent J. Stricker
IPC分类号： C07C45/50
CPC分类号： C07C45/80 , C07C45/50 , C07C67/347 , Y02P20/584 , C07C69/738 , C07C69/716 , C07C47/02
摘要： A non-aqueous hydroformylation process with liquid catalyst recycle involving a hydroformylation step and one or more stages of phase separation to recover a high molecular weight aldehyde product with efficient recovery of rhodium catalyst. The process includes a hydroformylation step to prepare a non-aqueous hydroformylation reaction product composition comprising one or more aldehyde products, one or more conjugated polyolefins, a rhodium-organophosphorus ligand complex, free organophosphorus ligand, and an organic solubilizing agent for said complex and said free ligand, and thereafter one or more stages of phase separation using added water under a carbon monoxide gas, hydrogen gas, or a mixture thereof. The process requires a specific range of total pressure for the hydroformylation, a specific range of total pressure for at least one of the separation stages, and a minimum sum of the total pressure of the hydroformylation step and the total pressure of the separation stage containing said gas.
摘要翻译： 具有液体催化剂循环的非水羰基化方法，其涉及加氢甲酰化步骤和一个或多个相分离阶段以回收高分子量醛产物并有效回收铑催化剂。 该方法包括加氢甲酰化步骤，以制备包含一种或多种醛产物，一种或多种共轭聚烯烃，铑 - 有机磷配体络合物，游离有机磷配体和用于所述络合物的有机增溶剂的非水羰基化反应产物组合物和所述 游离配体，然后在一氧化碳气体，氢气或其混合物中使用加入的水进行一个或多个相分离阶段。 该方法需要加氢甲酰化的总压力的特定范围，至少一个分离阶段的总压力的特定范围，以及加氢甲酰化步骤的总压力和含有所述分离阶段的分离阶段的总压力的最小总和 加油站。
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公开(公告)号：US20130274490A1
公开(公告)日：2013-10-17
申请号：US13444827
申请日：2012-04-11
IPC分类号： C11B1/10
摘要： Various embodiments of the present invention are directed to processes and methods for extracting lipids from a variety of algae species. An exemplary method comprises treating the algae with a mixture of at least one nonpolar solvent and at least one polar solvent heated to temperature at which the nonpolar solvent and the polar solvent are miscible.
摘要翻译： 本发明的各种实施方案涉及从各种藻类物种中提取脂质的方法和方法。 一个示例性的方法包括用至少一种非极性溶剂和至少一种加热到非极性溶剂和极性溶剂可混溶的温度的极性溶剂的混合物处理藻类。
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