公开(公告)号：US07282538B2

公开(公告)日：2007-10-16

申请号：US10941626

申请日：2004-09-15

申请人： Anna Zheng ,  Yong Guan ,  Dafu Wei ,  Hong Lu

发明人： Anna Zheng ,  Yong Guan ,  Dafu Wei ,  Hong Lu

IPC分类号： C08L23/36

CPC分类号： C08L27/06 ,  C08F255/00 ,  C08F255/02 ,  C08F257/02 ,  C08F259/04 ,  C08J3/226 ,  C08J2323/02 ,  C08J2423/00 ,  C08L23/10 ,  C08L25/06 ,  C08L33/14 ,  C08L51/06 ,  C08L79/02 ,  C08L2666/02 ,  C09J151/06 ,  Y10T428/1352 ,  C08L2666/24 ,  C08L2666/20

摘要： The present invention belongs to the field of polymerization and processing of polymer and relates to the preparation of a kind of functional polyolefin master batch. The functional master batch is produced by liquid phase, melt phase, or solid phase reaction after mixing the polyolefin resin, polyamine and guanidine salt oligomer, olefin monomer and initiator. The molecular structure of functional polyolefin master batch is shown below: wherein R is a polyamine and guanidine salt oligomer bonded onto polyolefin molecular chain by covalence bond, while S is one selected from hydrogen, chlorine, methyl, or phenyl group.Blending mentioned functional master batch with the corresponding polyolefin, the various antimicrobe products, such as fibers, film, pipe and other plastic articles can be obtained. Besides endowing products with excellent permanent antimicrobe property, it also provides fibers with good-dyeable and antistatic ability and bumpers with easy-paintable ability.

摘要翻译： 本发明属于聚合物的聚合和加工领域，涉及一种功能性聚烯烃母料的制备。 功能性母料在混合聚烯烃树脂，多胺和胍盐低聚物，烯烃单体和引发剂后，通过液相，熔融相或固相反应生产。 功能性聚烯烃母料的分子结构如下所示：其中R是通过共价键键合到聚烯烃分子链上的多胺和胍盐低聚物，而S是选自氢，氯，甲基或苯基的一种。 将功能性母料与相应的聚烯烃混合，可以获得各种抗微生物产品，如纤维，薄膜，管材和其他塑料制品。 除了赋予具有优异永久抗微生物性能的产品外，还提供具有良好耐染和抗静电能力的纤维，并具有易于涂装的能力。

公开(公告)号：US07531225B2

公开(公告)日：2009-05-12

申请号：US11751894

申请日：2007-05-22

申请人： Anna Zheng ,  Yong Guan ,  Dafu Wei ,  Hong Lu

发明人： Anna Zheng ,  Yong Guan ,  Dafu Wei ,  Hong Lu

IPC分类号： C08L23/36 ,  B29D22/00

CPC分类号： C08L27/06 ,  C08F255/00 ,  C08F255/02 ,  C08F257/02 ,  C08F259/04 ,  C08J3/226 ,  C08J2323/02 ,  C08J2423/00 ,  C08L23/10 ,  C08L25/06 ,  C08L33/14 ,  C08L51/06 ,  C08L79/02 ,  C08L2666/02 ,  C09J151/06 ,  Y10T428/1352 ,  C08L2666/24 ,  C08L2666/20

摘要： The present invention belongs to the field of polymerization and processing of polymer and relates to the preparation of a kind of functional polyolefin master batch. The functional master batch is produced by liquid phase, melt phase, or solid phase reaction after mixing the polyolefin resin, polyamine and guanidine salt oligomer, olefin monomer and initiator. The molecular structure of functional polyolefin master batch is shown below: wherein R is a polyamine and guanidine salt oligomer bonded onto polyolefin molecular chain by covalence bond, while S is one selected from hydrogen, chlorine, methyl, or phenyl group. Blending mentioned functional master batch with the corresponding polyolefin, the various antimicrobe products, such as fibers, film, pipe and other plastic articles can be obtained. Besides endowing products with excellent permanent antimicrobe property, it also provides fibers with good-dyeable and antistatic ability and bumpers with easy-paintable ability.

摘要翻译： 本发明属于聚合物的聚合和加工领域，涉及一种功能性聚烯烃母料的制备。 功能性母料在混合聚烯烃树脂，多胺和胍盐低聚物，烯烃单体和引发剂后，通过液相，熔融相或固相反应生产。 功能性聚烯烃母料的分子结构如下所示：其中R是通过共价键键合到聚烯烃分子链上的多胺和胍盐低聚物，而S是选自氢，氯，甲基或苯基的一种。 将功能性母料与相应的聚烯烃混合，可以获得各种抗微生物产品，如纤维，薄膜，管材和其他塑料制品。 除了赋予具有优异永久抗微生物性能的产品外，还提供具有良好耐染和抗静电能力的纤维，并具有易于涂装的能力。

公开(公告)号：US20070270552A1

公开(公告)日：2007-11-22

申请号：US11751894

申请日：2007-05-22

申请人： Anna Zheng ,  Yong Guan ,  Dafu Wei ,  Hong Lu

发明人： Anna Zheng ,  Yong Guan ,  Dafu Wei ,  Hong Lu

IPC分类号： C08F136/14

CPC分类号： C08L27/06 ,  C08F255/00 ,  C08F255/02 ,  C08F257/02 ,  C08F259/04 ,  C08J3/226 ,  C08J2323/02 ,  C08J2423/00 ,  C08L23/10 ,  C08L25/06 ,  C08L33/14 ,  C08L51/06 ,  C08L79/02 ,  C08L2666/02 ,  C09J151/06 ,  Y10T428/1352 ,  C08L2666/24 ,  C08L2666/20

摘要： The present invention belongs to the field of polymerization and processing of polymer and relates to the preparation of a kind of functional polyolefin master batch. The functional master batch is produced by liquid phase, melt phase, or solid phase reaction after mixing the polyolefin resin, polyamine and guanidine salt oligomer, olefin monomer and initiator. The molecular structure of functional polyolefin master batch is shown below: wherein R is a polyamine and guanidine salt oligomer bonded onto polyolefin molecular chain by covalence bond, while S is one selected from hydrogen, chlorine, methyl, or phenyl group. Blending mentioned functional master batch with the corresponding polyolefin, the various antimicrobe products, such as fibers, film, pipe and other plastic articles can be obtained. Besides endowing products with excellent permanent antimicrobe property, it also provides fibers with good-dyeable and antistatic ability and bumpers with easy-paintable ability.

摘要翻译： 本发明属于聚合物的聚合和加工领域，涉及一种功能性聚烯烃母料的制备。 功能性母料在混合聚烯烃树脂，多胺和胍盐低聚物，烯烃单体和引发剂后，通过液相，熔融相或固相反应生产。 功能性聚烯烃母料的分子结构如下所示：其中R是通过共价键键合到聚烯烃分子链上的多胺和胍盐低聚物，而S是选自氢，氯，甲基或苯基的一种。 将功能性母料与相应的聚烯烃混合，可以获得各种抗微生物产品，如纤维，薄膜，管材和其他塑料制品。 除了赋予具有优异永久抗微生物性能的产品外，还提供具有良好耐染和抗静电能力的纤维，并具有易于涂装的能力。

公开(公告)号：US20050133952A1

公开(公告)日：2005-06-23

申请号：US10941626

申请日：2004-09-15

申请人： Anna Zheng ,  Yong Guan ,  Dafu Wei ,  Hong Lu

发明人： Anna Zheng ,  Yong Guan ,  Dafu Wei ,  Hong Lu

IPC分类号： C08L23/36 ,  C08F8/30 ,  C08F255/00 ,  C08F255/02 ,  C08F257/02 ,  C08F259/04 ,  C08L23/10 ,  C08L33/14 ,  C08L51/06 ,  C08L79/02 ,  C08L101/00 ,  C09J151/06 ,  B29C47/38 ,  B29C47/60

CPC分类号： C08L27/06 ,  C08F255/00 ,  C08F255/02 ,  C08F257/02 ,  C08F259/04 ,  C08J3/226 ,  C08J2323/02 ,  C08J2423/00 ,  C08L23/10 ,  C08L25/06 ,  C08L33/14 ,  C08L51/06 ,  C08L79/02 ,  C08L2666/02 ,  C09J151/06 ,  Y10T428/1352 ,  C08L2666/24 ,  C08L2666/20

摘要： The present invention belongs to the field of polymerization and processing of polymer and relates to the preparation of a kind of functional polyolefin master batch. The functional master batch is produced by liquid phase, melt phase, or solid phase reaction after mixing the polyolefin resin, polyamine and guanidine salt oligomer, olefin monomer and initiator. The molecular structure of functional polyolefin master batch is shown below: wherein R is a polyamine and guanidine salt oligomer bonded onto polyolefin molecular chain by covalence bond, while S is one selected from hydrogen, chlorine, methyl, or phenyl group. Blending mentioned functional master batch with the corresponding polyolefin, the various antimicrobe products, such as fibers, film, pipe and other plastic articles can be obtained. Besides endowing products with excellent permanent antimicrobe property, it also provides fibers with good-dyeable and antistatic ability and bumpers with easy-paintable ability.

摘要翻译： 本发明属于聚合物的聚合和加工领域，涉及一种功能性聚烯烃母料的制备。 功能性母料在混合聚烯烃树脂，多胺和胍盐低聚物，烯烃单体和引发剂后，通过液相，熔融相或固相反应生产。 功能性聚烯烃母料的分子结构如下所示：其中R是通过共价键键合到聚烯烃分子链上的多胺和胍盐低聚物，而S是选自氢，氯，甲基或苯基的一种。 将功能性母料与相应的聚烯烃混合，可以获得各种抗微生物产品，如纤维，薄膜，管材和其他塑料制品。 除了赋予具有优异永久抗微生物性能的产品外，还提供具有良好耐染和抗静电能力的纤维，并具有易于涂装的能力。

公开(公告)号：US08546503B2

公开(公告)日：2013-10-01

申请号：US13145868

申请日：2009-01-24

申请人： Anna Zheng ,  Jian Zhang ,  Yong Guan ,  Fuzeng Hu ,  Dafu Wei ,  Shuzhong Wang

发明人： Anna Zheng ,  Jian Zhang ,  Yong Guan ,  Fuzeng Hu ,  Dafu Wei ,  Shuzhong Wang

IPC分类号： C08F2/00 ,  C08F112/08 ,  C08F4/00

CPC分类号： C08F2/38 ,  C08F297/02

摘要： This invention deals with an approach to control anionic polymerization. The anionic polymerization is conducted by adding a kind of initiator ligand compound, directly or in the form of solution into the monomer or initiator at the same or different time, or at different stages. The metal atoms in the ligand can form the association with the initiator cations, while the alkyloxy groups in the initiator ligand can restrict the entering channel of the addition of the monomers due to their relatively large volume or steric hindrance. Therefore, the initiator ligand compound can restrict the rate of anionic polymerization, restrain the side reaction, and make the anionic polymerization possible to be conducted at room or even higher temperature. The molar ratio of initiator ligand compound to initiator is from 0.01:1 to 20:1. Compared with present technologies, the method of this invention can control and adjust the homopolymerization and copolymerization rate, side reactions and the polymerization temperature, and make it possible to industrialize.

摘要翻译： 本发明涉及一种控制阴离子聚合的方法。 阴离子聚合通过在相同或不同的时间或不同阶段直接或以溶液的形式加入到单体或引发剂中进行一种引发剂配体化合物进行。 配体中的金属原子可以与引发剂阳离子形成缔合，而引发剂配体中的烷氧基可能由于其相对较大的体积或空间位阻而限制加入单体的进入通道。 因此，引发剂配体化合物可以限制阴离子聚合速度，抑制副反应，并且可以在室温甚至更高温度下进行阴离子聚合。 引发剂配体化合物与引发剂的摩尔比为0.01：1至20：1。 与现有技术相比，本发明的方法可以控制和调节均聚和共聚速率，副反应和聚合温度，并使其成为可能。

公开(公告)号：US20120116023A1

公开(公告)日：2012-05-10

申请号：US13145868

申请日：2009-01-24

申请人： Anna Zheng ,  Jian Zhang ,  Yong Guan ,  Fuzeng Hu ,  Dafu Wei ,  Shuzhong Wang

发明人： Anna Zheng ,  Jian Zhang ,  Yong Guan ,  Fuzeng Hu ,  Dafu Wei ,  Shuzhong Wang

IPC分类号： C08F2/06 ,  C08F2/02 ,  C08F12/08 ,  C08F20/14 ,  C08F299/00

CPC分类号： C08F2/38 ,  C08F297/02

摘要： This invention deals with an approach to control anionic polymerization. The anionic polymerization is conducted by adding a kind of initiator ligand compound, directly or in the form of solution into the monomer or initiator at the same or different time, or at different stages. The metal atoms in the ligand can form the association with the initiator cations, while the alkyloxy groups in the intiator ligand can restrict the entering channel of the addition of the monomers due to their relatively large volume or steric hindrance. Therfore, the initiator ligand compound can restrict the rate of anionic polymerization, restrain the side reaction, and make the anionic polymerization possible to be conducted at room or even higher temperature.The molar ratio of initiator ligand compound to initiator is from 0.01:1 to 20:1. Compared with present technologies, the method of this invention can control and adjust the homopolymerization and copolymerization rate, side reactions and the polymerization temperature, and make it possible to industrialize.

摘要翻译： 本发明涉及一种控制阴离子聚合的方法。 阴离子聚合通过在相同或不同的时间或不同阶段直接或以溶液的形式加入到单体或引发剂中进行一种引发剂配体化合物进行。 配体中的金属原子可以与引发剂阳离子形成缔合，而配体配位体中的烷氧基可能由于其相对较大的体积或空间位阻而限制加入单体的进入通道。 因此，引发剂配体化合物可以限制阴离子聚合的速率，抑制副反应，并且可以在室温甚至更高的温度下进行阴离子聚合。 引发剂配体化合物与引发剂的摩尔比为0.01：1至20：1。 与现有技术相比，本发明的方法可以控制和调节均聚和共聚速率，副反应和聚合温度，并使其成为可能。