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公开(公告)号：US20120029247A1
公开(公告)日：2012-02-02
申请号：US12676831
申请日：2008-09-03
摘要： A process is described for the preparation of water-soluble cellulose hydrolysis products, which comprises admixing cellulose with an ionic liquid capable of solvating or dissolving at least some of the cellulose, said ionic liquid being a compound comprised solely of cations and anions and which exists in a liquid state at a temperature at or below 15O° C., the cations in said ionic liquid having the general formula (I), in which Z represents a nitrogen or phosphorus atom, R1 represents a methyl or ethyl group, each of R2 and R3, which may be the same or different, is selected from C4-3alkyl, optionally-substituted benzyl, optionally-substituted phenyl, and C5-7 cycloalkyl, and R4 represents C1-8 alkyl, optionally-substituted benzyl, optionally-substituted phenyl or C5-7cyclohexyl; in which the optional substituents on a benzyl or phenyl ring are one, two or three substituents selected from C1-4alkyl or alkoxy groups, halogen atoms and nitro groups; and treating the resulting solvate or solution with an acid in the presence of water, said acid having a pKa in water of less than 2 at 25° C.
摘要翻译： 描述了用于制备水溶性纤维素水解产物的方法，其包括将纤维素与能够溶解或溶解至少一些纤维素的离子液体混合，所述离子液体是仅由阳离子和阴离子组成的化合物，其存在 在等于或低于150℃的液态下，具有通式（I）的所述离子液体中的阳离子，其中Z表示氮或磷原子，R1表示甲基或乙基，R2各自表示 和可以相同或不同的R 3选自C 4-3烷基，任选取代的苄基，任选取代的苯基和C 5-7环烷基，R 4表示C 1-8烷基，任选取代的苄基，任选取代的 苯基或C 5-7环己基; 其中苄基或苯环上的任选取代基是选自C 1-4烷基或烷氧基，卤素原子和硝基的一个，两个或三个取代基; 并在酸存在下用酸处理得到的溶剂合物或溶液，所述酸在25℃下的水中pKa小于2。
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2.发明授权Preparation method of functional master batch of polyolefin and its application 有权功能性母料聚烯烃的制备方法及其应用公开(公告)号：US07282538B2
公开(公告)日：2007-10-16
申请号：US10941626
申请日：2004-09-15
申请人： Anna Zheng , Yong Guan , Dafu Wei , Hong Lu
发明人： Anna Zheng , Yong Guan , Dafu Wei , Hong Lu
IPC分类号： C08L23/36
CPC分类号： C08L27/06 , C08F255/00 , C08F255/02 , C08F257/02 , C08F259/04 , C08J3/226 , C08J2323/02 , C08J2423/00 , C08L23/10 , C08L25/06 , C08L33/14 , C08L51/06 , C08L79/02 , C08L2666/02 , C09J151/06 , Y10T428/1352 , C08L2666/24 , C08L2666/20
摘要： The present invention belongs to the field of polymerization and processing of polymer and relates to the preparation of a kind of functional polyolefin master batch. The functional master batch is produced by liquid phase, melt phase, or solid phase reaction after mixing the polyolefin resin, polyamine and guanidine salt oligomer, olefin monomer and initiator. The molecular structure of functional polyolefin master batch is shown below: wherein R is a polyamine and guanidine salt oligomer bonded onto polyolefin molecular chain by covalence bond, while S is one selected from hydrogen, chlorine, methyl, or phenyl group.Blending mentioned functional master batch with the corresponding polyolefin, the various antimicrobe products, such as fibers, film, pipe and other plastic articles can be obtained. Besides endowing products with excellent permanent antimicrobe property, it also provides fibers with good-dyeable and antistatic ability and bumpers with easy-paintable ability.
摘要翻译： 本发明属于聚合物的聚合和加工领域，涉及一种功能性聚烯烃母料的制备。 功能性母料在混合聚烯烃树脂，多胺和胍盐低聚物，烯烃单体和引发剂后，通过液相，熔融相或固相反应生产。 功能性聚烯烃母料的分子结构如下所示：其中R是通过共价键键合到聚烯烃分子链上的多胺和胍盐低聚物，而S是选自氢，氯，甲基或苯基的一种。 将功能性母料与相应的聚烯烃混合，可以获得各种抗微生物产品，如纤维，薄膜，管材和其他塑料制品。 除了赋予具有优异永久抗微生物性能的产品外，还提供具有良好耐染和抗静电能力的纤维，并具有易于涂装的能力。
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公开(公告)号：US11172868B2
公开(公告)日：2021-11-16
申请号：US16041084
申请日：2018-07-20
申请人： Yi Zheng , Anna Zheng , Qi Wu , Hui Jiang , Shun Zhang , Weining Hu
发明人： Yi Zheng , Anna Zheng , Qi Wu , Hui Jiang , Shun Zhang , Weining Hu
摘要： A system and method to screen for malignant gliomas, other brain tumors, and brain injuries use disturbance coefficient, differential impedances, and artificial neural networks. The system uses prescribed excitation signals with several system configurations to measure the differential impedances, calculate harmonic responses and nonlinearity of brain tissue, and estimate the disturbance coefficient that indicates the likelihood of malignant gliomas, other brain tumors, and brain injuries. The disturbance coefficient is a weighted sum of many parameters such as receiving differential impedances, transmission differential impedances, harmonic responses, frequency dispersion, and nonlinear responses using different system configurations and different excitation signals. The method includes arranging the transmitters, receivers, and transmission lines to maximize the sensitivity of detecting brain tissue condition. The artificial neural network is trained to estimate the disturbance coefficient using clinical data. The method provides a sensitive and cost effective approach for screening malignant gliomas, other brain tumors, and brain injuries.
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公开(公告)号：US20190021647A1
公开(公告)日：2019-01-24
申请号：US16041084
申请日：2018-07-20
申请人： Yi Zheng , Anna Zheng , Qi Wu , Hui Jiang , Shun Zhang , Weining Hu
发明人： Yi Zheng , Anna Zheng , Qi Wu , Hui Jiang , Shun Zhang , Weining Hu
摘要： A system and method to screen for malignant gliomas, other brain tumors, and brain injuries use disturbance coefficient, differential impedances, and artificial neural networks. The system uses prescribed excitation signals with several system configurations to measure the differential impedances, calculate harmonic responses and nonlinearity of brain tissue, and estimate the disturbance coefficient that indicates the likelihood of malignant gliomas, other brain tumors, and brain injuries. The disturbance coefficient is a weighted sum of many parameters such as receiving differential impedances, transmission differential impedances, harmonic responses, frequency dispersion, and nonlinear responses using different system configurations and different excitation signals. The method includes arranging the transmitters, receivers, and transmission lines to maximize the sensitivity of detecting brain tissue condition. The artificial neural network is trained to estimate the disturbance coefficient using clinical data. The method provides a sensitive and cost effective approach for screening malignant gliomas, other brain tumors, and brain injuries.
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公开(公告)号：US08721795B2
公开(公告)日：2014-05-13
申请号：US12676824
申请日：2008-09-03
IPC分类号： C13K1/02
摘要： A process is described for the preparation of water-soluble cellulose hydrolysis products The process comprises admixing cellulose with an ionic liquid capable of solvating or dissolving at least some of the cellulose, said ionic liquid being a compound comprised solely of cations and anions and which exists in a liquid state at a temperature at or below 150° C., and in which the anions are selected from sulfate, hydrogen sulfate and nitrate; and treating the resulting solvate or solution with an acid in the presence of water, said acid having a pKa in water of less than 2 at 25° C.
摘要翻译： 描述了用于制备水溶性纤维素水解产物的方法。该方法包括将纤维素与能够溶解或溶解至少一些纤维素的离子液体混合，所述离子液体是仅由阳离子和阴离子组成的化合物，其存在 在等温或低于150℃的液态下，其中阴离子选自硫酸盐，硫酸氢盐和硝酸盐; 并在酸存在下用酸处理得到的溶剂合物或溶液，所述酸在25℃下的水中pKa小于2。
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公开(公告)号：US08546503B2
公开(公告)日：2013-10-01
申请号：US13145868
申请日：2009-01-24
申请人： Anna Zheng , Jian Zhang , Yong Guan , Fuzeng Hu , Dafu Wei , Shuzhong Wang
发明人： Anna Zheng , Jian Zhang , Yong Guan , Fuzeng Hu , Dafu Wei , Shuzhong Wang
IPC分类号： C08F2/00 , C08F112/08 , C08F4/00
CPC分类号： C08F2/38 , C08F297/02
摘要： This invention deals with an approach to control anionic polymerization. The anionic polymerization is conducted by adding a kind of initiator ligand compound, directly or in the form of solution into the monomer or initiator at the same or different time, or at different stages. The metal atoms in the ligand can form the association with the initiator cations, while the alkyloxy groups in the initiator ligand can restrict the entering channel of the addition of the monomers due to their relatively large volume or steric hindrance. Therefore, the initiator ligand compound can restrict the rate of anionic polymerization, restrain the side reaction, and make the anionic polymerization possible to be conducted at room or even higher temperature. The molar ratio of initiator ligand compound to initiator is from 0.01:1 to 20:1. Compared with present technologies, the method of this invention can control and adjust the homopolymerization and copolymerization rate, side reactions and the polymerization temperature, and make it possible to industrialize.
摘要翻译： 本发明涉及一种控制阴离子聚合的方法。 阴离子聚合通过在相同或不同的时间或不同阶段直接或以溶液的形式加入到单体或引发剂中进行一种引发剂配体化合物进行。 配体中的金属原子可以与引发剂阳离子形成缔合，而引发剂配体中的烷氧基可能由于其相对较大的体积或空间位阻而限制加入单体的进入通道。 因此，引发剂配体化合物可以限制阴离子聚合速度，抑制副反应，并且可以在室温甚至更高温度下进行阴离子聚合。 引发剂配体化合物与引发剂的摩尔比为0.01：1至20：1。 与现有技术相比，本发明的方法可以控制和调节均聚和共聚速率，副反应和聚合温度，并使其成为可能。
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公开(公告)号：US20120116023A1
公开(公告)日：2012-05-10
申请号：US13145868
申请日：2009-01-24
申请人： Anna Zheng , Jian Zhang , Yong Guan , Fuzeng Hu , Dafu Wei , Shuzhong Wang
发明人： Anna Zheng , Jian Zhang , Yong Guan , Fuzeng Hu , Dafu Wei , Shuzhong Wang
IPC分类号： C08F2/06 , C08F2/02 , C08F12/08 , C08F20/14 , C08F299/00
CPC分类号： C08F2/38 , C08F297/02
摘要： This invention deals with an approach to control anionic polymerization. The anionic polymerization is conducted by adding a kind of initiator ligand compound, directly or in the form of solution into the monomer or initiator at the same or different time, or at different stages. The metal atoms in the ligand can form the association with the initiator cations, while the alkyloxy groups in the intiator ligand can restrict the entering channel of the addition of the monomers due to their relatively large volume or steric hindrance. Therfore, the initiator ligand compound can restrict the rate of anionic polymerization, restrain the side reaction, and make the anionic polymerization possible to be conducted at room or even higher temperature.The molar ratio of initiator ligand compound to initiator is from 0.01:1 to 20:1. Compared with present technologies, the method of this invention can control and adjust the homopolymerization and copolymerization rate, side reactions and the polymerization temperature, and make it possible to industrialize.
摘要翻译： 本发明涉及一种控制阴离子聚合的方法。 阴离子聚合通过在相同或不同的时间或不同阶段直接或以溶液的形式加入到单体或引发剂中进行一种引发剂配体化合物进行。 配体中的金属原子可以与引发剂阳离子形成缔合，而配体配位体中的烷氧基可能由于其相对较大的体积或空间位阻而限制加入单体的进入通道。 因此，引发剂配体化合物可以限制阴离子聚合的速率，抑制副反应，并且可以在室温甚至更高的温度下进行阴离子聚合。 引发剂配体化合物与引发剂的摩尔比为0.01：1至20：1。 与现有技术相比，本发明的方法可以控制和调节均聚和共聚速率，副反应和聚合温度，并使其成为可能。
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8.发明申请PREPARATION METHOD OF FUNCTIONAL MASTER BATCH OF POLYOLEFIN AND ITS APPLICATION 有权聚烯烃功能主要批料的制备方法及其应用公开(公告)号：US20070270552A1
公开(公告)日：2007-11-22
申请号：US11751894
申请日：2007-05-22
申请人： Anna Zheng , Yong Guan , Dafu Wei , Hong Lu
发明人： Anna Zheng , Yong Guan , Dafu Wei , Hong Lu
IPC分类号： C08F136/14
CPC分类号： C08L27/06 , C08F255/00 , C08F255/02 , C08F257/02 , C08F259/04 , C08J3/226 , C08J2323/02 , C08J2423/00 , C08L23/10 , C08L25/06 , C08L33/14 , C08L51/06 , C08L79/02 , C08L2666/02 , C09J151/06 , Y10T428/1352 , C08L2666/24 , C08L2666/20
摘要： The present invention belongs to the field of polymerization and processing of polymer and relates to the preparation of a kind of functional polyolefin master batch. The functional master batch is produced by liquid phase, melt phase, or solid phase reaction after mixing the polyolefin resin, polyamine and guanidine salt oligomer, olefin monomer and initiator. The molecular structure of functional polyolefin master batch is shown below: wherein R is a polyamine and guanidine salt oligomer bonded onto polyolefin molecular chain by covalence bond, while S is one selected from hydrogen, chlorine, methyl, or phenyl group. Blending mentioned functional master batch with the corresponding polyolefin, the various antimicrobe products, such as fibers, film, pipe and other plastic articles can be obtained. Besides endowing products with excellent permanent antimicrobe property, it also provides fibers with good-dyeable and antistatic ability and bumpers with easy-paintable ability.
摘要翻译： 本发明属于聚合物的聚合和加工领域，涉及一种功能性聚烯烃母料的制备。 功能性母料在混合聚烯烃树脂，多胺和胍盐低聚物，烯烃单体和引发剂后，通过液相，熔融相或固相反应生产。 功能性聚烯烃母料的分子结构如下所示：其中R是通过共价键键合到聚烯烃分子链上的多胺和胍盐低聚物，而S是选自氢，氯，甲基或苯基的一种。 将功能性母料与相应的聚烯烃混合，可以获得各种抗微生物产品，如纤维，薄膜，管材和其他塑料制品。 除了赋予具有优异永久抗微生物性能的产品外，还提供具有良好耐染和抗静电能力的纤维，并具有易于涂装的能力。
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9.发明申请Preparation method of functional master batch of polyolefin and its application 有权功能性母料聚烯烃的制备方法及其应用公开(公告)号：US20050133952A1
公开(公告)日：2005-06-23
申请号：US10941626
申请日：2004-09-15
申请人： Anna Zheng , Yong Guan , Dafu Wei , Hong Lu
发明人： Anna Zheng , Yong Guan , Dafu Wei , Hong Lu
IPC分类号： C08L23/36 , C08F8/30 , C08F255/00 , C08F255/02 , C08F257/02 , C08F259/04 , C08L23/10 , C08L33/14 , C08L51/06 , C08L79/02 , C08L101/00 , C09J151/06 , B29C47/38 , B29C47/60
CPC分类号： C08L27/06 , C08F255/00 , C08F255/02 , C08F257/02 , C08F259/04 , C08J3/226 , C08J2323/02 , C08J2423/00 , C08L23/10 , C08L25/06 , C08L33/14 , C08L51/06 , C08L79/02 , C08L2666/02 , C09J151/06 , Y10T428/1352 , C08L2666/24 , C08L2666/20
摘要： The present invention belongs to the field of polymerization and processing of polymer and relates to the preparation of a kind of functional polyolefin master batch. The functional master batch is produced by liquid phase, melt phase, or solid phase reaction after mixing the polyolefin resin, polyamine and guanidine salt oligomer, olefin monomer and initiator. The molecular structure of functional polyolefin master batch is shown below: wherein R is a polyamine and guanidine salt oligomer bonded onto polyolefin molecular chain by covalence bond, while S is one selected from hydrogen, chlorine, methyl, or phenyl group. Blending mentioned functional master batch with the corresponding polyolefin, the various antimicrobe products, such as fibers, film, pipe and other plastic articles can be obtained. Besides endowing products with excellent permanent antimicrobe property, it also provides fibers with good-dyeable and antistatic ability and bumpers with easy-paintable ability.
摘要翻译： 本发明属于聚合物的聚合和加工领域，涉及一种功能性聚烯烃母料的制备。 功能性母料在混合聚烯烃树脂，多胺和胍盐低聚物，烯烃单体和引发剂后，通过液相，熔融相或固相反应生产。 功能性聚烯烃母料的分子结构如下所示：其中R是通过共价键键合到聚烯烃分子链上的多胺和胍盐低聚物，而S是选自氢，氯，甲基或苯基的一种。 将功能性母料与相应的聚烯烃混合，可以获得各种抗微生物产品，如纤维，薄膜，管材和其他塑料制品。 除了赋予具有优异永久抗微生物性能的产品外，还提供具有良好耐染和抗静电能力的纤维，并具有易于涂装的能力。
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公开(公告)号：US20110312048A1
公开(公告)日：2011-12-22
申请号：US12676824
申请日：2008-09-03
摘要： A process is described for the preparation of water-soluble cellulose hydrolysis products The process comprises admixing cellulose with an ionic liquid capable of solvating or dissolving at least some of the cellulose, said ionic liquid being a compound comprised solely of cations and anions and which exists in a liquid state at a temperature at or below 15O° C., and in which the anions are selected from sulfate, hydrogen sulfate and nitrate; and treating the resulting solvate or solution with an acid in the presence of water, said acid having a pKa in water of less than 2 at 25° C.
摘要翻译： 描述了用于制备水溶性纤维素水解产物的方法。该方法包括将纤维素与能够溶解或溶解至少一些纤维素的离子液体混合，所述离子液体是仅由阳离子和阴离子组成的化合物，其存在 在等于或低于150℃的温度下处于液态，其中阴离子选自硫酸根，硫酸氢根和硝酸根; 并在酸存在下用酸处理得到的溶剂合物或溶液，所述酸在25℃下的水中pKa小于2。
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