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公开(公告)号：US11344654B2
公开(公告)日：2022-05-31
申请号：US16869677
申请日：2020-05-08
Applicant: Arkema France
Inventor： Rene-Paul Eustache , Frederic Malet , Eric Gamache , Alejandra Reyna-Valencia , Damien Rauline
Abstract: The present invention relates to the use of a copolymer containing polyether blocks and polyamide blocks for manufacturing an inflatable catheter element, such as a catheter balloon, with improved bursting strength, in which said copolymer has the following characteristics: a number-average molecular mass of the PE blocks greater than 500 g/mol, and a number-average molecular mass of the PA blocks greater than 10,000 g/mol.
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公开(公告)号：US10316127B2
公开(公告)日：2019-06-11
申请号：US15527406
申请日：2015-11-24
Applicant: Arkema France
Inventor： Christophe Navarro , Aline O. Couffin , Rosangela Pirri , Frederic Malet
IPC: C08L67/00 , C08F279/06 , C08F279/02 , C08L51/04
Abstract: The present invention relates to a multistage polymer, its composition, its process of preparation, and its use as impact modifier in thermoplastic compositions. More particularly the present invention relates to a process for manufacturing a polymer composition comprising a multistage polymer and its use as impact modifier in thermoplastic compositions.
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3.发明申请COPOLYMERS COMPRISING POLYAMIDE BLOCKS AND POLYETHER BLOCKS AND HAVING IMPROVED MECHANICAL PROPERTIES 有权包含聚酰胺块和聚醚嵌段并具有改进的机械性能的共聚物公开(公告)号：US20130296502A1
公开(公告)日：2013-11-07
申请号：US13859380
申请日：2013-04-09
Applicant: Arkema France
Inventor： Frederic Malet
IPC: C08G81/00
CPC classification number: C08G81/00 , C08G69/40 , Y10T428/139 , Y10T428/249921
Abstract: The invention relates to a process for producing a shaped article having excellent mechanical properties, said article comprising a block copolymer PAX.Y/PE comprising polyamide (PA) blocks alternating with polyether (PE) blocks, prepared from homopolyamide blocks PAX.Y by polycondenstation of linear aliphatic diamines where PAX.Y is selected from the group consisting of PA 10,12; PA 6,18; PA 10,14; and PA 12.12, reacted with polyether PE blocks in the presence of a catalyst to produce a block copolymer PAX.Y/PE, wherein said PE blocks are either PE diols, or PE blocks comprising NH2 ends. The articles formed are either a fabric, film, sheet, rod, pipe, injection-molded component, or a shoe sole; the copolymer PAX.Y/PE has an improved flexural modulus of at least 300 MPa greater than a copolymer polyamide 12/polytetrametylene with the same size of PA block and with the same size of PE block respectively.
Abstract translation: 本发明涉及一种具有优异机械性能的成型制品的制造方法，所述制品包含嵌段共聚物PAX.Y / PE，其包含与聚醚（PA）嵌段交替的聚酰胺嵌段（PE）嵌段，其由均聚酰胺嵌段PAX.Y通过缩聚 的线性脂族二胺，其中PAX.Y选自PA10,12; PA 6,18; PA 10,14; 和PA12.12在催化剂存在下与聚醚PE嵌段反应生成嵌段共聚物PAX.Y / PE，其中所述PE嵌段是PE二醇或包含NH 2端的PE嵌段。 形成的制品是织物，薄膜，片材，棒材，管材，注射成型部件或鞋底; 共聚物PAX.Y / PE具有比具有相同尺寸的PA嵌段和相同尺寸的PE嵌段的共聚物聚酰胺12 /聚四亚甲基具有至少300MPa的改进的弯曲模量。
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公开(公告)号：US10759939B2
公开(公告)日：2020-09-01
申请号：US15523448
申请日：2015-11-04
Applicant: Arkema France
Inventor： Frederic Malet
Abstract: The present invention relates to an impact modified polyamide composition. In particular, the present invention relates to impact modified transparent polyamide compositions comprising a multistage polymer. More particularly, the present invention relates to the use of multistage polymer as impact modifier in a transparent polyamide composition.
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Patent Agency Ranking
公开(公告)号：US20190062545A1
公开(公告)日：2019-02-28
申请号：US16113258
申请日：2018-08-27
Applicant: ARKEMA FRANCE
Inventor： Laure BERDIN , Damien Rauline , Karine LOYEN , Frederic Malet
Abstract: A transparent antistatic composition based on polymethyl methacrylate (PMMA), including: 55% to 99.9% by weight of PMMA, and 0.1% to 45% by weight of at least one polyamide (PA) block-containing and polyether (PE) block-containing copolymer (PEBA) inlcuding polyethylene glycol (PEG), with respect to the total composition weight, said copolymer being characterized in that it includes in the range 50% to 80% by weight of PEG with respect to the total weight of copolymer.
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公开(公告)号：US09809683B2
公开(公告)日：2017-11-07
申请号：US15027603
申请日：2014-10-06
Applicant: Arkema France
Inventor： Frederic Malet
Abstract: The invention relates to a copolymer comprising at least two distinct polyamide blocks and at least one polyether block, and a method for preparation of said copolymer comprising the following steps: —in a first step, the polyamide block PA1 is prepared by polycondensation of chosen monomers: amino acids, lactames or diamines and dicarboxylic acids, in the presence of an appropriate chain limiter; —then, in a second optional step, the polyamide PA1 block obtained is reacted with all or part of the polyether PE blocks, in the presence or absence of a catalyst; —in a third step, the polyamide PA2 block is prepared by polycondensation of the chosen isomers: amino acids, lactams or diamines and dicarboxylic acids, in the presence of an appropriate chain limiter; —in a fourth optional step, the polyamide PA2 block obtained is reacted with all or part of the polyether PE blocks, in the presence or absence of a catalyst; —in a fifth step, PA1 or the reaction medium from step 2 is reacted with PA2 or the reaction medium from step 4 and with PE or the remainder of PE not added in step 2 or 4.
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公开(公告)号：US12071538B2
公开(公告)日：2024-08-27
申请号：US16113258
申请日：2018-08-27
Applicant: ARKEMA FRANCE
Inventor： Laure Berdin , Damien Rauline , Karine Loyen , Frederic Malet
CPC classification number: C08L33/12 , C08L53/00 , C08L71/00 , C08L77/00 , C09K3/16 , C08L33/12 , C08L53/00 , C08L33/12 , C08L71/00 , C08L77/00
Abstract: A transparent antistatic composition based on polymethyl methacrylate (PMMA), including: 55% to 99.9% by weight of PMMA, and 0.1% to 45% by weight of at least one polyamide (PA) block-containing and polyether (PE) block-containing copolymer (PEBA) including polyethylene glycol (PEG), with respect to the total composition weight, said copolymer being characterized in that it includes in the range 50% to 80% by weight of PEG with respect to the total weight of copolymer.
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公开(公告)号：US20170306149A1
公开(公告)日：2017-10-26
申请号：US15523448
申请日：2015-11-04
Applicant: Arkema France
Inventor： Frederic Malet
Abstract: The present invention relates to an impact modified polyamide composition. In particular, the present invention relates to impact modified transparent polyarnide compositions comprising a multistage polymer. More particularly, the present invention relates to the use of multistage polymer as impact modifier in a transparent polyamide composition.
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9.发明授权Copolymers comprising polyamide blocks and polyether blocks and having improved mechanical properties 有权包含聚酰胺嵌段和聚醚嵌段并具有改进的机械性能的共聚物公开(公告)号：US08889822B2
公开(公告)日：2014-11-18
申请号：US13859380
申请日：2013-04-09
Applicant: Arkema France
Inventor： Frederic Malet
CPC classification number: C08G81/00 , C08G69/40 , Y10T428/139 , Y10T428/249921
Abstract: The invention relates to a process for producing a shaped article having excellent mechanical properties, said article comprising a block copolymer PAX.Y/PE comprising polyamide (PA) blocks alternating with polyether (PE) blocks, prepared from homopolyamide blocks PAX.Y by polycondenstation of linear aliphatic diamines where PAX.Y is selected from the group consisting of PA 10,12; PA 6,18; PA 10,14; and PA 12.12, reacted with polyether PE blocks in the presence of a catalyst to produce a block copolymer PAX.Y/PE, wherein said PE blocks are either PE diols, or PE blocks comprising NH2 ends. The articles formed are either a fabric, film, sheet, rod, pipe, injection-molded component, or a shoe sole; the copolymer PAX.Y/PE has an improved flexural modulus of at least 300 MPa greater than a copolymer polyamide 12/polytetrametylene with the same size of PA block and with the same size of PE block respectively.
Abstract translation: 本发明涉及一种具有优异机械性能的成型制品的制造方法，所述制品包含嵌段共聚物PAX.Y / PE，其包含与聚醚（PA）嵌段交替的聚酰胺嵌段（PE）嵌段，其由均聚酰胺嵌段PAX.Y通过缩聚 的线性脂族二胺，其中PAX.Y选自PA10,12; PA 6,18; PA 10,14; 和PA12.12在催化剂存在下与聚醚PE嵌段反应生成嵌段共聚物PAX.Y / PE，其中所述PE嵌段是PE二醇或包含NH 2端的PE嵌段。 形成的制品是织物，薄膜，片材，棒材，管材，注射成型部件或鞋底; 共聚物PAX.Y / PE具有比具有相同尺寸的PA嵌段和相同尺寸的PE嵌段的共聚物聚酰胺12 /聚四亚甲基具有至少300MPa的改进的弯曲模量。
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